• Title/Summary/Keyword: Radical

Search Result 10,298, Processing Time 0.032 seconds

New Radical Allylation Reactions Using 2-Bromo-3-(phenylthio)propene and Their Application to the Synthesis of Carbocyclic Compounds

  • 유병우;Dennis P. Curran
    • Bulletin of the Korean Chemical Society
    • /
    • v.17 no.11
    • /
    • pp.1009-1018
    • /
    • 1996
  • A study on the application of vinyl radical cyclization via free radical allylation reaction in the synthesis of various carbocyclic compounds is described. In connection with this study, a new allyl transfer reagent, 2-bromo-3-(phenylthio)propene 1 is developed and it was shown that vinyl radical cyclization through free radical allylation reaction using reagent 1 provides a valuable approach to carbocyclic systems with a reactive exo-alkylidene moiety, which is advantageous for further transformations.

LOWER RADICALS OF Γ-RINGS

  • Le Roux, H.J.
    • Kyungpook Mathematical Journal
    • /
    • v.27 no.2
    • /
    • pp.191-195
    • /
    • 1987
  • In this note we introduce the concept of a lower radical for ${\Gamma}$-rings. As an application we also characterise the prime radical introduced by Barnes [1] as a lower radical. Furthermore it is shown that the prime radical can also be determined by the class of all semiprime ${\Gamma}$-rings.

  • PDF

THE STRUCTURE OF THE RADICAL OF THE NON SEMISIMPLE GROUP RINGS

  • Yoo, Won Sok
    • Korean Journal of Mathematics
    • /
    • v.18 no.1
    • /
    • pp.97-103
    • /
    • 2010
  • It is well known that the group ring K[G] has the nontrivial Jacobson radical if K is a field of characteristic p and G is a finite group of which order is divided by a prime p. This paper is concerned with the structure of the Jacobson radical of such a group ring.

ON THE RANGE OF DERIVATIONS

  • Chang, Ick-Soon
    • Journal of the Chungcheong Mathematical Society
    • /
    • v.12 no.1
    • /
    • pp.187-191
    • /
    • 1999
  • In this paper we will show that if [G(y), x]D(x) lies in the nil radical of A for all $x{\in}A$, then GD maps A into the radical, where D and G are derivations on a Banach algebra A.

  • PDF

RADICALS AND HOMOMORPHIC IMAGES OF ${C^*}$-ALGEBRAS

  • Han, Hyuk
    • Communications of the Korean Mathematical Society
    • /
    • v.14 no.2
    • /
    • pp.365-371
    • /
    • 1999
  • In this paper, we prove that the range of homomorphism from a C\ulcorner-algebra A into a commutative Banach algebra B whose radical is nil contains no non-zero element of the radical of B. Using this result we show that there is no non-zero homomorphism from a C\ulcorner-algebra into a commutative radical nil Banach algebra.

  • PDF

RESULTS ON THE RANGE OF DERIVATIONS

  • Jung, Yong-Soo
    • Bulletin of the Korean Mathematical Society
    • /
    • v.37 no.2
    • /
    • pp.265-272
    • /
    • 2000
  • Let D be a derivation on an Banach algebra A. Suppose that [[D(x), x], D(x)] lies in the nil radical of A for all $x{\;}{\in}{\;}A$. Then D(A) is contained in the Jacobson radical of A.

  • PDF

The radical bromination reaction of ethylenecarbonate

  • Moon, Do-Won
    • Archives of Pharmacal Research
    • /
    • v.6 no.1
    • /
    • pp.1-6
    • /
    • 1983
  • The reaction of ethylenecarbonate (I) with bromine was carried out in the presence of benzolperoxide as radical initiator. The following several different esters being ring opened were obtained; bromoacetyl-bromoformate, (1-hyroxy, 1, 2-dibromo)-ethyl bromoformate, (1-hydroxy, 1, 2, 2'-tribromo)diethylacarbonate, 2-bromoethyl-tribromoacetate, (1-acetoxy, 1'-bromomethyl)-bromomalo nate, 2-bromoethyl-bromoacetoxy-tribromoacetate.

  • PDF

Antioxidative activities of Artemisia capillaris-Fermented Hericium erinaceum Mycelium (인진쑥 노루궁뎅이 버섯균사체 발효물의 항산화 활성)

  • Kim, Seung-Sub;Kyeong, Inn-Goo;Lee, Mi-La;Kim, Dong-Goo;Shin, Ji-Young;Yang, Jin-Yi;Lee, Gwang-Ho;Eum, Won-Sik;Kang, Jung-Hoon
    • Journal of the Korean Applied Science and Technology
    • /
    • v.31 no.4
    • /
    • pp.719-730
    • /
    • 2014
  • The hot water extract from Artemisia capillaris fermented with Hericium erinaceum mycelium (AC-HE) were assessed for the protection against oxidative modification of biological macromolecules and cell death. Antioxidant activity of AC-HE evaluated using 2,2-diphenyl-1-picrylhydrazyl radical, 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) radical and peroxyl radical scavenging assays. AC-HE showed 61.73% DPPH radical scavenging activity at $500{\mu}g/mL$, 97.39% ABTS radical scavenging activity at $250{\mu}g/mL$, and 44.18% peroxyl radical scavenging activity at $100{\mu}g/mL$. AC-HE were shown to significantly inhibited DNA strand breakage induced by peroxyl radical. AC-HE also prevented peroxyl radical-mediated human serum albumin modification. AC-HE effectively inhibited $H_2O_2$ induced cell death and significantly increased of the 11.47% cell survival at $100{\mu}g/mL$. AC-HE also decreased intracellular reactive oxygen species (ROS) levels in $H_2O_2$-treated cells. The results suggested that AC-HE can contribute to antioxidant and protected cells from oxidative stress-induced cell injury.

Radical Scavenging Activity of Ethanol Extracts and Solvent Partitioned Fractions from Various Red Seaweeds (홍조류 에탄올 추출물 및 다양한 용매 분획물의 라디칼 소거능)

  • Cho, MyoungLae;Lee, Dong-Jin;You, SangGuan
    • Ocean and Polar Research
    • /
    • v.34 no.4
    • /
    • pp.445-451
    • /
    • 2012
  • The EtOH extracts of red seaweeds (Symphyocladia latiuscula, Chondrus ocellatus and Carpopeltis affinis) and solvent partitioned fractions were investigated for their 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulphonic acid) (ABTS) and 1,1-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging effects and the total phenolic contents were correlated with ABTS and DPPH radical scavenging activities. The EtOH extracts and their solvent partitioned fractions exhibited strong ABTS and DPPH radical scavenging activities. Among the solvent partitioned fractions obtained from n-Hexane (HX), methylenchloride (MC), ethylacetate (EA), and buthanol (BuOH), the HX fraction from C. affinis showed higher radical scavenging activities than other fractions. Total phenolic contents showed significant correlation ($r^2$ = 0.709) with ABTS radical scavenging activity. The results of this study suggest that the strong radical scavenging activity of HX fraction from C. affinis is a promising natural antioxidant for healthcare products.