• Title/Summary/Keyword: Pores

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Investigation of Degradation Mechanism of High Alumina Refractory in a Coal Gasifier (석탄 가스화기에서의 고알루미나 내화물의 손상 기구 규명)

  • Kim, Yuna;Lee, Jae Goo;Oh, Myongsook S.
    • Applied Chemistry for Engineering
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    • v.20 no.6
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    • pp.638-645
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    • 2009
  • High alumina refractory used in a coal gasifier was analyzed and the degradation mechanism by molten slag was investigated. The depth of refractory severely damaged by slag varied between 12~40 mm, including the adhered slag layer. The sample also showed the cracks formed in parallel to the slag/refractory interface. The degree of degradation varied with the micro-structures in the refractory. Fused alumina grains showed the uneven boundary and pore formation just along the edges, while the tablet alumina showed the slag penetrated between sintered alumina around which the formation of Al-Fe phase was observed. Calcium aluminate cements were not observed at the high temperature zone near the slag/refractory interface, probably due to dissolution into molten slag. Around large grains of alumina, rod shape alumina, which appeared to be recrystallized during cooling, were observed, and large pores were also formed around those grains. Therefore, in high alumina refractories, hot molten slag dissolves the bonding phase and rod-shape alumina phase is recrystallized upon cooling. During this process, cracks are developed due to structural change, and the degradation occurs by physical causes such as structural spalling.

The effects of fermentation agent and fermentation temperature on the quality of Bori-sangoedduk (발효원과 발효온도가 보리상외떡의 품질특성에 미치는 영향)

  • Kwak, Eun-Jung;Park, Sang-Hee;Kim, Ji-Sang;Lee, Young-Soon
    • Korean journal of food and cookery science
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    • v.23 no.2 s.98
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    • pp.173-179
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    • 2007
  • The effects of fermentation agent and fermentation temperature on the quality of Bori-sangoedduk We examined the effects of fermentation agent and fermentation temperature on the quality characteristics of Bori-sangoedduk a traditional dduk(rice cake) from Jeju, Korea. Bori-sangoedduk was prepared by mixing wheat flour, barely flour, and Borisul or Takju as the fermentation agent the mixture was then fermented at 30, 35, and $40^{\circ}$C. for 3 hr, and steamed. The L- value of the Takju group was higher than that of the Borisul group, and the samples fermented at $30^{\circ}$C in each group had higher than L-values than those fermented at $35^{\circ}$C and $40^{\circ}$C . The a- and b-values did not differ significantly by the fermentation agents and fermentation temperatures. The loaf volume of the Borisul group was higher than that of the Takju group however, there were no significant differences according to fermentation temperature. The values of hardness, springiness, and cohesiveness were lower in the Borisul group than in the Takju group due to a greater number of pores and surface cracks. Hardness, springiness, and cohesiveness values were highest at fermentation temperatures of 30, 35, and $40^{\circ}$C , respectively, in both groups, compared to samples at other temperatures. In the acceptance test, the Takju group was preferred over the Borisul group for appearance, texture, taste, flavor, and overall preference. There were also statistically significant preferences in taste, flavor, and overall preference for samples fermented at $40^{\circ}$C , in both groups, compared to those fermented at $30^{\circ}$C and $35^{\circ}$C. In the descriptive test, there were no differences in color according to fermentation agent and fermentation temperature, however, the Takju group was shinier than the Borisul group. In addition, the Takju group was harder and springier than the Borisul group, and had less sour taste and flavor than the Borisul group. Finally, in terms of overall preference, we found that Bori-sangoedduk made with Takju and fermented at $40^{\circ}$C for 3 hr was the best formula, due particularly to its taste and flavor.

Effect of Crystal Particle Deposition on Morphology of Zeolite Membrane and its Separation Performance (결정입자 도포가 제올라이트 막 구조 및 분리성능에 미치는 영향)

  • Lee, Yong-Taek;Jeong, Heon-Kyu;Jeong, Dong-Jae;Yun, Mi-Hye;Ahn, Hyo-Seong
    • Membrane Journal
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    • v.18 no.3
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    • pp.198-205
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    • 2008
  • A novel technology for homogeneous deposition of zeolite particles on a porous support was developed so that those particles played a seeding role for the growth of zeolite crystals. After the particles were dispersed in water, the aqueous solution was 134 through the bore of a porous tubular support. By keeping the other side of the support in a vacuum, the aqueous solution passed through the pores of the support, leading the particles to be homogeneously deposited on the support. The amount of the deposited particles was investigated by changing the following operating parameters: a particle concentration in the solution, a time for deposition, and the feeding rate of the solution. The amount of the deposited particles increased from 0.0019 g to 0.0208 g as the concentration of the particles was changed from 0.01 wt% to 0.3 wt%, while the feeding rate and the deposition time were kept to 100 mL/min and 4 min, respectively. As the deposition time was varied from 1 min to 4 min, the deposition amount increased from 0.0004g to 0.0019g at the typical condition of the rest parameters. Also, it was observed that the deposited weight increased from 0.0029 g to 0.01 g as the feeding rate increased from 100 mL/min to 300 mL/min. However, the total permeance of water and ethanol decreased through the zeolite membrane as the deposited weight increased.

The effect of Dynamite Explosion on Physical Properties of Orchard Soil (폭약(爆藥)에 의(依)한 과수원토양(果樹園土壤)의 물리성개량(物理性改良)에 관(關)한 연구)

  • Yoo, S.H.;Koh, K.C.;Cho, Y.K.
    • Korean Journal of Soil Science and Fertilizer
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    • v.11 no.2
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    • pp.61-66
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    • 1979
  • This experiment was conducted to find out the simple and economical method to improve physical properties of the soil that was very poor for the establishment of orchard. Jeonnam clay loam soils distributed mainly on rolling and hill side slope, were treated with the explosion of two kinds of dynamite at the depth of 1 m. The change of physical properties was investigated vertically and horizontally after soil profile had settled to some extent. The results were summarized as : 1. The original soil was very high in bulk density and soil hardness. Total porosity and aeration porosities were lower than critical level providing root elongation. It was more apparent in the subsoil than in the surface soil. 2. It was recognized that soil mass destruction and cracking by dynamite explosion decreased soil bulk density and soil hardness and increased porosity, especially non-capillary pores. 3. Effective radius of the improved physical properties by explosion with two dynamites was 100cm at 60cm depth and 30cm at 80cm depth. But with the use of three dynamites it was 100cm at 80cm depth. 4. It was thought that soil mass destruction and cracking caused by explosion was uneven in the two dynamites, and three dynamites was more effective to improve physical properties evenly. 5. With the use of two dynamites, Ammonium explosive was superior to gelatin dynamite.

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A Study on Soil Characteristics of Paddy Fields with Re-established Soils

  • Sonn, Yeon-Kyu;Moon, Yong-Hee;Zhang, Yong-Seon;Jung, Kang-Ho;Cho, Hye-Rae;Hyun, Byung-Keun;Shin, Kook-Sik;Han, Kyeong-Hwa
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.3
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    • pp.194-204
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    • 2015
  • Six study sites in Gumi, Goryeong in Gyeongbuk province and Naju in Jeonnam province were selected to investigate soil properties of poorly drained horizons in paddy soils. The horizons were re-established layers which were parent material layers originated from fluvial deposits. Topsoil layers were differentiated from piled parent materials while soil structure of the topsoil layer was massive with striated microstructure. Compaction at soil re-establishment and a lack of structure and aggregate development in these soils may cause the limitation of vertical water movement and result in poorly drained horizons. Soil samples were taken from paddy fields with top soils of sandy loam, silt loam and silty clay loam and re-established soils of coarse and fine texture. The samples were taken from each horizon for the analyses of soil chemical and mineral properties. Soils with re-established soils of coarse texture had greater amounts of sands from top soil texture distributions, while soils with fine texture had greater amounts of silts. Chemical properties of top soils were analyzed from rice cultivated soils at the time of re-establishments and one year after the re-establishments. The coarse texture of the re-established horizons decreased in EC values from 0.23 to $0.11(dS\;m^{-1})$, available phosphate values from 112 to $54(mg\;kg^{-1})$, and exchangeable Ca values from 6.6 to $4.9(cmol_c\;kg^{-1})$. On the other hand, soils with fine texture showed decrease only in pH and exchangeable Ca values. Especially, organic matter and available phosphate contents showed heterogeneous distributions from each horizon. This result may be caused by mixture of plough layer and subsurface layer during and consolidation. Hydraulic conductivity values were low at the boundaries of top soil and parent material layers except SL/coarse soil. Soil microstructure was massive structure without soil clods or pores and showed striated structure. Therefore, re-established paddy fields with fluvial deposits as parent material layers showed limited vertical movements of soil water because of occurrence of compacted layers and less-development of soil clods and aggregates.

Studies on Anatomical Properties of Forsythia in Korea (한국산(韓國産) 개나리속(屬)의 해부학적(解剖學的) 성질(性質)에 관한 연구(硏究))

  • Kim, Jae-Kyung;Hong, Byung-Wha
    • Journal of the Korean Wood Science and Technology
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    • v.12 no.4
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    • pp.31-35
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    • 1984
  • These experiments were carried out to investigate anatomical properties of Forsythia in Korea. The results obtained were summarized as follows: It was estimated that the vessel of cross section was almost simple pore and multiple pores which were compounded two or three units were showed sometimes and arrangement of vessel were ring porous wood. In the mean length of vessel, Forsythia koreana was ranged $539.98{\pm}154.71{\mu}$ and Forsythia ovata $602.22{\pm}157.38{\mu}$ and Forsythia nakaii T. Lee $465.50{\pm}83.02{\mu}$. In the mean length of fiber wood, Forsythia koreana $387.40{\pm}68.23{\mu}$, and Forsythia ovata was $533.90{\pm}106.77{\mu}$ and Forsythia nakaii T. Lee was $482.40{\pm}72.33{\mu}$. The type of Ray parenchyma was heterogeneous ray I tissue. The mean length of procumbent ray cell in the radial section was $42.14{\pm}8.30{\mu}$ and that of rectangle type in up right ray cell was $45.76{\pm}7.19{\mu}$ and that of square type was $26.66{\pm}2.99{\mu}$. The mean height of ray parenchyma in the tangential section was $174.80{\pm}37.51{\mu}$ and the width of ray parenchyma was $17.25{\pm}3.59{\mu}$ and the mean number of ray parenchyma was $14{\pm}3$.

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Anatomical Characteristics of Kenaf Grown in Reclaimed Land(I)-Differences in Phloem and Xylem with Growth Period and Height- (간척지에서 재배된 양마(Kenaf)의 해부학적 특성(I)-사부와 목부의 생장기관과 높이에 따른 차이-)

  • Lee, Seon-Hwa;Lee, Se-na;Kwon, Sung-Min;Lee, Myoung-Ku;Cho, Dong-Ha;Kim, Nam-Hun
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.6
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    • pp.43-49
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    • 2007
  • Anatomical properties of Kenaf (Hibiscus cannabinus L.) planted in a reclaimed-land of Korea were examined to understand the growth characteristics by an optical and scanning electron microscopy. The samples of kenaf were taken from four positions of the stem (3, 35, 70, 105 cm above from the ground) in four growth periods (July. August, September, October) from seeding planted in the middle of May. Bast fiber, phloem rays, cortex parenchyma cells and sieve tube members were observed in phloem, and vessel elements, fibers and rays in xylem. Solitary and multiple radial pores existed in xylem. The cell types of ray parenchyma in radial section were procumbent, upright, and square. The intervascular pitting showed an alternate type. Xylem proportion, the number of bast fibers and dimension of phloem rays increased with increasing growth period, and decreased with increasing stem height. The proportion of multiseriate rays was higher than that of uniseriate and biseriate rays in xylem with increasing growth period. On the other hand, The proportion of multiseriate rays was lower than that of uniseriate and biseriate rays in xylem with increasing stem height.

Gas Transport Behaviors through Multi-stacked Graphene Oxide Nanosheets (적층된 산화그래핀 분리막의 기체 투과 거동 평가)

  • Lee, Min Yong;Park, Ho Bum
    • Membrane Journal
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    • v.27 no.2
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    • pp.167-181
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    • 2017
  • Graphene-based materials have been considered as a promising membrane material, due to its easy processability and atomic thickness. In this study, we studied on gas permeation behavior in few-layered GO membranes prepared by spin-coating method. The GO membrane structures were varied by using different GO flake sizes and GO solutions at various pH levels. The GO membranes prepared small flake size show more permeable and selective gas separation properties than large one due to shortening tortuosity. Also gas transport behaviors of the GO membranes are sensitive to slit width for gas diffusion because the pore size of GO membranes ranged from molecular sieving to Knudsen diffusion area. In particular, due to the narrow pore size of GO membranes and highly $CO_2$-philic properties of GO nanosheets, few-layered GO membranes exhibit ultrafast and $CO_2$ selective character in comparison with other gas molecules, which lead to outstanding $CO_2$ capture properties such as $CO_2/H_2$, $CO_2/CH_4$, and $CO_2/N_2$. This unusual gas transport through multi-layered GO nanosheets can explain a unique transport mechanism followed by an adsorption-facilitated diffusion behavior (i.e., surface diffusion mechanism). These findings provide the great insights for designing $CO_2$-selective membrane materials and the practical guidelines for gas transports through slit-like pores and lamellar structures.

Biochemical and Cytological Changes of Pseudomonas sp. DJ-12 Cells in Response to Catechol Treatment (Catechol 처리에 의한 Pseudomonas sp. DJ-12의 생화학 및 세포학적 변화)

  • 고연자;임재윤;김치경;이기성
    • Korean Journal of Microbiology
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    • v.35 no.2
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    • pp.139-145
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    • 1999
  • Aromatic hydrocarbons which are not easily degraded by microorganisms can be accumulated in the conlaminated environment for a long lime, producing toxic effects on wild lives and humans. However, the sublethal concentrations of the chemicals induce the synthesis of stress-shock proteins in the cells and increase the adaptability of the organisms to the environmental stresses. In this study, therefore, the cells of Psezido~nonus sp. DJ- 12 treated with catechol at various concentrations were inveshgated for their survival, biodegtadability of catechol, production of stress-shock proteins, and cytological changes. The organisms were capable of degrading catechol at the range of 0.5 to 1.0 mM concentration wilhin 6 hours incubation, but they were killed by $10^2$-10$^3$ celllinl at 3 mM or higel- concentration without any catechol degradation. These cells treated with catechol begm lo produce DnaK and GroEL at 1 mM and 0.5 mM. respectively. Pseudumonas sp. DJ-12 treated with 10 mM catechol for I hour exhihiled some punctuated pores on the cell wall and contortion of the rod shape. The cells treated with he sublethal concentration of catechol showed the increased tolerance for suvival when exposed to the lethal concentration, and such tolerant effects were functioned crossly among benzoate, 4-chlorobenzoate, 'and catechol.

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Surface Apatite Growth of NaOH and SBF Treated CP-Ti, Ti-6Al-4V and ECAP-Ti (NaOH처리와 SBF침적에 따른 CP-Ti, Ti-6Al-4V 및 ECAP-Ti의 표면 아파타이트 성장)

  • Oh Seok-Jin;Ruy Jae-Gyeoung;Lee Seung-Woo;Kim Yun-Jong;Han Man-So;Kim Chang-Hyu
    • Korean Journal of Materials Research
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    • v.14 no.12
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    • pp.893-899
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    • 2004
  • Even though Ti-6Al-4V has gained popularity as an implant material, the possible dissolution of Al and V ions in body fluids remains a matter of concern. Though commercially pure Ti (Cp-Ti) overcomes this problem, the mechanical strength of pure titanium remains very low. Thus, in this experiment Cp-Ti was processed by Equal channel angular processing (ECAP), in order to increase the mechanical strength. The biocompatibility of ECAP-Ti, Cp-Ti and Ti-6Al-4V was examined by the apatite formation on each sample surface, after treating the surface with 5M NaOH and soaking in Simulated body fluids (SBF). Initially, the samples were mechanically polished on silicone carbide paper (#2000). The polished samples were treated with 5M NaOH solution at $60^{\circ}C$ for 24 hours. The NaOH treated samples were washed gently with distill water and dried at $40^{\circ}C$ for 1 day. The dried samples were heat treated in air at $600^{\circ}C$ for 1 hour. The surface morphology of these samples were studied using SEM and XRD. The SEM studies showed network of pores in all samples. The XRD showed oxide layer formation on Cp-Ti and Ti-6Al-4V. samples. However the oxide layer in ECAP-Ti was not substantial. These samples were immersed in SBF, kept at $36.5^{\circ}C$ for seven days period. At the end of 7 days, the apatite formation was confirmed only on Cp-Ti and was not observed in Ti-6Al-4V and ECAP-Ti. These observations of apatite formation relate to the fact that Cp-Ti showed greater oxide layer than other samples. The apatite examined was confirmed as tricalcium phosphate (TCP) using EDS and XRD.