• 제목/요약/키워드: Zn electrode

검색결과 397건 처리시간 0.019초

산화물과 질산염으로 제조한 투명전극 타깃용 다성분계 IGZO 세라믹스 (Multicomponent IGZO Ceramics for Transparent Electrode Target Fabricated from Oxides and Nitrates)

  • 이현권;윤지혜;조경식
    • 한국분말재료학회지
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    • 제26권5호
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    • pp.375-382
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    • 2019
  • Homogeneous multicomponent indium gallium zinc oxide (IGZO) ceramics for transparent electrode targets are prepared from the oxides and nitrates as the source materials, and their properties are characterized. The selected compositions were $In_2O_3:Ga_2O_3:ZnO$ = 1:1:2, 1:1:6, and 1:1:12 in mole ratio based on oxide. As revealed by X-ray diffraction analysis, calcination of the selected oxide or nitrides at $1200^{\circ}C$ results in the formation of $InGaZnO_4$, $InGaZn_3O_6$, and $InGaZn_5O_8$ phases. The 1:1:2, 1:1:6, and 1:1:12 oxide samples pressed in the form of discs exhibit relative densities of 96.9, 93.2, and 84.1%, respectively, after sintering at $1450^{\circ}C$ for 12 h. The $InGaZn_3O_6$ ceramics prepared from the oxide or nitrate batches comprise large grains and exhibit homogeneous elemental distribution. Under optimized conditions, IGZO multicomponent ceramics with controlled phases, high densities, and homogeneous microstructures (grain and elemental distribution) are obtained.

온벽 펄스 레이저 증착법을 이용해 합성한 Ga 도핑된 산화아연계 나노선 에탄올 가스 센서의 특성 (Sensing Characteristics of ZnO-based Ethanol Gas Sensor on Ga-doped Nanowires by Hot Walled Pulsed Laser Deposition)

  • 정다운;김경원;이득희;;김상식;이상렬
    • 한국전기전자재료학회논문지
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    • 제24권7호
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    • pp.594-598
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    • 2011
  • We have investigated the sensing properties of ethanol gas sensor with pure ZnO and Ga-doped ZnO nanowires on Au coated (0001) sapphire substrates grown by hot walled pulsed laser deposition. Randomly aligned ZnO nanowires arrays were grown on a Au-electrode patterned under ambient conditions. ZnO nanowires have various sizes and shapes with a different substrate position inside a furnace. The average of length and diameter of the ZnO nanowires were $8\;{\mu}m$ and 100 nm respectively, and confirmed by field emission scanning electron microscopy. Sensitivity chanege characterization of the gas sensor was found that measured sensitivities of the ethanol gas sensors were 83.3% and 68.3% at $300^{\circ}C$ respectively.

3층으로 적층된 ZnO 바리스터의 열분포 해석 (Thermal Distribution Analysis of Triple-Stacked ZnO Varistor)

  • 장경욱
    • 한국전기전자재료학회논문지
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    • 제36권4호
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    • pp.391-396
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    • 2023
  • Recently, as power and electronic devices have increased in frequency and capacity, it has become a major concern to protect electronic circuits and electronic components used in these devices from abnormal voltages such as various surges and pulse noise. To respond to variously rated voltages applied to power electronic devices, the rated voltages of various varistors can be obtained by controlling the size of internal particles of the varistor or controlling the number of layers of the varistor. During bonding, the problem of unbalanced thermal runaway occurring between the electrode and the varistor interface causes degradation of the varistor and shortens its life of the varistor. In this study, to solve the problem of unbalanced heat distribution of stacked varistors to adjust the operating voltage, the contents of the ZnO-based varistor composition were 96 wt% ZnO, 1 mol% Sb2O3, 1 mol% Bi2O3, 0.5 mol% CoO, 0.5 mol% MnO, and 1 mol% TiO2. A multi-layered ZnO varistor was modeled by bonding a single varistor with a composition in three layers according to the operating voltage. The thermal distribution of the triple-layered ZnO varistor was analyzed for the thermal runaway phenomenon that occurred during varistor operation using the finite element method according to Comsol 5.2.

금속-공기전지의 Anode전극 반응에 관한 연구 (Study on the Anode Electrode Reaction in the Metal-Air Cell)

  • 김용혁
    • 한국전기전자재료학회논문지
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    • 제23권12호
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    • pp.1002-1006
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    • 2010
  • In this study, magnesium (Mg), zinc (Zn) and aluminium (Al) as anode electrode and the solution of NaCl dissolved with 2~20 wt% as electrolytes were used for the metal-air cell. The open circuit voltage, short circuit current and I-V characteristics upon different kinds of anode electrode and electrolyte concentration were investigated. The open circuit voltage, initially about 1.45 V, rises to 1.6 V during the first 10 minutes indicating the necessity of an induction time to activate the catalyst on the air cathode. The short circuit current increases with an increased concentration of NaCl, causes an increase in the conductivity of the electrolyte solution, but the open circuit voltage did not under undergo influence of electrolyte. From NaCl 20 wt% electrolyte, the maximum output power of the magnesium electrode materials was measured with 177mW. It is found that the power characteristics of metal-air cell could be improved by using magnesium electrode materials in the NaCl electrolyte.

스퍼터링 증착법을 이용한 ZnO/Al/ZnO 구조의 유연투명전극 연구 (Aluminum based ZnO/Al/ZnO flexible Transparent Electrodes Fabricated by Magnetron sputtering)

  • 방금혁;최두호
    • 마이크로전자및패키징학회지
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    • 제25권2호
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    • pp.31-34
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    • 2018
  • 차세대 유연 광전소자 적용을 위한 금속-산화물 샌드위치 구조인 ZnO/Al/ZnO 박막의 유연투명전극 기초연구를 수행하였다. 모든 증착은 유연성을 가지는 PET 기판 상에서 이루어졌으며, 상 하부 ZnO층의 두께가 광 투과도에 미치는 영향을 확인하기 위하여 Al 층의 두께는 모두 8 nm로 고정시킨 채 상부 ZnO 층의 두께는 5-70 nm, 하부 ZnO 층의 두께는 2.5-20 nm까지 변화를 주었다. 가시광선영역(380 nm-770 nm) 파장대를 가지는 광원의 투과도에 대하여 측정한 결과, 상부 ZnO 층의 두께가 30 nm이며 하부 ZnO 층의 경우 2.5 nm 일 때 가장 높은 투과도를 보였다. 400 nm 파장기준 투과도 62%, 면저항 $19{\Omega}/{\Box}$, 그리고 곡률반경 5 mm 조건에서의 휨 테스트 후 면저항과 투과도의 변화가 발생하지 않는 ZnO/Al/ZnO 유연투명전극 결과를 보고한다.

Mass Transfer to Amalgamated Copper Rotating Disk Electrode

  • Sulaymon, Abbas H.;Abbar, Ali H.
    • Journal of Electrochemical Science and Technology
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    • 제3권4호
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    • pp.165-171
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    • 2012
  • An experimental study of mass transfer to an amalgamated copper rotating disc electrode has been employed to determine an empirical correlation for the mass transfer rate in laminar flow. The study was performed in a three-electrodes configuration using 0.1 M boric acid and 0.1M potassium chloride as supporting electrolyte with Zn (II) concentration in the range (25-100 mg $dm^{-3}$). Polarization curves at different zinc ion concentration are reported. Hydrogen and oxygen reduction has also been considered.The diffusion coefficients and mass transfer coefficient were obtained using limiting diffusion current technique based on zinc ion reduction. A least squares analysis indicates that the laminar flow results for 13067 < Re > 57552 and 550 < Sc > 1390 can be correlated by the following equation with correlation coefficient (CR) equal to 0.98: $sh=0.61Re^{0.5}Sc^{1/3}$.

페라이트 칩 노이즈 필터의 설계 및 특성에 관한 연구 (A study on the design and properties of ferrite chip noise filter)

  • 이창호;김왕섭;김경용
    • 전자공학회논문지A
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    • 제32A권4호
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    • pp.57-64
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    • 1995
  • Three models for the transformation of ferrite chip noise filter that has jagged type of electrode into cylinderical ferrite beadfilter were presented. The properties of filters were also calculated based on the proposed models. The measured properties of ferrite chip noise filter with jagged-type electrode fabricated with Ag electrode and Ni-Zn ferrite revealed that the model 3 was the best one to describe the behavior of filters. In particular, the calculated values of model 3 agreed well with measured ones as functions of electrode patterns and chip thickness. The present study showed that the properties of fiters could be designed by theoretical models and fabricated with required characteristics.

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전기증착법을 이용한 ZnO 막대구조의 형성 및 염료감응형 태양전지에의 응용 (Fabrication of ZnO Rod by Electrodeposition and Its Application to Dye Sensitized Solar Cell)

  • 김혜영;조윤경;이기영;이인회;탁용석
    • Korean Chemical Engineering Research
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    • 제50권1호
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    • pp.162-166
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    • 2012
  • 본 연구에서는 전해증착법과 열처리를 통하여 ITO 투명전극 위에 고밀도의 ZnO 막대구조를 형성하는 방법을 조사하였다. 증착과정에서 $Zn(OH)_2$와 ZnO가 함께 형성되는 것을 고려할 때 전기화학적 ZnO 증착효율은 33% 이하를 나타내었다. $500^{\circ}C$ 열처리 후 ZnO는 (002)를 선택적으로 갖는 결정구조를 형성하며, 나노막대 구조의 성장속도는 0.986 ${\mu}m/hr$로 측정되었다. 그리고 전기화학적으로 제조한 ZnO 막대를 염료감응 태양전지의 전극으로 사용시 측정된 전지효율은 0.21%로서 태양전지용 전극으로서의 가능성을 확인하였다.

Co-sputtering법으로 제작한 ZnTe 태양전지의 특성 (Characteristics of the ZnTe solar cell by the co-sputtering methods)

  • 장유진;김성우;최혁환;이명교;권태하
    • 한국정보통신학회논문지
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    • 제8권2호
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    • pp.440-448
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    • 2004
  • 본 논문에서는 II-Vl족의 ZnTe 화합물반도체 태양전지를 제작하기 위하여 투명전극(AZO) 및 Buffer layer(ZnO)의 특성과 태양전지의 효율에 가장 큰 영향을 미치는 광흡수층의 에너지밴드갭을 줄이는 연구를 하였다. ZnTe박막은 Zn(Zinc)과 Te(Tellurium)를 co-sputtering법을 이용하여 증착하였다. ZnTe 박막은 Zn과 Te의 RF power를 각각 50W, 30W로 하여 10mTorr의 Ae 분위기에서 20$0^{\circ}C$의 기판온도로 제작되었으며, 이때의 에너지밴드갭은 1.73eV였다. 이렇게 제작된 박막을 진공상태에서 $400^{\circ}C$의 온도로 10초간 열처리하여 1.67eV의 에너지밴드갭을 얻을 수 있었고, 이때의 Zn과 Te의 비율은 32%:68%였다. 최적의 조건에서 태양전지는 6.85% (Voc:0.69V, Jsc:21.408㎃/$cm^2$, Fill Factor (FF):0.46)의 효율을 얻을 수 있었다.