• Journal of the Korean Applied Science and Technology
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• v.35 no.3
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• pp.731-743
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• 2018

In bio-jet fuel production, selecting operating conditions of hydro-upgrading is of great importance to make iso-Paraffin rich hydrocarbons with carbon distribution including jet fuel range. Herein, iso-Paraffin rich biofuel including jet fuel range hydrocarbons ($C_8-C_{16}$) is produced from simultaneous cracking and isomerization using n-Paraffin rich hydrocarbon derived from hydrotreated vegetable oil over 0.5 wt..% Pt/Zeolite catalyst. We report and analyze the yields and compositions in the produced hydrocarbons affected by various operating conditions, such as reaction temperature, reaction pressure, molar ratio of reactants, and weight hourly space velocity. Aforementioned operating conditions not only can help interpret the reaction dynamics of hydro-upgrading, but also further produce bio jet-fuel after distillation.

• Journal of the Korean Applied Science and Technology
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• v.35 no.3
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• pp.865-875
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• 2018

Selection of optimum reaction conditions during deoxygenation process of palm oil is essential factor to obtain the maximum yield of bio-jet fuel. In this context, the deoxygenation of palm oil was carried out in a fixed bed reactor with an internal diameter of 1 inch loaded with a 1 wt.% $Pt/Al_2O_3$ catalyst. The composition of the organic liquid product(OLP), which can be utilized as a transportation fuel through the upgrading process, was analyzed by a gas chromatography method. The palm oil/hydrogen ratio and hydrogen pressure in the feed affected the decarboxylation(DCB) and hydrodeoxygenation(HDO) reactions, resulting in a change in the composition of the OLP. As the reaction temperature increased, the continuous cracking reaction of the deoxygenation product was promoted and the product composition in the $C_5{\sim}C_{14}$ region was increased. Thus, the results can help to understand the characteristics of deoxidation reaction of palm oil as well as the subsequent process, hydro-upgrading, to obtain the maximum yield of bio-jet fuel.

• International Journal of Highway Engineering
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• v.13 no.4
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• pp.103-115
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• 2011

Concrete slab curls and warps due to the uneven distribution of temperature and moisture and as the result, internal stress develops within the slab. Therefore, environmental loads must be considered in addition to the traffic loads to predict the lifespan of the concrete pavement more accurately. The strength of the concrete slab is gradually decreases to a certain level at which fatigue cracking is generated by the repetitive traffic and environmental loadings. In this study, a new fatigue regression model was developed based on the results from previously performed studies. To verify the model, another laboratory flexural fatigue test program which was not used in the model development, was conducted and compared with the predictions of other existing models. Each fatigue model was applied to analysis logic of cumulative fatigue damage of concrete pavement developed in the study. The sensitivity of cumulative fatigue damage calculated by each model was analyzed for the design factors such as slab thickness, joint spacing, complex modulus of subgrade reaction and the load transfer at joints. As the result, the model developed in this study could reflect environmental loading more reasonably by improving other existing models which consider R, minimum/maximum stress ratio.

• International Journal of Highway Engineering
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• v.13 no.4
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• pp.117-122
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• 2011

Asphalt concrete pavement can be widely seen on urban streets, highways, parking lots, and bike trails. Asphalt concrete pavement is relatively temperature sensitive materials due to the viscoelastic behavior, which can be defined as flexible performance in summer and rigid performance in winter. In terms of maintenance, it can be fixed quite easily if damaged. In addition, asphalt concrete pavement is generally found to be black and grey in color. However, several colors can be adopted to change the appearance of plain old boring, black and grey. Generally, there are two types of color systems in hot mix asphalt concrete materials. One system uses colored cementitious material that is applied to pavement surface through coating the surface of the asphalt pavement. The major disadvantage to this system requires a careful skill set to be used on the construction site in order to prevent taking off the cementitious material. The other coloring system colors the asphalt hot mixtures through using color additives. The main advantage to this system is that the asphalt pavement layer is colored using the same techniques that are already used in paving. The disadvantage is that the colors are limited to mainly reds and browns. In this study, a suggested color additive was evaluated, based on rutting, moisture sensitivity, and fatigue cracking performance.

• International Journal of Highway Engineering
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• v.13 no.4
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• pp.81-91
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• 2011

This study was conducted to evaluate the necessity of the anchor lug system in continuously reinforced concrete pavement(CRCP) by comparing longitudinal displacements of CRCPs with and without anchor lugs, and to investigate the effect of horizontal cracking on CRCP performance by measuring the vertical displacements. The measurements before and after the anchor lug section was separated were conducted for 12 days in June, and for 14 days in August after the abrupt displacements according to cutting disappeared, respectively. This short term measurement results showed that when anchor lugs were installed, a daily displacement variation at any location was less than 0.1mm; therefore, longitudinal movements were negligibly small. When there were no anchor lugs, longitudinal displacements mainly occurred near the free end and the displacement variation was small; therefore, an expansion joint system seems to be employed at a CRCP terminus without installing anchor lugs. However, further studies are needed to verify the terminus behavior due to annual temperature changes. The horizontal crack width variation was ignorable and did not affect the vertical displacement of the slab. Therefore, the horizontal crack did not delaminate the slab and did not seem to reduce the structural capacity and performance of CRCP.

• International Journal of Highway Engineering
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• v.13 no.4
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• pp.51-59
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• 2011

Tensile stress occurs and random crack develops in concrete pavement slab when it contracts by variation of temperature and humidity. The tensile stress decreases and the random crack is minimized by sawcutting the slab and inducing the crack with regular spacing. The random crack, joint damage, decrease of load transfer efficiency are caused by too wide joint spacing while too narrow joint spacing leads to increase of construction cost and decrease of comfort. A mechanistic-empirical joint spacing design method for the concrete pavement was developed in this study. Structurally and environmentally weakest sections were found among the sections showing good performance, and design strengths were determined by finite element analysis on the sections. The joint width for which the load transfer efficiency is suddenly lowered was determined as allowable joint with referring to existing research results. The maximum joint spacing for which the maximum tensile stress calculated by the finite element analysis did not exceed the design strength were found. And the maximum joint width expected by the maximum joint spacing were compared to the allowable joint width. The new method developed in this study was applied to two zones of Hamyang-Woolsan Expressway being designed. The same joint spacing as a test section constructed by 8.0m of joint spacing wider than usual was calculated by the design method. Very low cracking measured at 6 years after opening of the test section verified the design method developed in this study.

• Applied Chemistry for Engineering
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• v.27 no.3
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• pp.227-238
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• 2016

This review article highlights different types of nano-sized catalysts for the selective alcohol oxidation to form aldehydes (or ketones) with supported or immobilized metal nanoparticles. Metal nanoparticle catalysts are obtained through dispersing metal nanoparticles over a solid support with a large surface area. The nanocatalysts have wide technological applications to industrial and academic fields such as organic synthesis, fuel cells, biodiesel production, oil cracking, energy conversion and storage, medicine, water treatment, solid rocket propellants, chemicals and dyes. One of main reactions for the nanocatalyst is an aerobic oxidation of alcohols to produce important intermediates for various applications. The oxidation of alcohols by supported nanocatalysts including gold, palladium, ruthenium, and vanadium is very economical, green and environmentally benign reaction leading to decrease byproducts and reduce the cost of reagents as opposed to stoichiometric reactions. In addition, the room temperature alcohol oxidation using nanocatalysts is introduced.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.4
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• pp.164-172
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• 2020

The fuel oil/heat exchanger installed in military aircraft is a device that cools the lubricant oil supplied to other devices, such as an AMAD, and a hydraulic pump using the low temperature of the fuel is cracked at the AMAD lubricant inlet port. If a crack in the heat exchanger occurs, the lubricant oil supplied to other equipment is not cooled. Therefore, the flight can no longer be performed. In this study, non-destructive inspection and microscopic examination of the fracture surface of the oil port were performed to analyze the crack tendency. The oil pipe connected to the oil port is a titanium pipe, which is fastened with over torque and has been identified as the leading cause of heat exchanger oil port cracks. In addition, it was verified as the main reason for cracking by finite element analysis. The material and diameter of the pipe were changed to improve this defect, and the applied torque was adjusted. In addition, the bending value of the pipe was adjusted to minimize the fatigue accumulation due to pulsating pressure. As a result, no cracks occurred on the heat exchanger via the ground test after the installation of an improved pipe under the same conditions.

• International Journal of Highway Engineering
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• v.20 no.1
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• pp.47-58
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• 2018

PURPOSES : The purpose of this study is to evaluate the mechanical properties of a cold-recycling asphalt mixture used as a base layer and to determine the optimum emulsified-asphalt content for ensuring the mixture's performance. METHODS : The physical properties (storage stability, mixability, and workability) of three types of asphalt emulsion (CMS-1h, CSS-1h, and CSS-1hp) were evaluated using the rotational viscosity test. Asphalt emulsion residues, prepared according to the ASTM D 7497-09 standard, were evaluated for their rheological properties, including the $G*/sin{\delta}$and the dynamic shear modulus (${\mid}G*{\mid}$). In addition, the Marshall stability, indirect tensile strength, and tensile-strength ratio (TSR) were evaluated for the cold-recycling asphalt mixtures fabricated according to the type and contents of the emulsified asphalt. RESULTS : The CSS-1hp was found to be superior to the other two types in terms of storage stability, mixability, and workability, and its $G*/sin{\delta}$ value at high temperatures was higher than that of the other two types. From the dynamic shear modulus test, the CSS-1hp was also found to be superior to the other two types, with respect to low-temperature cracking and rutting resistance. The mixture test indicated that the indirect tensile strength and TSR increased with the increasing emulsified-asphalt content. However, the mixtures with one-percent emulsified-asphalt content did not meet the national specification in terms of the aggregate coverage (over 50%) and the indirect tensile strength (more than 0.4 MPa). CONCLUSIONS : The emulsified-asphalt performance varied greatly, depending on the type of base material and modifying additives; therefore, it is considered that this will have a great effect on the performance of the cold-recycling asphalt pavement. As the emulsified-asphalt content increased, the strength change was significant. Therefore, it is desirable to apply the strength properties as a factor for determining the optimum emulsified-asphalt content in the mix design. The 1% emulsified-asphalt content did not satisfy the strength and aggregate coverage criteria suggested by national standards. Therefore, the minimum emulsified-asphalt content should be specified to secure the performance.

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.1
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• pp.6-12
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• 2018

Recently, The use of the curtain wall method is increasing in construction. The curtain wall construction is widely applied to the exterior wall of the building for shortening construction period and economical efficiency. However, the replacement of deterioration of the weather resistance and structural behavior of the sealing material connecting the curtain wall method and the glass frame is necessary for introduction of the stable curtain wall method and quality improvement in accordance with KS F 4910 standard. In this study, the elastic restoring force test was performed in the external environment. In this study, the deterioration of the sealant was evaluated for structural sealants. In Korea, studies on the variable displacement behavior of structural sealants are lacked. In this study, the reproduced results in laboratory conditions are compared with the deteriorating conditions exposed to the external environment, and they are reflected in the design of sealing materials in the future. According to the results of the study, it was confirmed that the existing structure sealant meets the quality standard of KS F 4910, but in the conditions performed in this study, adhesion failure of the specimen and cracking of the surface occurred. Especially, in the weather resistance test, it is necessary to evaluate the long-term durability performance of the structural sealant used in the curtain wall method by checking the insoluble state of all the test pieces. Therefore, in order to apply a conventional structural sealant to the site, it is necessary to introduce another durability performance evaluation.