• 대한화학회지
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• 제10권4호
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• pp.166-174
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• 1966

cinnamoylated photosensitive polymer의 광증감 경화반응기구를 반응속도론적으로 연구했다. Cinnamic acid(C)와 증감제(S)의 first excited singlet and lowest triplet energy level diagram과 증감제의 농도증가에 따른 sensitivity의 포화 등의 사실로부터 이 반응의 주요과정은 C와 S의 광 energy흡수에 의한 $C^{*(1)}$ 및 $S^{*(1)}$로의 여기, $S^{*(1)}{\to}S^{*(3)}$ intersystem crossing, S의 excimer 형성, $S^{*(3)}{\to}C^{*(3)}$ energy transfer 그리고 $C^{*(3)}$와 C의 termination 등임을 가정하고 다음 반응속도를 구했다. $-\frac{d[C]}{dt} = \frac{K_1[C]}{K_2 + [C]}[\frac{I^c_{abs}}{K_3 + [S]} + \frac{K_4[C]}{(K_5 + [C])(K_6 + [S])}(I^s_{abs} + \frac{K_7I^c_{abs}[S]}{K_8 + [S]})]$ $I^c_{abs}$와 $I^s_{abs}$ ;C 및 S의 광흡수율 $K_n$;상수 적외선 흡수스펙트럼 분석의 결과, Cinnamoyl 에스테르화도와 sensitivity의 관계 및 증감제의 농도와 sensitivity의 관계에 대하여 발표된 실험 data는 윗식을 만족시키므로 가정한 반응기구에 대한 뒷받침을 얻었다.

• 대한조선학회지
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• 제25권4호
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• pp.47-57
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• 1988

A new discrete method using idealized rigid body-spring model is introduced. This rigid element method is known to be more efficient and accurate than the finite element method in the inelastic range of structural analysis owing to simplified stress-strain and strain-displacement relations This kind of physical concept using idealized rigid model has been already applied among structural engineers to some problems such as rigid-plastic analysis or plastic design considering rigid bodies and plastic hinges. However the most rigorous and systematic research has been recently performed by T. Kawai et al.[1]. In this paper, an attempt is made to analyze the collapse behavior of stiffened plates under lateral loading by some modification and expansion of Kawai's rigid element approach to the collapse of plates without stiffener. Stiffened plates are treated as orthotropic plates which have equivalent bending rigidities. By employing Morley's plate element resubdivision technique, variety is given to mesh-division styles which have greate effect on the accuracy of numerical results. Some examples are shown to verify the validity of applying rigid element method to the ultimate strength analysis of stiffened plates. It is clarified that lateral deflections and detailed collapse patterns up to the ultimate state of stiffened plates can be easily obtained by the present approach.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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• pp.528-529
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• 2008

A new concept based on sample current measurements for detecting of via-hole defects on wafer has been performed by low energy electron beam microcolumn. The microcolumn has been operated at a low voltage of 290 eV with total emission current of 400 nA, and a sample current of 6 nA. The test sample was fabricated with SiO2 layer of 300 nm thickness on a piece of a silicon substrate. Preliminary results of both sample current method and secondary electron method show microcolumn and its control can be useful technology for detecting of via-hole defects on wafer.

• 분석과학
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• 제18권5호
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• pp.403-409
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• 2005

최근 내분비계장애물질로 알려진 PAHs 화합물 중 하나인 벤조피렌은 대표적인 PAHs 화합물로 음식을 조리, 가공할 때 식품의 주성분인 탄수화물, 단백질, 지방 등이 분해되어 생성되는 열분해 산물이며 토양, 공기, 물, 식품 등 전 환경매체에서 검출되고 있다. 본 연구에서는 PAHs[benzo(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(a)pyrene, dibenzo(a,h)anthracene, benzo(g,h,i)perylene, indeno(1,2,3-c,d)pyrene]에 대하여 어류 중 지방의 알칼리 분해시간에 따른 분해효율, 추출 용매에 따른 추출효율, 정제컬럼의 용출량에 따른 정제효율 등을 비교 실험하여 알칼리분해를 이용한 어류 중 PAHs의 전처리방법을 확립하고자 하였다. 균질화된 시료를 알칼리 분해하여 n-hexane으로 추출하고 증류수로 세척한 후 Sep-Pak florisil cartridge로 정제하여 HPLC/FLD(고속액체크로마토그래피/형광검출기) 로 동시 정량 분석하였으며 각각의 PAHs에 대한 회수율은 약 90~106% 수준이었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 영호남 합동 학술대회 및 춘계학술대회 논문집 센서 박막 기술교육
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• pp.27-30
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• 2006

In this paper, the undoped and Co-doped $Zn_4SnSe_6$ single crystals grown by the chemical transporting reaction(CTR) method using iodine as a transporting agent are investigated. For the crystal growth, the temperature gradient of the CTR furnace was kept at $680^{\circ}C$ for the source zone and at $780^{\circ}C$ for the growth zone for 7days. It was found from the analysis of x-ray diffraction that the $Zn_4SnSe_6$ and $Zn_4SnSe_6Co^{2+}$ compounds have a monoclinic structure. The direct optical energy band gap of the $Zn_4SnSe_6$ and $Zn_4SnSe_6Co^{2+}$ single crystals at 300K were found to be 2.146eV and 2.042eV.

• 한국약용작물학회지
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• 제16권6호
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• pp.446-454
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• 2008

An advanced extraction method by ultrasonic extraction with applied solid phase extraction (SPE) has been developed for the determination of simultaneous eight major ginsenosides, namely ginsenosides Rg1, Re, Rf, Rb1, Rg2, Rc, Rb2, and Rd in the root of Panax ginseng. Four extraction methods including n-BuOH reflux extraction (Method A), 70% EtOH reflux extraction (Method B), 50% MeOH reflux extraction with SPE (Method C), and 50% MeOH ultrasonication with SPE clean-up process (Method D) were investigated for the determination of eight major ginsenosides. Total contents of ginsenosides were highest by extraction of Method C as $2.408{\pm}0.011%$. However, Method D was evaluated as relatively simpler and more efficient method due to short extraction time, small solvent consumption and less expensive, compared to conservative reflux method. Ginsenosides were also satisfactorily separated with good resolution and the accuracy range was between 1.05 and 4.06% as relative standard deviation (RSD) by Method D. SPE condition and HPLC condition were further optimized for determination of eight major ginsenosides by the ultrasonic extraction method. Conclusively, ultrasonic extraction of 2 g sample of ginseng using ultrasonic bath and 1 loading for SPE was evaluated as proper condition for extraction of ginseng.

• 해양환경안전학회:학술대회논문집
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• 해양환경안전학회 2007년도 추계학술발표회
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• pp.35-41
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• 2007

An International Convention on the control of harmful anti-fouling system on ships(AFS Convention) was adopted on 5 October 2001 at Diplomatic Conference in London, and is expected to be presently effectuated with ratification of more than 25-member nations possessing about 25% of total world tonnage. This convention regulates the operation of harmful anti-fouling system and especially prohibits the use of organotin compounds contained in anti-fouling paint. Organotin compounds have a tendency to be easily extracted by specific solvents and have high polarity and low volatility as specific characteristics. This drives us to attempt of going through the process named derivatization that is required in analysis using a gas chromatography(GC). This study was conducted to determine the proper pre-treatment method, ethylation in comparison with hydridization on the analysis of tributyltin in organotin compounds and to verify the application of the method through the experimental analysis practically used anti-fouling paint and painted layer sample of the served ship.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 일렉트렛트 및 응용기술
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• pp.93-96
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• 2002

In this study, PZT thin films were fabricated using sol-gel processing onto Si/$SiO_2$/Ti/Pt substrates. PZT sol with different Zr/Ti ratio(20/80, 30/70, 40/60, 52/48) were prepared, respectively. The films were fabricated by using the spin-coating method on substrates. The films were heat treated at $450^{\circ}C$, $650^{\circ}C$ by rapid thermal annealing(RTA). The preferred orientation of the PZT thin films were observed by X-ray diffraction(XRD), and Scanning electron microscopy(SEM). All of the resulting PZT thin films were crystallized with perovskite phase. The fine crystallinity of the films were fabricated. Also, we found that the ferroelectric properties from the dielectric constant of the PZT thin films were over 600 degrees, P-E hysteresis constant. And the leakage current densities of films were lower than $10^{-8}A/cm^2$. It is concluded that the PZT thin films by sol-gel process to be convinced of application for ferroelectric memory device.

• 한국측량학회지
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• 제11권1호
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• pp.55-60
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• 1993

자연 생태계의 일부분으로 발생한 삼림은 공기를 맑게하고 수자원을 보존하며, 번식과 멸종의 방지, 휴식공간 제공 그리고 인간생활 환경을 형성하고 보존시키는 역할을 수행한다. 본 연구에서 원격탐사 자료를 이용하여 삼림식생을 분류한 것은 침염수, 활엽수, 농경지 및 초지, 물의 네 가지로 삼림식생정보를 분류하였다. TM 수치영상을 컴퓨터를 이용하여 분류할 경우, 물지역의 특성 값은 제 4밴드에서 7-13 D.N으로 나타났다. 그러나 침엽수, 활엽수, 농경지 및 초지는 모두 비슷한 특성 값이 나타나므로 화상처리를 해야했다. 화상처리를 제 2밴드와 제 3밴드를 합성한 영상을 비연산처리한 결과, 제 3밴드로부터 활엽수 지역은 72-91의 D.N으로 나타나고, 제 1밴드에서의 침엽수 지역은 l18∼136, 제 3밴드에서의 농경지 및 초지는 96-120의 D.N에서 일치하였다. 또한 최대 우도법으로 분류한 결과와 TM 수치영상의 현지답사에 대한 비교오차를 구한 결과 침엽수, 활엽수, 농경지와 초지 및 물에서 각각 －7.43%, ＋1.89%, ＋7.58%, -2.04%의 분류 정확도를 얻었다. 결론적으로 이 결과는 원격탐사 자료를 이용한 삼림식생분류가 매우 유용한 것임이 입증되었다.

• 천문학회지
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• 제25권1호
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• pp.1-9
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• 1992

We present new approach to analysis of velocity data of globular clusters. Maximum likelihood method is applied to get model parameters such as central potential, anisotropy radius, and total mass fractions in each mass class. This method can avoid problems in conventional binning method of chi-square. We utilize three velocity components, one from line of sight radial velocity and two from proper motion data. In our simplified scheme we adopt 3 mass-component model with unseen high mass stars, intermediate visible stars, and low mass dark remnants. Likelihood values are obtained for 124 stars in M13 for various model parameters. Our preferred model shows central potential of $W_o=7$ and anisotropy radius with 7 core radius. And it suggests non-negligible amount of unseen high mass stars and considerable amount of dark remnants in M13.