• 제목/요약/키워드: available Si

검색결과 430건 처리시간 0.027초

Long-term Assessment of Chemical Properties from Paddy Soils in Gyeongnam Province

  • Son, Daniel;Sonn, Yeon-Kyu;Kang, Seong-Soo;Heo, Jae-Young;Kim, Dae-Ho;Choi, Yong-Jo;Lee, Sang-Dae;Ok, Yong Sik;Lee, Young Han
    • 한국토양비료학회지
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    • 제49권2호
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    • pp.132-137
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    • 2016
  • Field monitoring was performed to evaluate the chemical properties of 260 paddy soils every 4 years from 1999 to 2015 in Gyeongnam province. Soil chemical properties, including soil pH, electrical conductivity, amount of organic matter (OM), available phosphate ($P_2O_5$), exchangeable potassium (K), calcium (Ca), magnesium (Mg) and sodium (Na), and available silicate ($SiO_2$) were analyzed. In 2015, the average values of pH, OM, available $P_2O_5$, exchangeable K, Ca, and Mg, and available $SiO_2$ was 5.8, $30g\;kg^{-1}$, $222mg\;kg^{-1}$, $0.37cmol_c\;kg^{-1}$, $6.5cmol_c\;kg^{-1}$, and $1.4cmol_c\;kg^{-1}$, $252mg\;kg^{-1}$, respectively. The frequency distribution within optimum range of paddy soils was 49.2%, 20.8%, 18.5%, and 5.8% for soil pH, OM, available $P_2O_5$, and available $SiO_2$, respectively. The available $P_2O_5$ concentrations in 2015 was excess level with portion of 58% and did not alter significantly during the experimental period. Although the average of available $SiO_2$ concentration has tended to increase with every year, the insufficient proportion of available $SiO_2$ concentration in 2015 was 48%. These results indicated that a balanced management of soil chemical properties can properly control the amount of fertilizer applied for sustainable agriculture in paddy field.

Effective Valence Shell Hamiltonian Calculations on Spin-Orbit Coupling of SiH, SiH+, and SiH2+

  • Chang, Ye-Won;Sun, Ho-Sung
    • Bulletin of the Korean Chemical Society
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    • 제24권6호
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    • pp.723-727
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    • 2003
  • Recently the ab initio effective valence shell Hamiltonian method $H^v$ has been extended to treat spin-orbit coupling in atoms or molecules. The quasidegenerate many-body perturbation theory based $H^v$ method has an advantage of determining the spin-orbit coupling energies of all valence states for both the neutral species and its ions with a similar accuracy from a single computation of the effective spin-orbit coupling operator. The new spin-orbit $H^v$ method is applied to calculating the fine structure splittings of the valence states of SiH, $SiH^+$, and $SiH^{2+}$ not only to assess the accuracy of the method but also to investigate the spin-orbit interaction of highly excited states of SiH species. The computed spin-orbit splittings for ground states are in good agreement with experiment and the few available ab initio computations. The ordering of fine structure levels of the bound and quasi-bound spin-orbit coupled valence states of SiH and its ions, for which neither experiment nor theory is available, is predicted.

시설재배 참외에 대한 규산 비료 시용 효과 (Effect of Silicate Fertilizer on Oriental Melon in Plastic Film House)

  • 이승호;조현종;신현진;신용습;박소득;김복진;정종배
    • 한국토양비료학회지
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    • 제36권6호
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    • pp.407-416
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    • 2003
  • 규산질 비료는 산성 토양의 개량 효과와 함께 병충해 발생 억제 효과를 나타내므로 농약 사용량을 줄일 수 있어 안전농산물의 생산을 유도할 수 있는 자재로 판단되고 있으며 일부 참외의 수량 증대와 상품성을 향상시킬 수 있는 것으로 알려져 있다. 그러나 현재 참외를 비롯한 과채류에 대하여 규산질 비료의 시용효과가 검정되어있지 않고 또한 적정 시용 기준이 설정되어 있지 못한 상태에서 농가별로 토양 유효규산 함량을 고려하지 않고 임의로 규산질 비료를 사용하고 있다. 본 연구에서 조사된 결과를 보면 참외 재배 포장에서 1 N NaOAc로 추출할 경우 최고 $500mg\;SiO_2\;kg^{-1}$ 수준까지 유효규산이 축적되어 있으며, $200mg\;SiO_2\;kg^{-1}$ 수준의 유효규산을 함유하고 있는 토양에 대한 규산질 비료의 시용은 참외의 생육이나 수량 증대에 영향을 미치지 못하는 것으로 나타났다. 또한 1 N NaOAc로 추출한 토양 유효규산 함량이 $100mg\;SiO_2\;kg^{-1}$ 이상인 경우 참외의 규산 흡수가 더 이상 증가하지 않는 것으로 나타났다. 따라서 토양 유효규산 함량을 무시한 과다 규산질 비료의 시용은 pH와 EC의 증가에 따른 부작용을 유발할 가능성도 높으므로 농가지도를 통하여 시용량이 적절히 조절되어야 할 것이며, 참외를 비롯한 밭작물에 대한 적정 토양 유효규산 함량과 시비 기준 확립을 위한 연구가 더욱 필요할 것으로 판단된다.

PCS용 2.5V Si CMOS 저잡음 증폭기 설계 (Design of 2.5V Si CMOS LNA for PCS)

  • 김진석;원태영
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2000년도 하계종합학술대회 논문집(2)
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    • pp.129-132
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    • 2000
  • In this paper, a 1.8㎓ low noise amplifier was designed and simulated using 0.2$\mu\textrm{m}$ Si CMOS process. Noise characteristics and s parameters were extracted for the 300$\mu\textrm{m}$ gate width and 0.25$\mu\textrm{m}$ gate length NMOS transistors. For high available power gain, each stage was designed cascode type. It revealed available power gain of 23.5dB, noise figure of 2.0dB, power consumption of 15㎽ at 2.5V. It was shown that designed low noise amplifier had good RF performance. Designed Si CMOS LNA is expected to be used for RF front-end in transceiver.

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Aluminum Engine Cylinder Bore 적용 AlSiMg/SiC 복합 용사피막의 내마모 특성 (Wear Resistance Characteristics of Thermal Sprayed AlSiMg/SiC Composite Coatings on Aluminum Engine Cylinder Bores)

  • 양병모;변응선;박경채
    • Journal of Welding and Joining
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    • 제17권6호
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    • pp.62-69
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    • 1999
  • The advantages of Thermal sprayed coatings as a replacement for cast iron liners are reduced weight, better heat transfer and reduced cost. One of the most important performance attributes of a cylinder bore coating is its wear resistance, since it must survive the abrasive sliding of both the piston rings and the piston skirt. In this study, composite powders were prepared by ball milling of Al-13Si-3Mg(wt%) alloy with SiC particles. The concentrations of SiC were 40 and 60wt%. The composite powders were sprayed using Metco-9MB plasma torch. Plasma sprayed coatings were heat-treated at 500℃ for 3 hours. The wear resistances of the plasma sprayed coatings were found to improve with heat treatment and superior to the commercially available G.C.I.(gray cast iron). AlSiMg-40SiC heat-treated coatings showed the best wear resistance in this study.

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Flexural Strength of Polysiloxane-Derived Strontium-Doped SiOC Ceramics

  • Eom, Jung-Hye;Kim, Young-Wook
    • 한국세라믹학회지
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    • 제52권1호
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    • pp.61-65
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    • 2015
  • The effect of Sr addition on the flexural strength of bulk SiOC ceramics was investigated in polymer-derived SiOC ceramics prepared by conventional hot pressing. Crack-free, dense SiOC discs with a 30 mm diameter were successfully fabricated from commercially available polysiloxane with 1 mol% strontium isopropoxide derived Sr as an additive. Agglomerates formed after the pyrolysis of polysiloxane led to the formation of domain-like structures. The flexural strength of bulk SiOC was strongly dependent on the domain size formed and Sr addition. Both the minimization of the agglomerate size in the starting powders by milling after pyrolysis and the addition of Sr, which reinforces the SiOC structure, are efficient ways to improve the flexural strength of bulk SiOC ceramics. The typical flexural strength of bulk Sr-doped SiOC ceramics fabricated from submicron-sized SiOC powders was ~209 MPa.

밭토양에 처리된 규산질 비료의 유효화와 토양반응 교정효과 (Availability of Silicate Fertilizer and its Effect on Soil pH in Upland Soils)

  • 조현종;최희열;이용우;이윤정;정종배
    • 한국환경농학회지
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    • 제23권2호
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    • pp.104-110
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    • 2004
  • 이화학적 특성이 다른 4가지의 밭토양에 대한 규산질 비료를 처리하여 토양의 유효규산 함량과 pH 변화에 미치는 효과를 조사하였다. 토양의 이화학적 특성과 기존 유효규산 함량에 상관없이 토양 유효규산 함량은 규산질 비료 시용량에 비례하여 증가하였다. 규산질 비료의 유효화 정도는 토양마다 차이가 있었으며 최저 9.1%에서 최고 19.2% 정도의 비율을 나타냈다. 규산질 비료 100 kg/10a 수준의 처리는 용탈 등으로 제거되지 않는 한 10 cm 질이 표토에 평균적으로 100 mg/kg 정도의 유효규산을 공급할 수 있는 것으로 나타났다. 퇴비 혼합처리는 토양 유효규산 함량 증가에 큰 영향을 미치지 못했으며, 석회 처리는 유효규산 함량을 다소 증가시켰다. 토양 pH 변화는 모든 토양에서 규산질 비료 시비량에 비례하여 증가하였으며, 규산질 비료 100 kg/10a 처리로 토양 pH를 $0.1{\sim}0.2$ 단위 증가시킬 수 있는 것으로 나타났다. 따라서 산성 토양의 경우에는 규산질 비료의 시용과는 별도로 pH 교정을 위해 석회비료를 시용해야 할 것이다.

Interaction of Gas-phase Atomic Hydrogen with Chemisorbed Oxygen Atoms on a Silicon Surface

  • Lee, Sang-Kwon;Ree, Jong-Baik;Kim, Yoo-Hang;Shin, Hyung-Kyu
    • Bulletin of the Korean Chemical Society
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    • 제32권5호
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    • pp.1527-1533
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    • 2011
  • The reaction of gas-phase atomic hydrogen with oxygen atoms chemisorbed on a silicon surface is studied by use of the classical trajectory approach. We have calculated the probability of the OH formation and energy deposit of the reaction exothermicity in the newly formed OH in the gas-surface reaction H(g) + O(ad)/Si${\rightarrow}$ OH(g) + Si. All reactive events occur in a single impact collision on a subpicosecond scale, following the Eley-Rideal mechanism. These events occur in a localized region around the adatom site on the surface. The reaction probability is dependent upon the gas temperature and shows the maximum near 1000 K, but it is essentially independent of the surface temperature. The reaction probability is also independent upon the initial excitation of the O-Si vibration. The reaction energy available for the product state is carried away by the desorbing OH in its translational and vibrational motions. When the initial excitation of the O-Si vibration increases, translational and vibrational energies of OH rise accordingly, while the energy shared by rotational motion varies only slightly. Flow of energy between the reaction zone and the solid has been incorporated in trajectory calculations, but the amount of energy propagated into the solid is only a few percent of the available energy released in the OH formation.

용융산화법으로 제조한 $Al_2O_3-SiC$ 세라믹스의 미세구조와 기계적 성질 (Microstructure and Mechanical Properties of the $Al_2O_3-SiC$ Ceramics Produced by Melt Oxidation)

  • 김일수
    • 한국세라믹학회지
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    • 제31권10호
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    • pp.1169-1175
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    • 1994
  • Five Al2O3/SiC/metal composites with four different particle sizes of green SiC abrasive grains are grown by the directed oxidation of an commercially available Al-alloy. Oxidation was conducted in air at 100$0^{\circ}C$, 96 hours long. Slip casted SiC-fillers were placed on the alloy or SiC powder deposited up to the required layer thickness. Their microstructures are described and measurements of density, elastic constants, frexural strength, fracture toughness and work of fracture are reported. The results are compared with those of commercial dense sintered Al2O3. The properties of produced materials have a strong relationship to not only the properties of Al2O3, SiC, Al and Si but also to the phase share and phase distribution. The composite materials are dense (0.5% porosity), tough (KIC = 3.4~6.4 MPa{{{{ SQRT { m} }}), strong ({{{{ sigma }}B = 170~345 MPa) and reasonably shrinkage free producible. The reinforcements is attained mainly through the plastic deformation of ductile metal phase.

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VBIC Model Application and Parameter Extraction and Optimization for SiGe HBT

  • Lee, Sang-Heung;Park, Chan-Woo;Lee, Seung-Yun;Lee, Ja-Yol;Kang, Jin-Yeong
    • 한국통신학회논문지
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    • 제28권8A호
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    • pp.650-656
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    • 2003
  • In 1995, a group of representatives from the integrated circuits and computer-aided design industries presented a industry standard bipolar model called the VBIC model. The VBIC model includes the improved Early effect, quasi-saturation, substrate parasitic, avalanche multiplication, and self-heating which are not available in the conventional SGP model. This paper applies VBIC model for SiGe HBT device and develops an accurate and efficient methodology to extract all the DC and AC parameters of the VBIC model for SiGe HBT device at room temperature. Simulated results by the extracted VBIC model parameter are compared with the measurement data and show very good agreement in both DC and s-parameters prediction.