• Journal of the Optical Society of Korea
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• 제14권2호
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• pp.65-76
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• 2010

Plasmonic-based biosensing technologies have been successfully commercialized and applied for monitoring various biomolecular interactions occurring at a sensor surface. In particular, the recent advances in nanofabrication methods and nanoparticle syntheses provide a new route to overcome the limitations of a conventional surface plasmon resonance biosensor, such as detection limit, sensitivity, selectivity, and throughput. In this paper, optical and physical properties of plasmonic nanostructures and their contributions to a realization of enhanced optical detection platforms are reviewed. Following vast surveys of the exploitation of metallic nanostructures supporting localized field enhancement, we will propose an outlook for future directions associated with a development of new types of plasmonic sensing substrates

• Advances in nano research
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• 제2권3호
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• pp.173-177
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• 2014

This study is aimed to the numerical modeling of the surface plasmon-polariton excitation by a layer of active (electrically pumped) quantum dots embedded in a semiconductor, covered with a metal. It is shown that this excitation becomes much more efficient if the metal has a form of a thin (with thickness of several nanometers) film. The cause of this enhancement in comparison with a thick covering metal film is the partial surface plasmon-polariton localized at the metal-semiconductor interface penetration into air. In result the real part of the metal+air half-space effective dielectric function becomes closer (in absolute value) to the real part of the semiconductor dielectric function than in the case of a thick covering metal film. This leads to approaching the point of the surface plasmon-polariton resonance (where absolute values of these parts coincide) and, therefore, the enhancement of the surface plasmon-polariton excitation. The calculations were made for a particular example of InAs quantum dot layer embedded in GaAs matrix covered with an Au film. Its results indicate that for the 10 nm Au film the rate of this excitation becomes by 2.5 times, and for the 5 nm Au film - by 6-7 times larger than in the case of a thick (40 nm or more) Au film.

• Applied Science and Convergence Technology
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• 제26권4호
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• pp.91-94
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• 2017

AThe effect of localized surface plasmon on silicon substrates was studied using silver nanoparticles. The nanoparticles were formed by self-arrangement through the surface energy using rapid thermal annealing (RTA) technique after the thin nanolayer of silver was deposited by thermal evaporation. By the theoretical calculation based on Mie scattering and dielectric function of air, indium tin oxide (ITO), and silver, the strong peak of scattering cross section of silver nanoparticles was found at 358 nm for air, and 460 nm for ITO, respectively. Accordingly, the strong suppression of reflectance under the condition of induced light of $30^{\circ}$ occurred at the specific wavelength which is almost in accordance with peak of scattering cross section. When the external quantum efficiency was measured using silicon solar cells with silver nanoparticles, there was small enhancement peak near the 460 nm wavelength in which the light was resonated between silver nanoparticles and ITO.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2011년도 춘계학술대회 논문집
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• pp.595-596
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• 2011

• 한국전기전자재료학회논문지
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• 제22권4호
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• pp.307-313
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• 2009

Quantitative analysis of optical scattering intensities from a Au nanoparticle with a diameter of 100 nm, which is effected by the localized surface plasmon resonance (LSPR), were numerically carried out by using a dark-field detection scheme on prism basal plane for two different beam incident modes of reflectance (R-mode) and transmittance (T-mode). Two-dimensional finite difference time domain (FDTD) algorithm was adopted, and its applicabilibility was verified by comparing the simulation results with the theoretical ones. Simulation results of the scattered light intensities from a Au nanoparticle revealed that the scattered intensity of the T-mode was much stronger than that of R-mode. Comparison of the calculated results with the theoretical intensity distribution on the prism showed that the scattered intensity is marimized when the evanescent field, which is generated from the interface of prism and air at TIR angle, is coupled with Au nanoparticle.

• Current Optics and Photonics
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• 제6권1호
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• pp.79-85
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• 2022

Tracers are one of the critical factors for improving the performance of velocimetry. Silver and gold nanoparticles as tracers with localized surface-plasmon resonance are analyzed for their scattering properties. The scattering cross sections, angular distribution of the scattering, and equivalent scattering cross sections from 53° and 1.5° half-angle cones at 532 nm are calculated, with particle sizes in the nanoscale range. The 53° and 1.5° half-angle cones used as examples correspond respectively to the collection cones for microscope objectives in microscopic measurements and camera lenses in macroscopic measurements. We find that there is a transitional size near 35 nm when comparing the equivalent scattering cross sections between silver and gold nanoparticles in water at 532 nm. The equivalent scattering cross section of silver nanoparticles is greater or smaller than that of gold nanoparticles when the particle radius is greater or smaller than 35 nm respectively. When the radius of the plasmonic nanoparticles is smaller than about 44 nm, their equivalent scattering cross sections are at least ten times that of TiO₂ nanoparticles. Plasmonic nanoparticles are promising for velocimetry applications.

• 한국재료학회지
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• 제21권10호
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• pp.525-531
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• 2011

Two dimensional (2D) arrays of noble metal nanoparticles are widely used in the sensing of nanoscale biological and chemical events. Research in this area has sparked considerable interest in many fields owing to the novel optical properties, e.g., the localized surface plasmon resonance, of these metallic nanoarrays. In this paper, we report successes in fabricating 2D arrays of gold nano-islands using nanosphere lithography. The reproducibility and the effectiveness of the nano-patterning method are tested by means of spin coating and capillary force deposition. We found that the capillary force deposition method was more effective for nanospheres with diameters greater than 600 nm, whereas the spin coating method works better for nanospheres with diameters less than 600 nm. The optimal deposition parameters for both methods were reported, showing about 80% reproducibility. In addition, we characterize gold nano-island arrays both geometrically with AFM as well as optically with UV-VIS spectrometry. The AFM images revealed that the obtained nano-arrays formed a hexagonal pattern of truncated tetrahedron nano-islands. The experimental and theoretical values of the geometric parameters were compared. The 2D gold nano-arrays showed strong LSPR in the absorption spectra. As the nano-islands increased in size, the LSPR absorption bands became red-shifted. Linear dependence of the plasmon absorption maximum on the size of the gold nano-islands was identified through the increment in the plasmon absorption maximum rate for a one nanometer increase in the characteristic length of the nano-islands. We found that the 2D gold nano-arrays showed nearly seven-fold higher sensitivity of the absorption spectrum to the size of the nano-islands as compared to colloidal gold nano-particles.

• 한국진공학회지
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• 제21권4호
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• pp.205-211
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• 2012

인듐주석산화막/폴리에틸렌 테레프탈레이트(ITO/PET: indium tin oxide/polyethylene terephthalate) 유연 기판 위에 성장된 산화아연(ZnO) 나노로드(nanorods)를 이용하여 형성된 은(Ag) 입자의 광학적 특성 및 소수성 표면에 대해 조사하였다. 시료를 준비하기 위해 스퍼터링법(sputtering)으로 코팅된 산화아연 씨드층(seed layer)을 이용하여 전기화학증착법(electrochemical deposition)으로 산화아연 나노로드를 성장시킨 후, 열증발증착법(thermal evaporation)을 사용하여 은을 증착하였다. 산화아연 나노로드의 불연속적인 표면 특성 때문에 은이 증착되면서 나노크기를 갖는 입자로 형성되었다. 비교를 위해 같은 조건으로 은을 평평한 ITO/PET에 증착하여 시료를 준비하였으며, 증착되는 은의 양을 조절하기 위해 100초에서 600초까지 열증발증착시간을 변화시켰다. 은 증착시간이 증가할수록 산화아연 나노로드 표면에 형성되는 은 입자의 크기와 양이 증가하였으며, 또한 빛의 흡수율이 가시광 영역에서 크게 증가하는 것을 확인하였다. 이는 은 입자의 국소표면플라즈몬공명(localized surface plasmon resonance)에서 기인된 것으로 짐작한다. 또한 물방울 테스트실험에서 평평한 ITO/PET에 증착된 은에서의 접촉각(contact angle)보다 산화아연 나노로드에 증착된 은 입자에서의 접촉각이 크게 증가함을 보여, 개선된 소수성 표면을 가질 수 있음을 확인하였다. 이러한 광학적 특성과 소수성 표면 결과는 산화아연 나노로드의 기반의 염료감응형 태양전지 또는 자정효과(self-cleaning)를 갖는 표면구조로 유연소자에 유용하게 응용할 수 있을 것으로 기대된다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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• pp.80-80
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• 2008

바이오 센서 응용 연구에 많이 사용되는 금(Au) 나노 입자를 이용한 국소 표면 플라즈몬 공명(Localized Surface Plasmon Resonance, LSPR)에 의한 산란광을 검출하는데 주로 이용되는 암시야(dark field) 현미경 검출 방식에 관한 전산모사를 통하여 입사광의 입사 방식에 따른 산란광 세기를 정량적으로 분석하였다. 전산모사 기법으로는 국소 표면 플라즈몬 공명의 동역학적인 현상을 모사할 수 있는 유한차분시간영역(Finite Difference Time Domain, FDTD) 기법을 이용하였는데, 이러한 기법이 암시야 현미경 전산 모사에 유효함을 우선적으로 검증하였다. 암시야 현미경 검출 방식의 모사에서 입사 광원의 반사 입사 방식과 투과 입사 방식을 비교하였고, 각각의 방식에 서 입사광의 입사각에 따른 산랑광 세기를 계산하였다. 이러한 전산모사를 통하여 프리즘을 통한 내부 전반사(Total Internal Reflection, TIR) 방식에서 입사 광원의 임계각 근처에서 많이 발생하는 에바네슨트 장(evanescent field)을 결합하는 경우 산란광 세기가 증가함을 관찰하였고, 이러한 세기의 변화를 프레넬(Fresnel) 방정식에 의해 계산된 에바네슨트 장의 세기 분포와 비교 분석하였다.

• 정보저장시스템학회논문집
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• 제3권1호
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• pp.43-46
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• 2007

The fabrication of metal nanostructures by a combination of atomic force microscopy nanomachining on a thin polymer resist, metal coating and lift-off is reported. Nanodots with sizes and nanowires with widths ranging between 50 and 100 nm have been successfully created. The present work exemplifies the feasibility and effectiveness of using a single-layer resist in comparison with a two-layer resist. In addition, the localized surface plasmon resonance peaks of the metal nanostructures have been measured and the selective growths of zinc oxide nanowires on the metal nanostructures are demonstrated.