• Bulletin of the Korean Chemical Society
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• v.13 no.1
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• pp.11-17
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• 1992

Vibration-to-vibration energy transfer probabilities for $HF(v=n)+H_2(v=0){\to}HF(v=n-1)+H_2(v=1)$ and $DF(v=n)+D_2(v=0){\to}DF(v=n-1)+D_2(v=1)$ including both the vibration-to-vibration and translation (V-V, T) and vibration-to-vibration and rotation (V-V, R) energy transfer paths have been calculated semiclassically using a simplified collision model and Morse-type intermolecular interaction potential. The calculated results are in reasonably good agreement with those obtained by experimental studies. They also show that the transition processes for $HF(v=1-3)+H_2(v=0){\to}HF(v=0-2)+H_2(v=1)$ and $DF(v=1,\;4)+D_2(v=0){\to}DF(v=0,\;3)+D_2(v=1)$ are strongly dependent on the V-V, T path at low temperature but occur predominantly via the V-V, R path with rising temperature. The vibration-to-vibration energy transfer for $HF(v=4)+H_2(v=0){\to}HF(v=3)+H_2(v=1)$ and $DF(v=2-3)+D_2(v=0){\to}DF(v=1-2)+D_2(v=1)$ occur predominantly via V-V, R path and V-V, T path through whole temperatures, respectively.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2019.05a
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• pp.323-324
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• 2019

For flash memory devices with Ge-MONOS(metal-Oxide-Nitride-Oxide-Silicon) structures, variations of threshold voltage with programming voltage were investigated. The programming voltage was observed in steps of 1V from 10V to 17V and programmed for 1 second. The threshold voltage from 10V to 14V was about 0.5V, which is not much different from that before programing, and the threshold voltages at 15V, 16V and 17V were 1.25V, 2.01V and 3.84V, respectively, which differed 0.75V, 1.49V and 3.44V from that before programing.

• Journal of Sericultural and Entomological Science
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• v.10
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• pp.35-40
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• 1969

Various formulae for estimation of spring leaf production in mulberry trees were calculated and obtained. Four varieties of mulberry trees were used as the materials, and four characters, namely branch length (X$_1$), node number (X$_2$), branch diameter (X$_3$) and branch number per stock (X$_4$) were studied. The formulae to estimate the leaf yield of spring mulberry trees are as follows: 1. $Y_1$v$_1$= -26.8939＋50.3950X$_1$＋1.1403X$_2$ $Y_1$v$_2$= -372.1091＋116.6371X$_1$＋0.1984X$_2$ $Y_1$v$_3$= 149.8203＋90.5125X$_1$-0.9775X$_2$ $Y_1$v$_4$= 108, 1496＋59.4533X$_1$＋1.4965X$_2$ Where $Y_1$v$_1$, $Y_1$v$_2$, $Y_1$v$_3$, $Y_1$v$_4$, are showed the estimated yield of the each variety, namely Gaeryang Seuban, Ilchirye, Nosang, and Suwon Sang No. 4, respectively. X$_1$ and X$_2$ denote the measured values of branch length and node number, respectively. 2. $Y_{7}$v$_1$= -54.4411＋32.9869c1.1127X$_2$＋21.7600X$_3$ $Y_{7}$v$_2$= -494.1480-1.8756X$_1$＋0.9788X$_2$＋110.0039X$_3$ $Y_{7}$v$_3$= 143.2836＋29.1779X$_1$＋0.1644X$_2$＋48.4135X$_3$ $Y_{7}$v$_4$= 1243.2549＋1.9454X$_1$＋2.7118X$_2$-75.6669X$_3$ Where $Y_{7}$v$_1$, $Y_{7}$v$_2$, $Y_{7}$v$_3$, $Y_{7}$v$_4$, are the estimated yield of the each variety, namely Gaeryang-Seuban, Ilchirye, Nosang, Suwon Sang No 4, respectively. X$_1$, X$_2$, X$_3$ denote the measured values of each character, branch length, node number, branch diameter and branch number per stock, respectively. 3. $Y_{11}$v$_1$=233.4780＋74.3713X$_1$＋1.2912X$_2$＋39.0420X$_3$-148.9300X$_4$ $Y_{11}$v$_2$=-317.0150＋15.l524X$_1$＋1.0861X$_2$＋156.7973X$_3$-148.3742X$_4$ $Y_{11}$v$_3$=178.7011＋29.8664X$_1$-0.2562X$_2$＋102.4632X$_3$-83.2693X$_4$ $Y_{11}$v$_4$= 264.0062＋47.7742X$_1$＋2.6996X$_2$＋92.8882X$_3$-192.3464X$_4$ Where $Y_{11}$v$_1$, $Y_{11}$v$_2$, $Y_{11}$v$_3$, $Y_{11}$v$_4$, are the estimated yield values of four varieties, and X$_1$, X$_2$, X$_3$, X$_4$, denote the measured values of four characters, namely branch length, node number, branch diameter and branch number per stock, respectively. The estimation method of mulberry spring leaf yield by measurement of some characters, in autumn the year before, could be the better method to determine the leaf yield of mulberry trees without destroying the leaves and without weighting the leaves of mulberry trees than the other methods.

• Journal of Sericultural and Entomological Science
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• v.9
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• pp.21-25
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• 1969

Various formulae for estimation of leaf production in mulberry trees were investigated and obtained. Four varieties of mulberry trees were used as the materials, and four characters. namely branch length (X, 1). branch diameter (X, 2). leaf number per branch (X, 3), and leaf area per branch (X, 4). were studies. The formulae to eatimate the leaf yield of mulberry trees are as follows: 1. Y$_1$v$_1$＝-115.760＋0.068X$_1$＋165.756X$_2$ Y$_1$v$_2$＝-221.500＋1.768X$_1$＋38.152X$_2$ Y$_1$v$_3$＝-253.826-0.116X$_1$＋289.507X$_2$ Y$_1$v$_4$＝ -157.559＋1.063X$_1$＋106.088X$_2$ where Y$_1$v$_1$, Y$_1$v$_2$, Y$_1$v$_3$, Y$_1$v$_4$, are showed the estimated yield of the each variety, namely Gaeryang souban, Ilchirye, Nosang. and Suwon Sang No. 4, respectively. X$_1$ and X$_2$ denote the measured values of branch length and branch diameter, respectively. 2. Y$\sub$7/v$_1$＝-118.478-0.665X$_1$＋184.445X$_2$＋2.346X$_3$ Y$\sub$7/v$_2$＝-217.432＋2.062X$_1$＋35.668X$_2$-1.058X$_3$ Y$\sub$7/v$_3$＝-206. 249-0.739X$_1$＋268.08X$_2$＋2.770X$_3$ Y$\sub$7/v$_4$＝-153.383＋0.009X$_1$＋2.024X$_2$＋0.171X$_3$where Y$\sub$7/v$_1$, Y$\sub$7/v$_2$, Y$\sub$7/v$_3$, Y$\sub$7/v$_4$, are the estimated yield of the each variety, namely Gaeryang. Souban, Ilichirye, Nosang, and Suwon Sang No. 4, respectively. X$_1$, X$_2$, X$_3$, denote the measured values of each character. branch length, branch diameter and leaf number per branch, respectively. 3. Y$\sub$11/v$_1$＝82. 567-1.283X$_1$＋15.501X$_2$＋0.640X$_3$＋3.511X$_4$ Y$\sub$11/v$_2$＝136.411＋0.311X$_1$＋1.921X$_2$-0. 217X$_3$＋0.214X$_4$ Y$\sub$11/v$_3$＝150.2Z7-0.139X$_1$＋11.788X$_2$＋0.143X$_3$＋0.381X$_4$ Y$\sub$11/v$_4$＝160.850＋0.323X$_1$＋66.076X$_2$-0.794X$_3$＋2..614X$_4$ where Y$\sub$11/v$_1$, Y$\sub$11/v$_2$, Y$\sub$11/v$_3$, Y$\sub$11/v$_4$, are the estimated yield values of four varieties, and X$_1$, X$_2$, X$_3$, X$_4$ denote the measured values of four characters. namely branch length, branch diameter. leaf number per branch and leaf area per branch. respectively. The estimation method of mulberry leaf yield by measurement of some characters, branch length. branch diameter. leaf number per branch and leaf area per branch. could be the better method to determine the leaf yield of mulberry trees without destroying the leaves and without weighting the leaves of mulberry trees than the other methods.

• Bulletin of the Korean Chemical Society
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• v.28 no.4
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• pp.581-588
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• 2007

To enhance the photodecomposition of concentrated ammonia into N2, Pt/V-TiO2 photocatalysts were prepared using solvothermal and impregnation methods. Nanometer-sized particles of 0.1, 0.5 and 1.0 mol% V-TiO2 were prepared solvothermally, and then impregnated with 1.0 wt% Pt. The X-ray diffraction (XRD) peaks assigned to V2O5 at 30.20 (010) and Pt metal at 39.80 (111) and 46.20 (200) were seen in the 1.0 wt% Pt/ 10.0 mol% V-TiO2. The particle size increased in the order: pure TiO2, V-TiO2 and Pt/V-TiO2 after thermal treatment at 500 °C, while their surface areas were in the reverse order. On X-ray photoelectron spectroscopy (XPS), the bands assigned to the Ti2p3/2 and Ti2p1/2 of Ti4+-O were seen in all the photocatalysts, and the binding energies increased in the order: TiO2 < Pt/V-TiO2 < V-TiO2. The XPS bands assigned to the V2p3/2 (517.85, 519.35, and 520.55 eV) and V2p1/2 (524.90 eV) in the V3+, V4+ and V5+ oxides appeared over V-TiO2, respectively, while the band shifted to a lower binding energy with Pt impregnation. The Pt components of Pt/ V-TiO2 were identified at 71.60, 73.80, 75.00 and 76.90 eV, which were assigned to metallic Pt 4f7/2, PtO 4f7/2, PtO2 4f7/2, and PtO 4f5/2, respectively. The UV-visible absorption band shifted closer towards the visible region of the spectrum in V-TiO2 than in pure TiO2 and; surprisingly, the Pt/V-TiO2 absorbed at all wavelengths from 200 to 800 nm. The addition of vanadium generated a new acid site in the framework of TiO2, and the medium acidic site increased with Pt impregnation. The NH3 decomposition increased with the amount of vanadium compared to pure TiO2, and was enhanced with Pt impregnation. NH3 decomposition of 100% was attained over 1.0 wt% Pt/1.0 mol% V-TiO2 after 80 min under illumination with 365 nm light, although about 10% of the ammonia was converted into undesirable NO2 and NO. Various intermediates, such as NO2, -NH2, -NH and NO, were also identified in the Fourier transform infrared (FT-IR) spectra. From the gas chromatography (GC), FT-IR and GC/mass spectroscopy (GC/MS) analyses, partially oxidized NO and NO2 were found to predominate over V-TiO2 and pure TiO2, respectively, while both molecules were reduced over Pt/V-TiO2.

• Applied Chemistry for Engineering
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• v.20 no.3
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• pp.273-278
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• 2009

A series of poly[2-(2,6-dimethylpyran-4-ylidene)malononitrile-alt-1,4-bis(dodecyloxy)-2,5-divinylbenzene] (PM-PPV), poly[2-{2,6-Bis-[2-(5-bromothiophen-2-yl)-vinyl]-pyran-4-ylidene}-malononitrile-alt-1,4-bis(dodecyloxy)-2,5-divinylbenzene] (PMT-PPV) and poly[2-[2,6-Bis-(2-{4-[(4-bromophenyl)-phenylamino]-phenyl}-vinyl)-pyran-4-ylidene]-malononitrile-alt-1,4-bis(dodecyloxy)-2,5-divinylbenzene] (PMTPA-PPV) were synthesized by the Heck coupling reaction. The band gap of PM-PPV, PMT-PPV and PMTPA-PPV were 2.18 eV, 1.90 eV and 2.07 eV, respectively. The LUMO energy levels of PM-PPV, PMT-PPV and PMTPA-PPV were 3.65 eV, 3.54 eV and 3.62 eV, respectively and the HOMO energy levels of those were 5.83 eV, 5.61 eV and 5.52 eV, respectively. The photovoltaic devices based on the polymers was fabricated. The efficiency of the solar cells based on PM-PPV, PMT-PPV and PMTPA-PPV were 0.028%, 0.031% and 0.11%, respectively and the open circuit voltage (Voc) was 0.59 V~0.69 V under AM 1.5 G and 1 sun condition ($100mA/cm^2$).

• Journal of the Korean Chemical Society
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• v.8 no.4
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• pp.147-152
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• 1964

Vanadium (IV) and vanadium (V) cupferrate compositions in benzene phase were determined by molar ratio method and continuous variation method spectrophotometrically at 450$m{\mu}$ or 445$m{\mu}$ of wavelength. Compositions of vanadium (IV) cupferrates, V(IV)/Cupf, varied from 1/2 to 1/4 with the acidity of solution from which the complexes were precipitated. The complexes precipitated were vanadium(IV) cupferrate($VCupf_4$) in solution with lower pH than 1.0, and vanadyl(IV) cupferrate ($VOCupf_2$) in solution with 1.8-4.3 of pH. It was considered, however, that the complexes in solution with 1.3-1.7 of pH might be hydrogen vanadyl(IV) cupferrate ($HVOCupf_3$) or nearly equimolar mixture of $VCupf_4\;and\;VOCupf_2$ complexes. Vanadium (V) cupferrate composition did not vary with the acidity of solution from which the complexes were precipitated. In solution with lower pH than 1.8, the complex precipitated was hydrogen vanadyl (V) cupferrate, $HVO_2Cupf_2$.

• Animal cells and systems
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• v.15 no.2
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• pp.131-138
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• 2011

Redox regulation is one of the ubiquitous mechanisms to modulate ion channels. We here investigated how 5,5'-dithio-bis (2-nitrobenzoic acid), a cysteine specific oxidizing reagent, modulates $Ca_v3.1$ and $Ca_v3.2$ T-type $Ca^{2+}$ channels expressed in Xenopus oocytes. Application of the reagent inhibited $Ca_v3.1$ and $Ca_v3.2$ currents in a dose-dependent manner. The oxidizing reagent (1 mM) reduced the peak amplitude of $Ca_v3.1$ and $Ca_v3.2$ currents by ~50% over 2-3 minutes and the decreased currents were fully recovered upon washout of it. The reagent slowed the activation and inactivation kinetics of $Ca_v3.1$, $Ca_v3.2$, and $Ca_v3.3$ channel currents. Notably, the reagent positively shifted both activation and steady-state inactivation curves of $Ca_v3.1$, while it did not those of $Ca_v3.2$. Utilizing chimeric channels from $Ca_v3.1$ and $Ca_v3.2$, we localized the domains III and IV of $Ca_v3.1$ responsible for the positive shifts of channel activation and steady-state inactivation. These findings provide hints relevant to the electrophysiological and molecular mechanisms accounting for the oxidative regulation of T-type channels.

• Korean Journal of Plant Resources
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• v.12 no.3
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• pp.171-178
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• 1999

The purpose of this study was to investigate the optimal mixture ratio for the mycelial culture of the Pleurotus ostreatus. The chief cultural media in this study were cotton hull, sawdust and rice straw and the supplemental media were zeolite, corn cob, defatted rice bran, white cotton, tobacco trash powder, rice hull and peat. The results of this study were as follows; the optimal mixture ratio of the chief cultural media were effective in 6 : 3 : 1(V/V, %), and the mycelial growth and density in the supplemental media were considerably better 1% zeolite,3% corn cob, 5% defatted rice bran, 1% white cotton, 1% tobacco trash powder, 7% rice hull in good order. The optimal mixture ratio be to the mixed supplemental media in the chief cultural media were as follows ; 2 : 2(V/V, %) at the conditions of mixed zeolite and corn cob; 3 : 2(V/V, %) at the conditions of mixed defatted rice bran and white cotton; 1 : 3(V/V, %) at the conditions of mixed tobacco trash powder and rice hull. At the conditions of the whole cultural media mixed, the mycelial growth and density were in good conditions ; cotton hull, sawdust, rice straw, zeolite, corn cob, defatted rice bran, white cotton, tobacco trash powder, rice hull, and peat were mixed 43.0 : 17.2 : 25.8 : 2.0 : 2.0 : 3.0 : 2.0 : 1.0 : 3.0 : 1.0 (V/V, %).

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.13 no.2
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• pp.1-4
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• 1977

The author determined the relationship between the hauling veloicty and the hydrodynamic resistance of the sablefish pot shaped conic frustum like, and induced the formulae to determine the diameter of the main line and the net horse power of the pot hauler. The results are summarized as follows: 1. The maximum hydrodynamic resistance (with its weight in water) of the pot T(kg), when the bottom webbing is covered by a cloth to imitate the catches are scattered on the bottom, is eatimated as $$ T=120v^{1.1} (0.3{\leqq}v{\leqq}0.8) $$ where v denotes the hauling velocity of the pot in m/sec. 2. When P. P. 3 strand rope is used as main line, the diameter d(mm)is recommended to satisfy the formula $$ d=72 \frac{D}{H} V^{1.1} where H denotes the depth of the fishing ground and D the intervals of the pots linked to the main in m respectively. 3. The pot hauler must displace the net horse power p(ps) of $$ P= \frac{75}{120} \frac{D}{H} v^{2.1}$$