• Title/Summary/Keyword: Gravimetry

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Study on Polymorphism of Cimetidine (시메티딘의 다형에 관한 연구)

  • Sohn, Young-Taek;Kim, Ki-Soo
    • Journal of Pharmaceutical Investigation
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    • v.23 no.2
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    • pp.81-87
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    • 1993
  • Five crystalline forms of cimetidine, four anhydrous and a monohydrate, have been prepared, and their thermal behavriours have been studied by differential thermal analysis and thermo-gravimetry. The dissolution rates of the five forms were determined in distilled water at $37^{\circ}C$. The results showed a significant difference in the dissolution rate. Polymorphic transformation occurred spontaneously during storage at room condition and was accelerated by applied energy during formulation process-milling.

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Diffusion of Water in Sulfonated Polystyrene Ionomers

  • Manoj, N.R.;Ratna, D.;Weiss, R.A.
    • Macromolecular Research
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    • v.12 no.1
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    • pp.26-31
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    • 2004
  • Using gravimetry, we have studied the diffusion of water into sulfonated polystyrene ionomers. Diffusion coefficients were calculated from Fick's equation. The water sorption was found to be dependent on the ion content (3.6-11 mol%) and the nature of the cation (H, Na, Li, or Zn). The sorption kinetics indicates a slight deviation from Fickian behavior. We used the analytical solution of Fick's equation to evaluate the concentration profiles, which are in good agreement with the experimental results.

Investigation of the Effects of CNT Dosages on the Hydration and Heating Properties of Cement Composites with Low Water-to-binder Ratio (낮은 물-바인더 비를 갖는 시멘트 복합체의 CNT 첨가량에 따른 수화특성 및 발열특성)

  • Oh, Sungwoo;Jung, Sang-hwa;Chung, Wonseok;Choi, Young Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.6
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    • pp.182-188
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    • 2018
  • Recently, various researches on the utilization of carbon nanotube(CNT) with superior electrical conductivity and large surface areas into concrete have been actively conducted. Thus, mechanical and thermal properties of cement-flyash composites were evaluated concerning the CNT replacements. Based on the low binder-to-water ratio, the cement composites were produced with 0.2 % and 0.5 % of CNT solids. The compressive strengths with various ages, isothermal calorimetry measurement, SEM analysis, thermal conductivity of cement composites and thermal gravimetry analysis were implemented. As the amount of CNT addition was increased, the thermal conductivity of cement composites were also increased. Also, there was no significant mechanical property differences between mixtures with and without CNTs.

Development of Conductive elastomer Roller for Image Forming High-Quality (고품질 화상형성을 위한 도전성 탄성체 롤러의 개발)

  • Jun, Ho-Ik;Cho, Hyun-Seob
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.10
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    • pp.3923-3927
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    • 2010
  • Primary charging roller rotated with contacting surface of OPC drum and take charge OPC drum. Owing to this reason, primary charging roller is made by elasticity substance with electric conduction. Properties of charging and image is changed by class of coating, method of coating and environment. This study developed coating material and coating method to make Image Forming of High- quality.

A Study on the Characteristics for Surface Potential of Photoconductive Drum in LBP (LBP 감광드럼의 표면전위 특성에 관한 연구)

  • Cho, Hyun-Seob;Ryu, In-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.10
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    • pp.3893-3897
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    • 2010
  • Developer roller of LBP(laser beam printer) cartridge made with magnetic substance and density of magnetic flux was decreased with the elapse of a year. Owing to this reason, quality of printing was decreased with decreasing of magnetic flux. This study investigated about the elapse of a year of magnetic substance and possible about usage of recycling production.

A Development of Primary Charging Roller for OPC Drum (OPC Drum의 저압 대전체 개발)

  • Cho, Hyun-Seob
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.2
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    • pp.243-247
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    • 2009
  • Primary charging roller is rotated with contacting surface of OPC drum and take charge OPC drum. Owing to this reason, primary charging roller is made by elasticity substance with electric conduction. Properties of charging and image is changed by class of coating, method of coating and environment. This study developed coating material and coating method to make print image of good quality.

A Study of Magnetic Properties for Recycling of Laser Printer Developer Roller (Laser Printer 현상기 Roller의 재활용을 위한 자성체 특성 연구)

  • Cho, Hyun-Seob
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.1
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    • pp.135-139
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    • 2009
  • Developer roller of laser printer cartridge made with magnetic substance and density of magnetic flux was decreased with the elapse of a year. Owing to this reason, quality of printing was decreased with decreasing of magnetic flux. This study investigated about the elapse of a year of magnetic substance and possible about usage of recycling production.

Evaluation of Thermal Property and Fluidity with Underfill for BGA Package (BGA 패키지를 위한 언더필의 열적 특성과 유동성에 관한 연구)

  • Noh, Bo-In;Lee, Bo-Young;Kim, Soo-Jung;Jung, Seung-Boo
    • Journal of Welding and Joining
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    • v.24 no.2
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    • pp.57-63
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    • 2006
  • In this study, the curing kinetics and thermal degradation of underfill were investigated using differential scanning calorimetry (DSC) and thermo gravimetry analysis (TGA). The mechanical and thermal properties of underfill were characterized using dynamic mechanical analysis (DMA) and thermo-mechanical analysis (TMA). Also, we presented on underfill dispensing process using Prostar tool. The non-isothermal DSC scans at various heating rates, the exothermic reaction peak became narrower with increasing the heating rate. The thermal degradation of underfill was composed of two processes, which involved chemical reactions between the degrading polymer and oxygen from the air atmosphere. The results of fluidity phenomena were simulated using Star CD program, the fluidity of the underfills with lower viscosity was faster.

Corrosion Monitoring of PEO-Pretreated Magnesium Alloys

  • Gnedenkov, A.S.;Sinebryukhov, S.L.;Mashtalyar, D.V.;Gnedenkov, S.V.;Sergienko, V.I.
    • Corrosion Science and Technology
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    • v.16 no.3
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    • pp.151-159
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    • 2017
  • The MA8 alloy (formula Mg-Mn-Се) has been shown to have greater corrosion stability than the VMD10 magnesium alloy (formula Mg-Zn-Zr-Y) in chloride-containing solutions by Scanning Vibrating Electrode Technique (SVET) and by optical microscopy, gravimetry, and volumetry. It has been established that the crucial factor for the corrosion activity of these samples is the occurrence of microgalvanic coupling at the sample surface. The peculiarities of the kinetics and mechanism of the corrosion in the local heterogeneous regions of the magnesium alloy surface were investigated by localized electrochemical techniques. The stages of the corrosion process in artificial defects in the coating obtained by plasma electrolytic oxidation (PEO) at the surface of the MA8 magnesium alloy were also studied. The analysis of the experimental data enabled us to determine that the corrosion process in the defect zone develops predominantly at the magnesium/coating interface. Based on the measurements of the corrosion rate of the samples with PEO and composite polymer-containing coatings, the best anticorrosion properties were displayed by the composite polymer-containing coatings.

A Study on Thermal Decomposition of RDX According to the Size using TGA (TGA를 이용한 RDX의 입자 크기에 따른 열적 분해 특성 연구)

  • Bum, Kil-Ho;Kim, Seung-Hee;Kim, Jin-Seuk
    • Journal of the Korea Institute of Military Science and Technology
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    • v.15 no.1
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    • pp.81-85
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    • 2012
  • This work is related to study the thermal decomposition of 1,3,5-trinitro-1,3,5-triazacylohexane(RDX) by differential scanning calorimeter and thermo-gravimetry with Kissinger's & Iso-conversional method under nonisothermal conditions, with heating rate from 2 to $8^{\circ}C$/min or given heating rate. We calculated and compared activation energy with these two methods. Iso-conversional method is better than Kissinger's method to study decomposition mechanism. We also investigated activation energy and frequency factor by Kissinger's & Iso-conversional method with the influence of particle size. In case of single crystal, Cl-3(large crystal) has better thermal stability than Cl-5(small crystal). The activation energy increased according to the size of the particle size.