• Title/Summary/Keyword: Secondary batteries

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Electrochemical Properties of LiNiO$_2$/Li cell (LiNiO$_2$/Li cell의 전기화학적 특성)

  • 전대규;김철중;성창호;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.279-282
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    • 1997
  • The propose of this study is research and improvement of LiNiO$_2$as cathode material for Lithium secondary batteries. LiNiO$_2$is prepared by heating LiOH . $H_2O$ and Ni(OH)$_2$(mole ratio 1 : 1) on various heat condition. In the result of XRD mesurement, all LiNiO$_2$prepared at this study showed hexagonal structure. In Cyclic Voltammetry, LiNiO$_2$is not conspicous about oxidation peak but oxidation curve change steeply over 3.8V and reduction peak discover at 3.6V. In discharge capacities, specific capacity is higher $O_2$than air when preliminary heated and 75$0^{\circ}C$ than $700^{\circ}C$, 80$0^{\circ}C$ when heated. Therefore, when preliminary heat at $650^{\circ}C$ $O_2$and heat at 75$0^{\circ}C$ carried out, discharge property is the best.

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Probing of Electrochemical Reactions for Battery Applications by Atomic Force Microscopy

  • Kim, Yun-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.98.2-98.2
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    • 2013
  • Electrochemical phenomena underpin a broad spectrum of energy, chemical, and information technologies such as resistive memories and secondary batteries. The optimization of functionalities in these devices requires understanding electrochemical mechanisms on the nanoscale. Even though the nanoscale electrochemical phenomena have been studied by electron microscopies, these methods are limited for analyzing dynamic electrochemical behavior and there is still lack of information on the nanoscale electrochemical mechanisms. The alternative way can be an atomic force microscopy (AFM) because AFM allows nanoscale measurements and, furthermore, electrochemical reaction can be controlled by an application of electric field through AFM tip. Here, I will summarize recent studies to probe nanoscale electrochemical reaction in battery applications by AFM. In particular, we have recently developed electromechanical based AFM techniques for exploring reversible and irreversible electrochemical phenomena on the nanoscale. The present work suggests new strategies to explore fundamental electrochemical mechanisms using the AFM approach and eventually will provide a powerful paradigm for probing spatially resolved electrochemical information for energy applications.

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THE SOC ESTIMATION OF THE LEAD-ACID BATTERY USING KALMAN FILTER

  • JEON, YONGHO
    • Journal of applied mathematics & informatics
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    • v.39 no.5_6
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    • pp.851-858
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    • 2021
  • In general, secondary batteries are widely used as an electric energy source. Among them, the state of energy storage of mobile devices is very important information. As a method of estimating a state, there is a method of estimating the state by integrating the current according to an energy storage state of a battery, and a method of designing a state estimator by measuring a voltage and estimating a charge amount based on a battery model. In this study, we designed the state estimator using an extended Kalman filter to increase the precision of the state estimation of the charge amount by including the error of the system model and having the robustness to the noise.

Various Alcohols as Electrolysis Suppressants in Zn-air Secondary Batteries

  • Yang, Soyoung;Kim, Ketack
    • Journal of Electrochemical Science and Technology
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    • v.9 no.4
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    • pp.339-344
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    • 2018
  • The gelling agent used in Zn-air cells plays a role in improving battery life. It prevents the evaporation of water and diffusion of $Zn^{2+}$ ions away from the current collector. Additional functionality was incorporated by replacing some of the gelling agents with new materials. Alcohols with moderate viscosity, namely maltose, sucrose, poly ethylene glycol 600, and 2-hydroxyethyl cellulose, were used to replace some gelling agents in this work. Among these alcohols, poly ethylene glycol 600 and 2-hydroxyethyl cellulose improved the cycle life of full cells. This improved cycle life was attributed to the inhibition of water electrolysis and the improved cycle life of the anode.

Design of Charge and Discharge System for Secondary Batteries (2차 전지용 충방전 시스템 설계)

  • Shim, Jae-Hwe;Lee, Jun-Ha
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2009.10a
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    • pp.690-691
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    • 2009
  • This study intends to discuss the Charge and Discharge Monitoring System for HEV. Study is aim to charge and discharge stability and efficient. This study is include hardware module and application software development. It is possible to maintain charge and discharge performance efficiently.

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Study on the preparation of electrochemical exfoliated graphene/Fe oxide compound according to synthetic conditions (합성 조건 변화에 따른 전기화학적 박리 그래핀/철 산화물 복합체 제조 연구)

  • Park, Eunjin;Kim, Yong-Tae;Choi, Jinsub
    • Journal of the Korean institute of surface engineering
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    • v.55 no.2
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    • pp.84-90
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    • 2022
  • With the growing interest in energy storage and conversion systems including secondary batteries, capacitors, and water electrolysis, various electrode materials are being developed to improve the energy efficiency. Among them, graphene is regarded as one of the promising candidates owing to its exceptional properties - large surface area, and excellent electrical conductivity. Herein, we report a facile one-step electrochemical approach to synthesize exfoliated graphene/Fe oxide compound. The effect of experimental conditions - the types of applied voltage, kinds of counter electrodes, acidity of electrolyte on the synthesis of graphene/Fe oxide compound is investigated.

Development of Battery Temperature Monitoring and Simulation System for Aging Method of Lithium-ion Battery for Electric Vehicles (전기차 리튬이온 배터리의 에이징 공법을 위한 배터리 온도 모니터링 및 시뮬레이션 시스템 개발)

  • Jeong, He-min;Hong, Seong-Wung
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2022.07a
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    • pp.149-152
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    • 2022
  • 최근 전기차의 기술 발전이 급속도로 증가함에 따라 이차전지의 수요가 증가하게 되었다. 그로인해 다량의 고품질 전지를 생산하기 위해 제조 공장이 가동되고 있지만 생산된 전지의 품질의 핵심이 되는 화성공정의 에이징 과정 진행 중 온도 관리에 실패할 경우, 전지의 폭발 및 화재의 위험이 있다. 본 논문은 이차전지를 생산하는 에이징 공정의 효율적인 온도 관리를 위해 목업 모형을 만들어 온도 센서를 통한 온도 수집 및 모니터링 시스템을 개발하고, 공조기 바람을 통해 전지의 온도가 변화하는 속도를 계산하고, 이상온도에 도달해 고온의 상태가 되었을 경우 주변 전지로 전달되는 열을 시뮬레이션 통한 효율적인 공조 대책을 제시하여 이차전지 생산의 품질 향상과 화재 예방을 통해 전기차 생산에 따른 리튬이온 전지의 수요 해결에 기여한다.

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Geometrical Defect Detection of Secondary Battery Using 3-Dimensional CAD Model (3D CAD 모델을 이용한 이차 전지의 형상 결함 검출)

  • Yeong-Ho Jo;Keun-Ho Rew;Sang-Yul Lee
    • Journal of Information Technology Applications and Management
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    • v.29 no.6
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    • pp.135-144
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    • 2022
  • In this study, we transformed 4680 type lithium-ion batteries to 3-dimensional CAD models and present a methodology to detect defects using Radon inverse transformation. Transparency was applied to the model to make it look like a CT image when viewed from the front. One normal and three defect models were created and analyzed. The models were saved as image files while rotating at a certain angle. Then, we used the Radon inverse transformation to reconstruct the original 3D geometry from the image files. Finally, we successfully found defects in the defect models for three cases.

Characterization of Compacted and Pressureless Sintered Parts for Molybdenum Oxide Powder according to Hydrogen Reduction Temperature (수소 환원 온도에 따른 몰리브덴 산화물의 성형 및 상압소결특성 평가)

  • Jong Hoon Lee;Kun-Jae Lee
    • Journal of Powder Materials
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    • v.31 no.4
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    • pp.336-341
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    • 2024
  • Molybdenum, valued for its high melting point and exceptional physical and chemical properties, is studied in diverse fields such as electronics, petrochemicals, and aviation. Among molybdenum oxides, molybdenum dioxide stands out for its higher electrical conductivity than other transition metal oxides due to its structural characteristics, exhibiting metallic properties. It is applied as pellets to gas sensors, semiconductors, and secondary batteries for its properties. Thus, research on molybdenum dioxide compaction and pressureless sintering is necessary, yet research on pressureless sintering is currently insufficient. This study synthesized MoO3 powder via solution combustion synthesis and reduced it using the 3% hydrogen/argon gas mixture to investigate the effect of reduction temperature on the powder. Additionally, the reduced powder was compacted and subjected to pressureless sintering with temperature as a variable. The density and the microstructure of brown parts were analyzed and discussed.

Microstructure analysis of 8 ㎛ electrolytic Cu foil in plane view using EBSD and TEM

  • Myeongjin Kim;Hyun Soon Park
    • Applied Microscopy
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    • v.52
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    • pp.2.1-2.6
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    • 2022
  • With the lightening of the mobile devices, thinning of electrolytic copper foil, which is mainly used as an anode collection of lithium secondary batteries, is needed. As the copper foil becomes ultrathin, mechanical properties such as deterioration of elongation rate and tear phenomenon are occurring, which is closely related to microstructure. However, there is a problem that it is not easy to prepare and observe specimens in the analysis of the microstructure of ultrathin copper foil. In this study, electron backscatter diffraction (EBSD) specimens were fabricated using only mechanical polishing to analyze the microstructure of 8 ㎛ thick electrolytic copper foil in plane view. In addition, EBSD maps and transmission electron microscopy (TEM) images were compared and analyzed to find the optimal cleanup technique for properly correcting errors in EBSD maps.