• Title/Summary/Keyword: Nano Carbon

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Electrochemical Characteristics of Porous Silicon/Carbon Composite Anode Using Spherical Nano Silica (구형 나노 실리카를 사용한 다공성 실리콘/탄소 음극소재의 전기화학적 특성)

  • Lee, Ho Yong;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.54 no.4
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    • pp.459-464
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    • 2016
  • In this study, the electrochemical characteristics of porous silicon/carbon composite anode were investigated to improve the cycle stability and rate performance in lithium ion batteries. In this study, the effect of TEOS and $NH_3$ concentration, mixing speed and temperature on particle size of nano silica was investigated using $St{\ddot{o}}ber$ method. Nano porous Si/C composites were prepared by the fabrication processes including the synthesis of nano $SiO_2$, magnesiothermic reduction of nano $SiO_2$ to obtain nano porous Si by HCl etching, and carbonization of phenolic resin. Also the electrochemical performances of nano porous Si/C composites as the anode were performed by constant current charge/discharge test, cyclic voltammetry and impedance tests in the electrolyte of $LiPF_6$ dissolved inorganic solvents (EC:DMC:EMC=1:1:1vol%). It is found that the coin cell using nano porous Si/C composite has the capacity of 2,006 mAh/g and the capacity retention ratio was 55.4% after 40 cycle.

1H Nuclear Magnetic Resonance of a Ferroelectric Liquid Crystalline System

  • Cha, J.K.;Lee, K.W.;Oh, I.H.;Han, J.H.;Lee, Cheol-Eui;Jin, J.I.;Choi, J.Y.
    • Journal of Magnetics
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    • v.15 no.2
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    • pp.61-63
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    • 2010
  • We used $^1H$ nuclear magnetic resonance (NMR) to study the phase transitions and molecular dynamics in a characteristic ferroelectric liquid crystal with a carbon number n = 7, S-2-methylbutyl 4-n-heptyloxybiphenyl-4'-carboxylate (C7). The results were compared with those of our recent work on S-2-methylbutyl 4-n-octanoyloxybiphenyl-4'-carboxylate (C8), with a carbon number n = 8. While the recrystallization and isotropic phase transitions exhibited a first-order nature in the $^1H$ NMR spin-lattice and spin-spin relaxation measurements, a second-order nature was shown at the Sm-A - Sm-$C^*$ liquid crystalline phase transition. A soft-mode anomaly arising from the tilt angle amplitude fluctuation of the director, of which only a hint had been noticed in the C8 system, was manifested in the C7 system at this transition.

Non-linear free and forced vibration analysis of sandwich nano-beam with FG-CNTRC face-sheets based on nonlocal strain gradient theory

  • Arani, Ali Ghorbanpour;Pourjamshidian, Mahmoud;Arefi, Mohammad
    • Smart Structures and Systems
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    • v.22 no.1
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    • pp.105-120
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    • 2018
  • In this paper, the nonlinear free and forced vibration responses of sandwich nano-beams with three various functionally graded (FG) patterns of reinforced carbon nanotubes (CNTs) face-sheets are investigated. The sandwich nano-beam is resting on nonlinear Visco-elastic foundation and is subjected to thermal and electrical loads. The nonlinear governing equations of motion are derived for an Euler-Bernoulli beam based on Hamilton principle and von Karman nonlinear relation. To analyze nonlinear vibration, Galerkin's decomposition technique is employed to convert the governing partial differential equation (PDE) to a nonlinear ordinary differential equation (ODE). Furthermore, the Multiple Times Scale (MTS) method is employed to find approximate solution for the nonlinear time, frequency and forced responses of the sandwich nano-beam. Comparison between results of this paper and previous published paper shows that our numerical results are in good agreement with literature. In addition, the nonlinear frequency, force response and nonlinear damping time response is carefully studied. The influences of important parameters such as nonlocal parameter, volume fraction of the CNTs, different patterns of CNTs, length scale parameter, Visco-Pasternak foundation parameter, applied voltage, longitudinal magnetic field and temperature change are investigated on the various responses. One can conclude that frequency of FG-AV pattern is greater than other used patterns.

Effects of constituents in CNT pastes on the field emission characteristics of carbon nanotubes

  • Yoon, Seung-Il;Kim, Sam-Soo;Lee, Yang-Kyu;Kim, Tae-Kwon;Lee, Dong-Gu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1206-1209
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    • 2006
  • Carbon nanotubes (CNTs) have been significantly used for the field emitters for display applications. However, the lifetime of CNT emitters which are formed by screen printing technique is not guaranteed yet, because the constituents in CNT paste affect the lifetime of CNTs. The CNT pastes for screen printing are normally composed of organic vehicles (nitro cellulose, ethyl cellulose, etc) and additives (glass frits, ITO, etc) with CNTs. In this study, the effects of constituents in CNT pastes on the lifetime and emission characteristics of CNTs were investigated by thermal and electrical analysis. Use of glass frits worsened the lifetime and electron emission of CNTs. However, an addition of ITO to CNT paste rather improved the lifetime of CNTs. Degradation of CNTs was small when nitro cellulose was used in CNT paste as an organic vehicle.

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Free vibration and buckling analysis of elastically restrained FG-CNTRC sandwich annular nanoplates

  • Kolahdouzan, Farzad;Mosayyebi, Mohammad;Ghasemi, Faramarz Ashenai;Kolahchi, Reza;Panah, Seyed Rouhollah Mousavi
    • Advances in nano research
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    • v.9 no.4
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    • pp.237-250
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    • 2020
  • An accurate plate theory for assessing sandwich structures is of interest in order to provide precise results. Hence, this paper develops Layer-Wise (LW) theory for reaching precise results in terms of buckling and vibration behavior of Functionally Graded Carbon Nanotube-Reinforced Composite (FG-CNTRC) annular nanoplates. Furthermore, for simulating the structure much more realistic, its edges are elastically restrained against in-plane and transverse displacement. The nano structure is integrated with piezoelectric layers. Four distributions of Single-Walled Carbon Nanotubes (SWCNTs) along the thickness direction of the core layer are investigated. The Differential Quadrature Method (DQM) is utilized to solve the motion equations of nano structure subjected to the electric field. The influence of various parameters is depicted on both critical buckling load and frequency of the structure. The accuracy of solution procedure is demonstrated by comparing results with classical edge conditions. The results ascertain that the effects of different distributions of CNTs and their volume fraction are significant on the behavior of the system. Furthermore, the amount of in-plane and transverse spring coefficients plays an important role in the buckling and vibration behavior of the nano-structure and optimization of nano-structure design.

Enhanced Field Emission Behavior from Boron-Doped Double-walled Carbon Nanotubes Synthesized by Catalytic Chemical Vapor Deposition

  • Kang, J.H.;Jang, H.C.;Choi, J.M.;Lyu, S.C.;Sok, J.H.
    • Journal of Magnetics
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    • v.17 no.1
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    • pp.9-12
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    • 2012
  • Attempts to dope carbon nanotube (CNT) with impurities in order to control the electronic properties of the CNT is a natural course of action. Boron is known to improve both the structural and electronic properties. In this report, we study the field emission properties of Boron-doped double-walled CNT (DWCNT). Boron-doped DWCNT films were fabricated by catalytic decomposition of tetrahydrofuran and triisopropyl borate over a Fe-Mo/MgO catalyst at $900^{\circ}C$. We measured the field emission current by varying the doping amount of Boron from 0.8 to 1.8 wt%. As the amount of doped boron in the DWCNT increases, the turn-on-field of the DWCNT decreases drastically from 6 V/${\mu}m$ to 2 V/${\mu}m$. The current density of undoped CNT is 0.6 mA/$cm^2$ at 9 V, but a doped-DWCNT sample with 1.8 wt% achieved the same current density only at only 3.8 V. This shows that boron doped DWCNTs are potentially useful in low voltage operative field emitting device such as large area flat panel displays.

Fabrication of CNT Flexible Field Emitters and Their Field Emission Properties

  • Shin, Dong-Hoon;Song, Yenan;Sun, Yuning;Shin, Ji-Hong;Lee, Cheol-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.384-384
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    • 2011
  • Carbon nanotubes (CNTs) have been studied as an ideal material for field emitters due to the high aspect ratio, excellent electrical property and good mechanical strength. There were many reports on CNT emitters fabricated on rigid substrates, but rare reports about CNT flexible field emitters. Recently, we considered that CNTs can be a good candidate for a flexible field emitter material because of their excellent Young's modulus and elasticity, which could not be achieved with metal tips or semiconducting nanowire tips. In this work, we demonstrated the CNT flexible field emitters fabricated by a simple method and studied the field emission properties of the CNT flexible field emitters under various bending conditions. The flexible field emitters showed stable and uniform emission characteristics. Especially, there is no remarkable change of the field emission properties at the CNT flexible field emitters according to the bending conditions. The CNT flexible field emitters also exhibited a good field emission performance like the low turn-on field and high emission current. Therefore, we suggest that the CNT flexible emitters can be used in many practical applications under different bending conditions.

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Design for Adhesive Carbon Heating Element X-ray Table with an Attached Heating Device (가열장치를 구비한 부착형 탄소발열체 X선 촬영대 고안)

  • Song, Jongnam;Kim, Eungkon
    • Journal of the Korean Society of Radiology
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    • v.9 no.3
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    • pp.131-137
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    • 2015
  • The purpose of this study is to warm up the conventional X-ray table by inventing and design for X-ray table with an attached heating device using less unloaded X-ray, CNT (carbon nano tube) heating element. Configuration of the product design for adhesive carbon heating element X-ray is composed of a conventional X-ray table, carbon nano tube planar heating element, an electrode line, flame resisting protective film, and the bottom film. Characteristics and advantages of this invented product is to provide gentle feeling, the sense of security, and eliminating anxiety to the patient wearing a patient gown and feel the cool air while receiving the test. Thus we are strongly recommend to use this device in the clinical situation.

An Accuracy Improvement Method for the Analysis of Process Variation Effect on CNTFET-based Circuit Performance (CNTFET 기반 회로 성능의 공정 편차 영향 분석을 위한 정확도 향상 방법)

  • Cho, Geunho
    • Journal of IKEEE
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    • v.22 no.2
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    • pp.420-426
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    • 2018
  • In the near future, CNTFET(Carbon NanoTube Field Effect Transistor) is considered as one of the most promising candidate for the replacement of modern silicon-based transistors by utilizing the ballistic or near-ballistic transport capability of CNT(Carbon NanoTube). For the large-scale fabrication of high performance CNTFET, semiconducting CNTs have to be well-aligned with a fixed pitch and high densities in the each CNTFET. However, due to the immaturity of the CNTFET fabrication process, CNTs can be unevenly positioned in a CNTFET and existing HSPICE library file cannot support the circuit level evaluation of performance variation caused by the unevenly positioned CNTs. To evaluate the performance variation, linear programming methodology was suggested previously, but the errors can be made during the calculation of the current and the gate capacitance of a CNTFET. In this paper, the reasons causing errors will be discussed in detail and the new methodology to reduce the errors will be also suggested. Simulation results shows that the errors can be reduced from 7.096% to 3.15%.

Carbon Nanotube DNA Bioconjugates as Nano-Bio Markers (탄소 나노튜브와 DNA와의 결합을 통한 나노-바이오 마커 응용)

  • Hwang Eung-Soo;Chengfan Cao;Hong Sang-Hyun;Jung Hye-Jin;Cha Chang-Yong;Choi Jae-Boong;Kim Young-Jin;Baik Seung-Hyun
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.668-671
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    • 2005
  • Carbon nanotubes exhibit strong fluorescence emissions in the region of near infrared regions where most biomolecules are transparent. Such signals are highly sensitive to environment variations as well as adsorption of specific biomolecules. In this research, single walled carbon nanotubes(SWNTs) are assembled with different types of DNAs and used to target specific types of DNAs. Dot blot investigations and corresponding raman spectroscopy observations demonstrated excellent selectivity of carbon nanotube-DNA bioconjugates. The results show possibility of using SWNT as generic nano-bio markers for precise detection of different kinds of genes.

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