• Title/Summary/Keyword: Polymeric

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Microwave Absorbing Characteristics of Epoxy Composites Containing Carbon Black and Carbon Fibers (카본블래랙과 탄소섬유를 포함하는 에폭시 복합체의 마이크로파 흡수 특성)

  • Lv, Xiao;Yang, Shenglin;Jin, Junhong;Zhang, Liang;Li, Guang;Jiang, Jianming
    • Polymer(Korea)
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    • v.33 no.5
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    • pp.420-428
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    • 2009
  • In this study, the composites containing carbon black (CB) or carbon fibers were prepared, and the microwave absorbing properties and the absorption mechanism of them were investigated and discussed in the frequency range of 2-18 GHz, respectively. The optimum mass fraction of CB has been found as 6%, and the carbon fibers were discovered to absorb radar wave either under parallel or vertical polarization, the suitable gap distance between each bundle of which was 5 mm. According to the results of the single constitute absorber samples, the structured composites with the two kinds of absorbers combination were fabricated and studied at 2-18 GHz. The top layer absorbers affect the absorption performance a lot; the maximum reflection loss of composites with CB as top layer absorbers was -31.8 dB with the frequency range of 2.4 GHz below -10 dB, and the other type with CFs as the top layer absorbers obtained the reflection loss peak value of -31.4 dB with 2 GHz below-10 dB.

Filtration Characteristics of Polymeric Porous Materials Composed of Polypropylene and Polyethylene (Polypropylene과 Polyethylene으로 구성된 기공성 고분자 소재의 여과특성)

  • Ahn, Byeng-Gil;Oh, Kyeong-Keun;Choi, Ung-Soo;Kwon, Oh-Kwan
    • Clean Technology
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    • v.4 no.2
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    • pp.32-40
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    • 1998
  • The polymeric porous materials which consist of polypropylene(PP) and polyethylene(PE) powder were prepared to apply to the air purification systems by extrusion sintering method. SEM analysis showed that a composite polymeric porous structure made up of PP and PE was obtained, where PE was melted and adhered to PP because the melting temperature of PE was lower than that of PP. The filtration characteristics and mechanical properties of polymeric porous materials were investigated by varying the head die temperature of the extruder, extrusion velocity, and the melt index and quantity of PE. The filtration efficiency was proportional to the quantity of PE but inversely proportional to the melt index of PE. The polymeric porous materials composed of PP and PE, which was made by extrusion sintering method, was found to be suitable for the filter element of the air purification system.

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Synthesis and Characteristic of Novel Soluble Triazoleimide Oligomers with Terminated Arylacetylene

  • Zhou, Xiao'an;Du, Lei;Wan, Liqiang;Wang, Xiaofei;E, Yanpeng;Huang, Farong
    • Bulletin of the Korean Chemical Society
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    • v.31 no.9
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    • pp.2603-2606
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    • 2010
  • Novel soluble triazoleimide oligomers terminated with arylacetylene terminated were synthesized by the Cu(I)-catalysed 1,3-dipolar cycloaddition polymerization of diazides and imide-containing dialkyne. Several molecular weight triazoleimide oligomers were prepared from diazide and dialkyne monomers with different stoichiometric combinations. The curing behaviors of the oligomers were tested by differential scanning calorimetry (DSC). The thermal properties of the cured products were evaluated by DSC and thermogravimetric analysis (TGA). These cured oligomers showed the glass transition temperature of about $225-235^{\circ}C$ and the decomposition temperature (at 5% weight loss) of about $385-393^{\circ}C$ in nitrogen.

Alpha-Amylase Immobilization on Epoxy Containing Thiol-Ene Photocurable Materials

  • Cakmakci, Emrah;Danis, Ozkan;Demir, Serap;Mulazim, Yusuf;Kahraman, Memet Vezir
    • Journal of Microbiology and Biotechnology
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    • v.23 no.2
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    • pp.205-210
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    • 2013
  • Thiol-ene polymerization is a versatile tool for several applications. Here we report the preparation of epoxide groups containing thiol-ene photocurable polymeric support and the covalent immobilization of ${\alpha}$-amylase onto these polymeric materials. The morphology of the polymeric support was characterized by scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) coupled with SEM was used to explore the chemical composition. The polymeric support and the immobilization of the enzyme were characterized by FTIR analysis. SEM-EDS and FTIR results showed that the enzyme was successfully covalently attached to the polymeric support. The immobilization efficiency and enzyme activity of ${\alpha}$-amylase were examined at various pH (5.0-8.0) and temperature ($30-80^{\circ}C$) values. The storage stability and reusability of immobilized ${\alpha}$-amylase were investigated. The immobilization yield was $276{\pm}1.6$ mg per gram of polymeric support. Enzyme assays demonstrated that the immobilized enzyme exhibited better thermostability than the free one. The storage stability and reusability were improved by the immobilization on this enzyme support. Free enzyme lost its activity completely within 15 days. On the other hand, the immobilized enzyme retained 86.7% of its activity after 30 days. These results confirm that ${\alpha}$-amylase was successfully immobilized and gained a more stable character compared with the free one.

Characterization of Synthetic Polymeric AI(III) Inorganic Coagulants for Water Treatment (상수처리용 합성 무기고분자 Al(III)계 응집제의 화학적특성)

  • Han Seung-Woo;Jung Chul-Woo;Kang Lim-Seok
    • Journal of Environmental Science International
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    • v.8 no.6
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    • pp.711-716
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    • 1999
  • This research explored the feasibility of preparing and utilizing a prefonned polymeric solution of Al(III) for coagulation in water treatment. Slow base(NaOH) injection into supersaturated aluminum chloride and aluminum sulfate solutions did produce high yields of Al polymers useful to water treatment applications. The method of characterization analysis was based on timed spectrophotometer with ferron as a color developing reagent. The hydrolytic Al species were divided into $monomeric(Al_a),\;polymeric(Al_b),\;and\;precipitate(Al_c)$ from the difference in reaction kinetics. The analysis of PACl's characteristics showed that the quantity of polymeric Al produced at value of$ r(OH_{added}/AI)=2.2$ was $83\%$ of the total aluminum in solution, as showing maximum contents and precipitated Al was dramatically increased when r was increased above 2.35. In addition, the characteristics of polyaluminum sulfate (PAS) showed that polymeric Al contained at r = 0.75 was $18\%$ of the total aluminum in solution. The synthesized PACI and PAS were stable during storing period, as indicating negligible aging effect. The effect of sulfate ion on PACI was dependent on the concentration of sulfate ion. That is, polymeric species decrease and precipitate species increase as sulfate ion concentration increased. It can be concluded that the sulfate cause the formation of $Al(OH)_{3(S)}$ at low pH. However, The effect of calcium ion was negligible for distribution of Al species.

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Elastic-Damage Constitutive Model for Nonlinear Tensile Behavior of Polymeric Foam (폴리머 폼의 비선형 인장거동을 모사하기 위한 기공이 고려된 손상 탄성 구성방정식)

  • Kwon, Sun-Beom;Lee, Jae-Myung
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.31 no.4
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    • pp.191-197
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    • 2018
  • This paper details the development of an isotropic elastic-damage constitutive model for polymeric foam based on irreversible thermodynamics to consider the growth and coalescence of voids. The constitutive equations describe the material behavior sustaining unilateral damage. To facilitate finite element analysis, the material properties for specific types of polymeric foams are applied to the developed model; the model is then implemented in ABAQUS as a user-defined material subroutine. To validate the developed damage model, the simulated results are compared to the results of a series of tensile tests on various polymeric foams. The proposed damage model can be utilized to further research on continuum damage mechanics and finite element analysis of polymeric foams in computational engineering.

Alginate Beads as Controlled Release Polymeric Drug Delivery System (Alginate Bead를 이용한 고분자 약물의 제어방출형 약물수송체)

  • Hwang, Sung-Joo;Rhee, Gye-Ju;Jo, Hang-Bum;Lee, Ki-Myung;Kim, Chong-Kook
    • Journal of Pharmaceutical Investigation
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    • v.23 no.1
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    • pp.19-26
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    • 1993
  • The purpose of this paper is to explore the possible applicability of alginate beads as an oral controlled release system of polymeric drugs. Cellulase was used as a model polymeric drug. The release of cellulase from alginate beads was moderately affected by the ratio of cellulase to sodium alginate and strongly affected by $CaCl_2$ concentration. However, the release was not particularly affected by the other factors such as sodium alginate concentration and curing time. The drug was not released from alginate beads at pH 1.2, but was released continuously up to 8 hr at pH 6.8. At pH 6.8, the beads were swollen highly up to 3 hr, thereafter, were eroded into the bulk solution up to 6 hr, completely. Drug release from the beads can be caused due to diffusion and erosion of the matrix. Activity of cellulase was reduced when alginate beads containing cellulase were stored in simulated gastric juice. Further investigation would be necessary to improve the acid resistance of the beads. Since the release of cellulase as a model polymeric drug could be controlled by the regulation of the preparation conditions of alginate beads, the alginate beads may be used for a potential oral controlled release system of such polymeric drugs as polypeptide drugs.

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Utilization of Image Analysis Technique for Characterization of Micro-Bubbles Generated by Polymeric Membrane Module (고분자 중공사막 모듈을 이용한 미세기포 발생과 이미지 분석기법을 이용한 기포 특성 파악)

  • Kim, Jun-Young;Chang, In-Soung
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.6
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    • pp.447-452
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    • 2011
  • In this study, the polymeric membrane module is used as a diffuser and an image analysis technique based on visual information is applied to get bubble characteristics. The bubble size generated passed through polymeric membrane module was smaller from 30 to 64% than that of air stone, and bubble volume over 70% was ranged from 0.2 to 0.82 mm. But over 80% the bubbles from air stone diffuser ranged from 0.77 to 1.08 mm. The air stone and polymeric membrane module used as diffuser for a flotation system. The floc size inside the flotation reactor using air stone diffuser was bigger than that of the polymeric membrane module, which means that the micro-bubbles generated from polymeric membrane module could provide better opportunities for collisions between colloidal particles than those from air stone diffuser. Therefore, there is a possibility to apply the polymeric membrane module as a diffuser to increase the removal efficiency in the flotation process. Also, the image analysis technique used in this study could be applied as a useful analytical tool for acquisition of an information about the bubble characteristic.