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http://dx.doi.org/10.12925/jkocs.2018.35.3.865

Effects of reaction conditions on composition of the organic liquid product during the deoxygenation process of palm oil  

Kim, Sungtak (Plant Engineering Division, Institute for Advanced Engineering (IAE))
Jang, Jeong Hee (Plant Engineering Division, Institute for Advanced Engineering (IAE))
Ahn, Minhwei (Plant Engineering Division, Institute for Advanced Engineering (IAE))
Kwak, Yeonsu (Plant Engineering Division, Institute for Advanced Engineering (IAE))
Han, Gi Bo (Plant Engineering Division, Institute for Advanced Engineering (IAE))
Jeong, Byung Hun (Advanced Propulsion Technology Center, Agency for Defense Development)
Han, Jeong Sik (Advanced Propulsion Technology Center, Agency for Defense Development)
Kim, Jae-Kon (Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority)
Publication Information
Journal of the Korean Applied Science and Technology / v.35, no.3, 2018 , pp. 865-875 More about this Journal
Abstract
Selection of optimum reaction conditions during deoxygenation process of palm oil is essential factor to obtain the maximum yield of bio-jet fuel. In this context, the deoxygenation of palm oil was carried out in a fixed bed reactor with an internal diameter of 1 inch loaded with a 1 wt.% $Pt/Al_2O_3$ catalyst. The composition of the organic liquid product(OLP), which can be utilized as a transportation fuel through the upgrading process, was analyzed by a gas chromatography method. The palm oil/hydrogen ratio and hydrogen pressure in the feed affected the decarboxylation(DCB) and hydrodeoxygenation(HDO) reactions, resulting in a change in the composition of the OLP. As the reaction temperature increased, the continuous cracking reaction of the deoxygenation product was promoted and the product composition in the $C_5{\sim}C_{14}$ region was increased. Thus, the results can help to understand the characteristics of deoxidation reaction of palm oil as well as the subsequent process, hydro-upgrading, to obtain the maximum yield of bio-jet fuel.
Keywords
Bio jet fuel; vegetable oil; Hydrodeoxygenation; reaction conditions; $Pt/Al_2O_3$;
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