Abstract
Vanadium (IV) and vanadium (V) cupferrate compositions in benzene phase were determined by molar ratio method and continuous variation method spectrophotometrically at 450$m{\mu}$ or 445$m{\mu}$ of wavelength. Compositions of vanadium (IV) cupferrates, V(IV)/Cupf, varied from 1/2 to 1/4 with the acidity of solution from which the complexes were precipitated. The complexes precipitated were vanadium(IV) cupferrate($VCupf_4$) in solution with lower pH than 1.0, and vanadyl(IV) cupferrate ($VOCupf_2$) in solution with 1.8-4.3 of pH. It was considered, however, that the complexes in solution with 1.3-1.7 of pH might be hydrogen vanadyl(IV) cupferrate ($HVOCupf_3$) or nearly equimolar mixture of $VCupf_4\;and\;VOCupf_2$ complexes. Vanadium (V) cupferrate composition did not vary with the acidity of solution from which the complexes were precipitated. In solution with lower pH than 1.8, the complex precipitated was hydrogen vanadyl (V) cupferrate, $HVO_2Cupf_2$.
有機溶媒(benzene)에 의한 抽出法을 利用하고, 分光光度法에 의한 몰比法과 連續變化法을 써서, V(IV)-cupferrate와 V(V)-cupferrate의 化學沮成이 水溶液相에서 有機溶媒相으로 分配된 다음에도 雙하지 않을 것이라는 假定밑에서, 水溶液의 酸性度에 따르는 cupferrate 錯化合物의 化學組成을 決定하였다. V(IV)-cupferrate의 benzene 溶液에서의 最大吸光波長은 pH에 따라 445$m{\mu}$ 또는 450$m{\mu}$이고, V(V)-cupferrate의 그것은 pH 1.8以下에서는 pH에 無關하게 445$m{\mu}$이었다. V(V)-cupferrate의 化學組成은 沈澱이 形成되는 水溶液의 pH에 따라 다르며, pH 1.0 以下에서는 $VCupf_4$, pH 1.3∼1.7에서는 $HVOCupf_3$ 또는 $VCupf_4$와 $VOCupf_2$의 거의 같은 몰씩으로된 混合物이고, pH 1.8∼4.3에서는 $VOCupf_2$이었다. V(V)-cupferrate의 化學組成은 水溶液의 pH에 따라 變化가 없고, pH 1.8 以下에서는 $HVO_2Cupf_2$이었다.