• 제목/요약/키워드: Q-matrix

검색결과 292건 처리시간 0.025초

Errors in Isotope Dilution Caused by Matrix-induced Mass Bias Effect in Quadrupole Inductively Coupled Plasma-Mass Spectrometry

  • Pak, Yong-Nam
    • Bulletin of the Korean Chemical Society
    • /
    • 제35권12호
    • /
    • pp.3482-3488
    • /
    • 2014
  • Matrix-induced mass bias and its effect on the accuracy of isotope ratio measurements have been examined for a quadrupole-based inductively coupled plasma-mass spectrometer (Q ICP-MS). Matrix-induced mass bias effect was directly proportional to % mass difference, and its magnitude varied for element and nebulizer flow rate. For a given element and conditions in a day, the effect was consistent. The isotope ratio of Cd106/Cd114 under $200{\mu}g\;g^{-1}$ U matrix deviated from the natural value significantly by 3.5%. When Cd 111 and Cd114 were used for the quantification of Cd with isotope dilution (ID) method, the average of differences between the calculated and measured concentrations was -0.034% for samples without matrix ($0.076{\mu}g\;g^{-1}$ to $0.21{\mu}g\;g^{-1}$ for the period of 6 months). However, the error was as large as 1.5% for samples with $200{\mu}g\;g^{-1}$ U. The error in ID caused by matrix could be larger when larger mass difference isotopes are used.

Dependency of the Critical Carbon Content of Electrical Conductivity for Carbon Powder-Filled Polymer Matrix Composites

  • Shin, Soon-Gi
    • 한국재료학회지
    • /
    • 제25권8호
    • /
    • pp.365-369
    • /
    • 2015
  • This paper investigates the dependency of the critical content for electrical conductivity of carbon powder-filled polymer matrix composites with different matrixes as a function of the carbon powder content (volume fraction) to find the break point of the relationships between the carbon powder content and the electrical conductivity. The electrical conductivity jumps by as much as ten orders of magnitude at the break point. The critical carbon powder content corresponding to the break point in electrical conductivity varies according to the matrix species and tends to increase with an increase in the surface tension of the matrix. In order to explain the dependency of the critical carbon content on the matrix species, a simple equation (${V_c}^*=[1+ 3({{\gamma}_c}^{1/2}-{{\gamma}_m}^{1/2})^2/({\Delta}q_cR]^{-1}$) was derived under some assumptions, the most important of which was that when the interfacial excess energy introduced by particles of carbon powder into the matrix reaches a universal value (${\Delta}q_c$), the particles of carbon powder begin to coagulate so as to avoid any further increase in the energy and to form networks that facilitate electrical conduction. The equation well explains the dependency through surface tension, surface tensions between the particles of carbon powder.

ALMOST EINSTEIN MANIFOLDS WITH CIRCULANT STRUCTURES

  • Dokuzova, Iva
    • 대한수학회지
    • /
    • 제54권5호
    • /
    • pp.1441-1456
    • /
    • 2017
  • We consider a 3-dimensional Riemannian manifold M with a circulant metric g and a circulant structure q satisfying $q^3=id$. The structure q is compatible with g such that an isometry is induced in any tangent space of M. We introduce three classes of such manifolds. Two of them are determined by special properties of the curvature tensor. The third class is composed by manifolds whose structure q is parallel with respect to the Levi-Civita connection of g. We obtain some curvature properties of these manifolds (M, g, q) and give some explicit examples of such manifolds.

Protective effects of quercetin-3-glucosyl-(1-2)-rhamnoside from Schizophragma hydrangeoides leaves on ultraviolet A-induced photoaging in human dermal fibroblasts

  • So Yeon Oh;Sung Chun Kim;Ho Bong Hyun;Hyejin Hyeon;Boram Go;Yong-Hwan Jung;Young-Min Ham
    • Journal of Applied Biological Chemistry
    • /
    • 제65권4호
    • /
    • pp.277-286
    • /
    • 2022
  • Schizophragma hydrangeoides (S. hydrangeoides) is a vine endogenous to Jeju Island and Ulleungdo, where it grows attached to the foothills and rock surfaces. Previous research has mostly focused on the whitening effect of S. hydrangeoides leaf extract. In this study, we investigated S. hydrangeoides leaf extract further, and detected four phytochemicals in the extract: chlorogenic acid, quercetin-3-O-glucosyl-(1-2)-rhamnoside, quercetin-3-O-xylosyl-(1-2)-rhamnoside, and quercitrin. We pretreated human dermal fibroblast (HDFn) cells with previously established concentrations of the four compounds for 1 h before ultraviolet A (UVA) irradiation. Among the four compounds, quercetin-3-O-glucosyl-(1-2)-rhamnoside (Q-3-GR) best inhibited matrix metalloproteinase-1 (MMP-1) levels. Thus, we investigated the protective effects of Q-3-GR on photoaging and its underlying mechanisms. Q-3-GR significantly reduced MMP-1 production and inhibited MMP-1 protein expression in UVA-irradiated HDFn cells. Furthermore, Q-3-GR increased procollagen type I production and protein expression. Q-3-GR exerted its anti-photoaging effects by downregulating the mitogen-activated protein kinase/ activator protein-1 signaling pathway, and upregulating the transforming growth factor-β/Smad signaling pathway. Thus, S. hydrangeoides leaf-derived Q-3-GR is a potential potent cosmetic ingredient for UV-induced skin aging.

THE EXISTENCE THEOREM OF ORTHOGONAL MATRICES WITH p NONZERO ENTRIES

  • CHEON, GI-SANG;LEE, SANG-GU;SONG, SEOK-ZUN
    • Journal of the Korean Society for Industrial and Applied Mathematics
    • /
    • 제4권1호
    • /
    • pp.109-119
    • /
    • 2000
  • It was shown that if Q is a fully indecomposable $n{\times}n$ orthogonal matrix then Q has at least 4n-4 nonzero entries in 1993. In this paper, we show that for each integer p with $4n-4{\leq}p{\leq}n^2$, there exist a fully indecomposable $n{\times}n$ orthogonal matrix with exactly p nonzero entries. Furthermore, we obtain a method of construction of a fully indecomposable $n{\times}n$ orthogonal matrix which has exactly 4n-4 nonzero entries. This is a part of the study in sparse matrices.

  • PDF

CONVERGENCE OF NEWTON'S METHOD FOR SOLVING A NONLINEAR MATRIX EQUATION

  • Meng, Jie;Lee, Hyun-Jung;Kim, Hyun-Min
    • East Asian mathematical journal
    • /
    • 제32권1호
    • /
    • pp.13-25
    • /
    • 2016
  • We consider the nonlinear matrix equation $X^p+AX^qB+CXD+E=0$, where p and q are positive integers, A, B and E are $n{\times}n$ nonnegative matrices, C and D are arbitrary $n{\times}n$ real matrices. A sufficient condition for the existence of the elementwise minimal nonnegative solution is derived. The monotone convergence of Newton's method for solving the equation is considered. Several numerical examples to show the efficiency of the proposed Newton's method are presented.

유한요소법의 정도수렴 (The Convergence of Accuracy Ratio in Finite Element Method)

  • 조순보
    • 한국공간구조학회논문집
    • /
    • 제3권2호
    • /
    • pp.85-90
    • /
    • 2003
  • If we use a third order approximation for the displacement function of beam element in finite element methods, finite element solutions of beams yield nodal displacement values matching to beam theory results to have no connection with the number increasing of elements of beams. It is assumed that, as the member displacement value at beam nodes are correct, the calculation procedure of beam element stiffness matrix have no numerical errors. A the member forces are calculated by the equations of $\frac{-M}{EI}=\frac{{d^2}{\omega}}{dx^2}\;and\;\frac{dM}{dx}=V$, the member forces at nodes of beams have errors in a moment and a shear magnitudes in the case of smaller number of element. The nodal displacement value of plate subject to the lateral load converge to the exact values according to the increase of the number of the element. So it is assumed that the procedures of plate element stiffness matrix calculations has a error in the fundamental assumptions. The beam methods for the high accuracy ratio solution Is also applied to the plate analysis. The method of reducing a error ratio of member forces and element stiffness matrix in the finite element methods is studied. Results of study were as follows. 1. The matrixes of EI[B] and [K] in the equations of M(x)=EI[B]{q} and M(x) = [K]{q}+{Q} of beams are same. 2. The equations of $\frac{-M}{EI}=\frac{{d^2}{\omega}}{dx^2}\;and\;\frac{dM}{dx}=V$ for the member forces have a error ratio in a finite element method of uniformly loaded structures, so equilibrium node loads {Q} must be substituted in the equation of member forces as the numerical examples of this paper revealed.

  • PDF

A p-DEFORMED q-INVERSE PAIR AND ASSOCIATED POLYNOMIALS INCLUDING ASKEY SCHEME

  • Savalia, Rajesh V.
    • 대한수학회논문집
    • /
    • 제34권4호
    • /
    • pp.1175-1199
    • /
    • 2019
  • We construct a general bi-basic inverse series relation which provides extension to several q-polynomials including the Askey-Wilson polynomials and the q-Racah polynomials. We introduce a general class of polynomials suggested by this general inverse pair which would unify certain polynomials such as the q-extended Jacobi polynomials and q-Konhauser polynomials. We then emphasize on applications of the general inverse pair and obtain the generating function relations, summation formulas involving the associated polynomials and derive the p-deformation of some of the q-analogues of Riordan's classes of inverse series relations. We also illustrate the companion matrix corresponding to the general class of polynomials; this is followed by a chart showing the reducibility of the extended p-deformed Askey-Wilson polynomials as well as the extended p-deformed q-Racah polynomials.

환경영향평가에서의 평가항목간 상호연계성에 관한 연구 (Study on the Interrelationship among the Environmental Factors in Environmental Impact Assessment)

  • 강명휘;이무춘
    • 환경영향평가
    • /
    • 제8권3호
    • /
    • pp.49-59
    • /
    • 1999
  • In this study, we individualize the clauses to sort out the troubled ones, draw up a interrelation model in order to visually organize the relations, and finally, suggest the desirable application idea. The interrelation model suggested in this study has been made based on the matrix method. On this matrix, we arranged the environmental factors on horizontal and vertical axis, and when we describe the relation of each factors, we set the horizontal axis as the base and divided the content into three grades : Fine, Medium, and Poor. In addition to that, we expressed those three grades into numerical value like 3 points for Level Fine, 2 points for Level Medium, and 1 point for Level Poor and then, we converted this numerical values into index numbers. We could classify the index numbers such as AS, PS, Q-index, P-index. AS is an index numerically shows the degree of giving environmental effect, PS is an index numerically shows the degree of receiving environmental effect, Q-index is an index shows the aggravate degree, and P-index shows the relation degree. The Q/P-index with large numbers has considerable effect on the environmental system, while the small numbered Q/P-index barely effect on the environmental system. Moreover, we classified the environmental factors into 5 levels(I~V) according to the relations between the Q-index and P-index. Level I is less affected by the environment and has more giving effect, while Level V is more sensitively affected by the environment and has more receiving effect, which we considered important. Therefore, we could come up with the result that if we consider the each level of factors when we evaluate the EIA, the result would be far more accurate and reliable since it contains mutual relation aspect of EIA. The suggested interrelation model in this thesis is presentable as one of those scoping system. We highly believe the need of scoping system in EIA and suggest the interrelation model as the alternative idea for scoping system.

  • PDF

James-Stein Type Estimators Shrinking towards Projection Vector When the Norm is Restricted to an Interval

  • Baek, Hoh Yoo;Park, Su Hyang
    • 통합자연과학논문집
    • /
    • 제10권1호
    • /
    • pp.33-39
    • /
    • 2017
  • Consider the problem of estimating a $p{\times}1$ mean vector ${\theta}(p-q{\geq}3)$, $q=rank(P_V)$ with a projection matrix $P_v$ under the quadratic loss, based on a sample $X_1$, $X_2$, ${\cdots}$, $X_n$. We find a James-Stein type decision rule which shrinks towards projection vector when the underlying distribution is that of a variance mixture of normals and when the norm ${\parallel}{\theta}-P_V{\theta}{\parallel}$ is restricted to a known interval, where $P_V$ is an idempotent and projection matrix and rank $(P_V)=q$. In this case, we characterize a minimal complete class within the class of James-Stein type decision rules. We also characterize the subclass of James-Stein type decision rules that dominate the sample mean.