Journal of the Korea Institute of Military Science and Technology (한국군사과학기술학회지)

The Korea Institute of Military Science and Technology (한국군사과학기술학회)
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A Study on Thermal Decomposition of RDX According to the Size using TGA

TGA를 이용한 RDX의 입자 크기에 따른 열적 분해 특성 연구

  • 범길호 (국방과학연구소 4기술연구본부 2부 고폭화약 연구팀) ;
  • 김승희 (국방과학연구소 4기술연구본부 2부 고폭화약 연구팀) ;
  • 김진석 (국방과학연구소 4기술연구본부 2부 고폭화약 연구팀)
  • Received : 2011.09.26
  • Accepted : 2012.01.27
  • Published : 2012.02.05
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Abstract

This work is related to study the thermal decomposition of 1,3,5-trinitro-1,3,5-triazacylohexane(RDX) by differential scanning calorimeter and thermo-gravimetry with Kissinger's & Iso-conversional method under nonisothermal conditions, with heating rate from 2 to $8^{\circ}C$/min or given heating rate. We calculated and compared activation energy with these two methods. Iso-conversional method is better than Kissinger's method to study decomposition mechanism. We also investigated activation energy and frequency factor by Kissinger's & Iso-conversional method with the influence of particle size. In case of single crystal, Cl-3(large crystal) has better thermal stability than Cl-5(small crystal). The activation energy increased according to the size of the particle size.

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References

  1. Lee, J. S. and Hsu, C. K., Thermochimica Acta, 367-368, pp. 185-188, 2001. https://doi.org/10.1016/S0040-6031(00)00668-7
  2. Albert S. Tompa, William F. Bryant Jr, Thermochimica Acta 367-368, pp. 433-441, 2001. https://doi.org/10.1016/S0040-6031(00)00674-2
  3. Davis D. D., Wedlich R. C., Thermochimica Acta, Vol. 171(1), pp. 1-13, 1990. https://doi.org/10.1016/0040-6031(90)87001-S
  4. Elmqvist C. J., Lagerkvist P. E., Svensson L. G., Journal of Hazardous Materrials, Vol. 7(3), pp. 281-290, 1983. https://doi.org/10.1016/0304-3894(83)80017-X
  5. Ottaway M. R., Granville R. J., Symp. Chem, Probl, Connected Stab. Explos., Vol. 8, pp. 1-14, 1988.
  6. Rothgery S. F., Audette D. E., Wedlich R. C., Thermochimica Acta, Vol. 185(2), p. 235, 1991. https://doi.org/10.1016/0040-6031(91)80045-K
  7. R. F. Boswell a.s. tompa, CPIA Publ., Vol. 588, pp. 97, 1992.
  8. R. F. Boswell a.s. tompa, CPIA Publ., Vol. 597, pp. 301, 1993.
  9. A. A. Elabbar, M. Abu El-Oyoun, and A. A. Abu-Sehly, JTUSCI, Vol. 1, pp. 44-50, 2008.
  10. Jae-Young Lee, Mi-Ja Shim, and Sang-Wook Kim, J. of Korean Ind & Eng. Chemistry, Vol. 5(4), pp. 731-736, August 1994.
  11. S. Vyazovkin., Jounal of Thermal Analysis, Vol. 49, pp. 1493-1499, 1997. https://doi.org/10.1007/BF01983708
  12. M, Fathollahi., S. M. Pourmortazavi. and S. G. Hosseini., Journal of Energetic Materials, Vol. 26, pp. 52-69, 2008.
  13. Yang, L., et al., Chinese Journal of Chemistry, Vol. 22, pp. 1219-1224, 2004.