• Macromolecular Research
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• 제15권5호
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• pp.418-423
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• 2007

A methacrylate copolymer based on isobornyl methacrylate (IBMA) and methyl methacrylate (MMA) was synthesized in an aqueous suspension via free-radical polymerization. The potential of this copolymer as a heat-resistant optical polymer is also discussed. 1,1,3,3-tetramethylbutyl peroxy-2-ethyl hexanoate and n-octyl mercaptan were used as the initiator and chain transfer agents, respectively. The effect of IBMA on the properties of the copolymer was investigated. The composition of the copolymer was analyzed using $^1H-NMR$, and the heat resistance by measuring the glass transition temperature, which exhibited a linear dependency on the IBMA content in the copolymer. Variation of the chain transfer content used in the synthesis step was effective for the optimization of the copolymer for practical use.

• 한국정보통신학회논문지
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• 제12권12호
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• pp.2253-2258
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• 2008

산화물 반도체 감지막이 동작온도에 따라 감응특성을 가지는 마이크로 흐름센서를 설계하기 위해서 통계적 수법에 기초한 Markov 체인 MCM을 이용하여 기초방정식을 정식화하고 마이크로 소자의 열 전달특성을 해석하였다. 계산 결과를 통하여 기존 유한차분법이 가지는 계산 정밀도와 차이가 없음을 확인하였다. 본 논문에서 제안한 Markov 체인 MCM을 활용하면 다양한 마이크로 소자의 열전달 특성과 같은 물리적 특성을 해석하고 설계하는데 유용할 것으로 판단된다.

• Bulletin of the Korean Chemical Society
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• 제16권10호
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• pp.972-976
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• 1995

A trace amount of 4-biphenylcarboxylate having a pre-twisted biphenyl moiety was attached to a poly(methyl methacrylate) side chain and the fluorescence properties of the chromophore were investigated in various solvents such as ethyl acetate and butyl chloride. At room temperature, the polymer exhibited a distinct red shift of the short wavelength emission (325 nm) and an enhanced emission intensity around 430 nm upon excitation at the absorption red edge. The temperature dependence of the intensity ratio (R) of the 325 nm emission to the 430 nm emission was observed when exciting at the red edge over the temperature range between -20 and 60 ℃. However, the temperature dependence was not observed when exciting at the shorter wavelength. The Arrhenius plot of the R value shows the activation energy of 6.0 kJ/mol which is in good agreement with the energy required for the twist of the biphenyl moiety. Together with the results of red edge excitation effects it was concluded that the pre-twisted geometry of the biphenyl moiety is preserved by the restriction of the polymer chain to facilitate the formation of the twisted intramolecular charge transfer (TICT) state upon excitation.

• Bulletin of the Korean Chemical Society
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• 제9권4호
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• pp.248-251
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• 1988

Mechanism of electrochemical polymerization of pyrrole (Py) on a Pt electrode in acidic aqueous solutions was studied by means of potentiostatic measurements, cyclic voltammetry and chronopotentiometry. Pyrrole molecule appeared to be initially oxidized via two-electron transfer step to produce oxidized pyrrole ion ($Py^+$), which was coupled with a non-oxidized pyrrole to yield a dimerized species, Py-Py. The Py-Py thus formed was further oxidized again via two-electron transfer step, which was followed by coupling with non-oxidized monomer and by concomitant expulsion of a $H^+$. Then the latter chain extension process was repeated. The chain extension and polypyrrole oxidation reactions occurred competitively.

• 한국경영과학회지
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• 제35권4호
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• pp.17-31
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• 2010

This study investigates two-stage return policy and recycling issues in an e-marketplace supply chain consisting of consumers, a retailer and a manufacturer. The manufacturer, a focal company in the e-marketplace supply chain, considers the recycling of commercial returns so offers the retailer a buy-back contract of which transfer payment consists of a wholesale price and a buy-back price. Then, under the given contract offer, the retailer determines a selling price and a return policy to control consumers' demand and return requests. We consider the retailer's opportunistic behavior and supply chain coordination issues based on the principal-agent paradigm. We compare the first-best and second-best optima and conduct comparative static analyses to evaluate the performance results of the buy-back contract and provide important managerial implications.

• Bulletin of the Korean Chemical Society
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• 제17권4호
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• pp.376-379
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• 1996

The bulk photopolymerization of methacrylic acid (MA) with phenylsilane was performed to produce poly(MA)s containing phenylsilyl moiety presumably as an end group. It was found that while the polymerization yields and intrinsic viscosities decreased, the TGA residue yields and the relative intensities of SiH IR stretching bands increased with increasing molar ratio of phenylsilane over MA. The phenylsilane seemed to significantly influence on the photopolymerization as both chain initiation and chain transfer agents.

• 한국IT서비스학회지
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• 제20권3호
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• pp.87-101
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• 2021

Since the introduction of block chain technology, its potential use in financial service area have been increasing, and financial firms are seeking ways to take advantage of the benefits of it. The purpose of this study is to present an approach to prioritize block chain-based services for bank. Toward this, we picked out potential financial services through focus group interview and derived the criteria that can be used in evaluating the priorities of block chain-based banking services in the same way. Then, we propose an analytic hierarchy process model to help decision makers prioritize the banking services while considering multiple criteria of technology issues, governmental regulations in the financial industry, cost, managerial issues, customers' needs, and the business opportunity for the bank. By using the analytic hierarchy process model, we can estimate the weighting coefficients to be assigned to each criteria and determine the order of priority in determining the best block chain-based service for the case study bank. The results show that banking login authentication would be forefront service, followed by money transfer, document notarization, and trade financing service in the order, and the trade financing could be most important service in terms of the business profitability for the bank in the future.

• 한국ITS학회 논문지
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• 제16권1호
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• pp.50-63
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• 2017

환승은 타고 있던 교통수단에서 다른 교통수단으로 갈아타는 것을 의미한다. 환승은 통행의 불편을 겪지만, 효율적인 대중교통을 이용하기 위해서는 어쩔 수 없이 발생할 수밖에 없다. 따라서 환승횟수를 최대한 줄이는 것이 대중교통의 활성화를 제공하고, 대중교통의 편의를 제공함에 있어서 아주 중요한 요소라고 할 수 있다. 본 연구에서 수집한 대중교통카드 자료는 평택시 평일 61,986건, 주말 69,100건이며, 수집된 교통자료카드를 이용하여 패턴분석 및 환승영향요인을 분석하였다. Trip Chain 분석 결과, 주말에 주 통행이 통근 및 통행이 아닌 쇼핑, 여가 등의 목적으로 환승 횟수가 많아지며, 통행거리는 10km이상 증가하며 통행시간도 약 9.9분 늘어나는 것으로 나타났다. 또한 Structural Equation Model의 결과, Factor 1릉 총 통행시간, 총 통행거리, Factor 2는 승 하차 인원수, Factor 3는 환승시간, 대기시간, Factor 4는 버스연계노선 수, 운행대수로 환승통행량에 영향을 주는 것으로 나타났다.

• 폴리머
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• 제26권6호
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• pp.759-766
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• 2002

스티렌과 물이 주된 원료로 구성된 혼합물을 high internal Phase emulsion (HIP보) 중합을 통하여 균일한 구형의 등방성 구조로 이루어진 저밀도의 열린 구조 미세기공 발포체를 제조하였고, 물, 가교결합제인 divinylbenzene, 사슬이동제인 dodecane의 함량 변화 등의 중합조건이 미세기공발포체의 기공 크기 및 물성에 미치는 영향을 조사하였다. 제조한 HIPE 발포체의 미세구조 모폴로지를 확인하기 위하여 SEM 사진으로 관찰하였고 기계적 물성을 평가하기 위하여 압축시험으로 압축 탄성률을 측정하였다. 연구 결과 오일 상에 수용액 상을 주입할 때 한 방울씩 연속적으로 주입하는 연속투여 방식의 경우가 한번에 주입하는 일괄투여 방식의 경우보다 균일하고 안정한 발포체를 제조하는데 효과적이었다. 교반속도와 계면활성제는 기공 크기와 계면의 window 크기에 상당한 영향을 끼쳤다. 사슬이동제의 첨가는 기공 크기를 증가시켰지만 window 크기는 오히려 감소시켰다. 발포체의 압축 탄성률은 가교결합제의 함량이 증가할수록, 사슬이동제의 함량이 감소할수록 증가하였다.

• 폴리머
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• 제32권6호
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• pp.566-572
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• 2008

메탈로센 [(TMDS)$Cp_2$]$ZrCl_2$, 촉매 1과 Exxon 촉매인 [$(n-Bu)_2Cp_2$]$ZrCl_2$, 촉매 2를 사용하여 폴리에틸렌 왁스를 제조하였다. 분자량을 조절하기 위하여 수소를 연쇄이동제로 사용하였다. 실험결과 수소의 주입량이 증가할수록 중합활성의 감소 생성된 폴리에틸렌 왁스의 분자량과 분자량 분포의 감소 그리고 폴리에틸렌 왁스의 융점 저하가 관찰되었다. 수소의 주입으로 폴리에틸렌의 분자량은 1500, 융점은 60 $^\circ$C까지 조절이 가능하였다. 수소의 양을 조절함으로써 메탈로센을 통해 분자량분포가 좁고 융점이 낮은 고품질의 폴리에틸렌 왁스의 제조가 가능하였다. 본 연구실에서 개발된 촉매 1은 알려진 가장 우수한 메탈로센인 촉매 2와 폴리에틸렌 왁스 제조에서 경쟁이 가능한 유사한 특성을 보였다.