Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference (한국전기전자재료학회:학술대회논문집)

The Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회)
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Electrochemical Properties of LiNiO$_2$/Li cell

LiNiO$_2$/Li cell의 전기화학적 특성

  • 전대규 (전남대학교 전기공학과) ;
  • 김철중 (전남대학교 전기공학과) ;
  • 성창호 (전남대학교 전기공학과) ;
  • 구할본 (전남대학교 전기공학과)
  • Published : 1997.11.01
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Abstract

The propose of this study is research and improvement of LiNiO$_2$as cathode material for Lithium secondary batteries. LiNiO$_2$is prepared by heating LiOH . $H_2O$ and Ni(OH)$_2$(mole ratio 1 : 1) on various heat condition. In the result of XRD mesurement, all LiNiO$_2$prepared at this study showed hexagonal structure. In Cyclic Voltammetry, LiNiO$_2$is not conspicous about oxidation peak but oxidation curve change steeply over 3.8V and reduction peak discover at 3.6V. In discharge capacities, specific capacity is higher $O_2$than air when preliminary heated and 75$0^{\circ}C$ than $700^{\circ}C$, 80$0^{\circ}C$ when heated. Therefore, when preliminary heat at $650^{\circ}C$ $O_2$and heat at 75$0^{\circ}C$ carried out, discharge property is the best.

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