• Title/Summary/Keyword: Gas to Liquids

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Cooling of Cryogenic Liquids by Gas Helium Injection (I) (가스분사에 의한 극저온 액체의 냉각에 관한 연구 (I))

  • Song, Yi-Hwa;Choi, Young-Hwan;Kim, Yoo;Chung, Yong-Gahp;Cho, Nam-Kyung;Jeong, Sang-Kwon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2003.10a
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    • pp.141-144
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    • 2003
  • In this paper, to satisfy the temperature requirement of turbopump-inlet condition, the cooling of cryogenic propellant is performed at the simulated suction-line of the Launch Vehicle. The cooling method is by using Gas helium injection. This study investigates the effect of helium injection on the liquid nitrogen which simulates the liquid oxygen. By using helium injection, the subcooling of liquid nitrogen can be achieved within four minute when the ratio of gas volume flowrate to the volume of L$N_2$ is approximately v/v$_{L}$≒0.8min$^{-1}$ . .

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Poly (vinyl acetate)-Ionic Liquids Membranes for $CO_2$ Capture (이산화탄소 포집용 폴리비닐아세테이트-이온성액체 막)

  • Lee, Sang-Jin;Choe, Su-Hyeon;Baek, Il-Hyeon
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2010.04a
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    • pp.199-199
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    • 2010
  • Polymeric membranes have been widely used to separate gas mixtures, such as $O_2/N_2,\;CO_2/CH_4,\;CO_2/N_2$, and olefin/paraffin. The permeation selectivity is the ratio between composition ratio at the permeate side and composition ratio at the feed side. In addition, the permeation selectivity is a product of solubility selectivity and diffusivity selectivity. We present a novel idea and describe its experimental result, which was achieved by preparing polymer gel films that included a room temperature ionic liquid (RTIL) in a polymer matrix. It is known that $CO_2$ can dissolve easily in imidazolium-based RTILs. We prepared polymer-ionic liquid gel films using an ionic liquid, 1-ethyl-3-methylimidazolium acetate ([emim] acetate, C-tri) and a host polymer, poly (vinyl acetate) (PVAc, Aldrich).

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Recovery of Toluene in gas by Polydimethylsiloxane/silica hybrid membrane permeation

  • Xu, De-Lin;Chung, Wook-jin;Jung, Bum-Suk;Gun, Eun-Mi;Ariz Lorenzana
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05b
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    • pp.176-179
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    • 2004
  • Volatile organic compounds (VOCs) are emitted as gases from certain solids or liquids. VOCs include a variety of chemicals, some of which may have short- and long-term adverse health effects. Current technologies for the treatment of VOC contaminated off-gasses are expensive to operate and more cost effective technologies are needed.(omitted)

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A Study on the Prevention Measures against Fire and Explosion Accidents during Splash Filling in Batch Process (회분식 공정에서 스플래쉬 필링(Splash Filling) 작업으로 인한 화재·폭발 사고 예방대책에 관한 연구)

  • Kim, Sang Ryung;Lee, Dae Jun;Kim, Jung Duk;Kim, Sang Gil;Yang, Won Baek;Rhim, Jong Guk
    • Journal of the Korean Institute of Gas
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    • v.24 no.3
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    • pp.33-39
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    • 2020
  • In general, in a batch reaction process in which products are made using flammable liquids, splash filling is used to clean the walls of the reactor by spraying flammable liquids, which are raw materials used for product, during cleaning of the reactor after work. During this process, mist of flammable liquid is generated, the lower limit of explosion is lowered, and fire·explosion may occur due to discharges caused by various types of complex charges, such as flow charge, collision charge, and ejection charge. Therefore, based on the recent accident case, to identify the risk when working in the form of splash filling with toluene in a batch process and perform an explosion impact analysis using the TNT equivalent method After that, we will analyze the accident results and suggest preventive measures such as constant purge system, improvement of cleaning method, and use of tantalum to prevent such accident.

The Characteristics of Exhaust Gas Emissions with GTL Fuel (GTL연료의 배출가스 특성 연구)

  • Gwoak, Soon-Chul;Seo, Chung-Yul;Kang, Dae-Il;Park, Jung-Min;Yim, Yoon-Sung;Hwan, Chun-Sik;Eom, Myoung-Do;Kim, Jong-Choon;Lee, Young-Jae;Pyo, Young-Dug;Jung, Choong-Sub;Jang, Eun-Jung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.6
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    • pp.17-22
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    • 2007
  • GTL(Gas-to-Liquids) fuel technology was converted from the natural gas, coal and biomass into the diesel or kerosene by Fisher-Tropsch synthesis. GTL fuel have very good merits on high cetane number, low density, free sulfur, lower aromatics contents and no poly-aromatic hydrocarbons as well as the autoignition characteristics. These physical properties make it valuable as a diesel fuel with lower emissions than the conventional diesel fuel. Furthermore, GTL fuel can be use not to the engine any modification. Therefore, to evaluate emissions of GTL fuel, the tested diesel vehicles were fueled on blends of GTL fuel/ultra low sulfur diesel fuel(ULSD). And then, we found out that GTL fuel reduced regulated emissions(CO, NOx, HC, PM) compare with conventional diesel fuel.

Determination of Capsaicin, Dihydrocapsaicin and Nonivamide by Gas Chromatography (기체크로마토그래피에 의한 캡사이신, 디하이드로캡사이신 및 노니바마이드(PAVA)의 정량)

  • Kim, Sang-Soo;Yoon, Joong-Soo
    • Journal of the Health Care and Life Science
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    • v.9 no.1
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    • pp.141-146
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    • 2021
  • Determination of capsaicin, dihydrocapsaicin and nonivamide in pungent liquids of self-defense spray were studied. The nonivamide having almost same spicy taste with capsaicin have been containing a few amounts in natural products, it had called as synthetic capsaicin or PAVA, have used to flavorings for foodstuffs and incapacitating agents of riot controls. Nowadays, it has been occasionally found that the quality controls of a self-defense sprays were not properly due to flood of illegal self-defense sprays. Thus, the simple analytical method with gas chromatography is developed, it is identified whether the products which have contained synthetic capsaicin were marked like natural materials as well as the pungent ingredients in it obeyed with permissible concentration to human or not was investigated. Finally, the pungent components and amounts in some kinds of self-defense spray were investigated.

Solubility of Hydrogen Sulfide and Methane in Ionic Liquids: 1-Ethy-3-methylimidazolium Trifluoromethanesulfonate and 1-Butyl-1-methylpyrrolidinium Trifluoromethanesulfonate (1-Ethyl-3-methylimidazolium trifluoromethanesulfonate와 1-Butyl-1-methylpyrrolidinium trifluoromethanesulfonate 이온성 액체에 대한 황화수소와 메탄의 용해도)

  • Lee, Byung-Chul
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.213-222
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    • 2016
  • Solubility data of hydrogen sulfide ($H_2S$) and methane ($CH_4$) in two kinds of ionic liquids with the same anion: 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([emim][TfO]) and 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate ([bmpyr][TfO]) are presented at pressures up to about 30 MPa and at temperatures between 303 K and 343 K. The gas solubilities in ionic liquids were determined by measuring the bubble point pressures of the gas + ionic liquid mixtures with various compositions at different temperatures using a high-pressure equilibrium apparatus equipped with a variable-volume view cell. The $H_2S$ solubilities in ionic liquid increased with the increase of pressure and decreased with the increase of temperature. On the other hand, the $CH_4$ solubilities in ionic liquid increased significantly with the increase of pressure, but there was little effect of temperature on the $CH_4$ solubility. For the ionic liquds [emim][TfO] and [bmpyr][TfO] with the same anion, the solubility of $H_2S$ as a molality basis was substantially similar, regardless of the temperature and pressure conditions as a molar concentration basis. Comparing the solubilities of $H_2S$ and $CH_4$ in the ionic liquid [emim][TfO], the solubilities of $H_2S$ were much greater than those of $CH_4$. For the same type of ionic liquid, the solubility data of $H_2S$ and $CH_4$ obtained in this study were compared to the solubility data of $CO_2$ from the literature. When compared at the same pressure and temperature conditions, the $CO_2$ solubility was in between the solubility of $H_2S$ and $CH_4$.

Advanced Alignment-Based Scheduling with Varying Production Rates for Horizontal Construction Projects

  • Greg Duffy;Asregedew Woldesenbet;David Hyung Seok Jeong;Garold D. Oberlender
    • International conference on construction engineering and project management
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    • 2013.01a
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    • pp.403-411
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    • 2013
  • Horizontal construction projects such as oil and gas pipeline projects typically involve repetitive-work activities with the same crew and equipment from one end of the project to the other. Repetitive scheduling also known as linear scheduling is known to have superior schedule management capabilities specifically for such horizontal construction projects. This study discusses on expanding the capabilities of repetitive scheduling to account for the variance in production rates and visual representation by developing an automated alignment based linear scheduling program for applying temporal and spatial changes in production rates. The study outlines a framework to apply changes in productions rates when and where they will occur along the horizontal alignment of the project and illustrates the complexity of construction through the time-location chart through a new linear scheduling model, Linear Scheduling Model with Varying Production Rates (LSMVPR). The program uses empirically derived production rate equations with appropriate variables as an input at the appropriate time and location based on actual 750 mile natural gas liquids pipeline project starting in Wyoming and terminating in the center of Kansas. The study showed that the changes in production rates due to time and location resulted in a close approximation of the actual progress of work as compared to the planned progress and can be modeled for use in predicting future linear construction projects. LSMVPR allows the scheduler to develop schedule durations based on minimal project information. The model also allows the scheduler to analyze the impact of various routes or start dates for construction and the corresponding impact on the schedule. In addition, the graphical format lets the construction team to visualize the obstacles in the project when and where they occur due to a new feature called the Activity Performance Index (API). This index is used to shade the linear scheduling chart by time and location with the variation in color indicating the variance in predicted production rate from the desired production rate.

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Eigenfunctions for Liouville Operators, Classical Collision Operators, and Collision Bracket Integrals in Kinetic Theory Made Amenable to Computer Simulations

  • Eu, Byung-Chan
    • Bulletin of the Korean Chemical Society
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    • v.33 no.3
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    • pp.779-789
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    • 2012
  • In the kinetic theory of dense fluids the many-particle collision bracket integral is given in terms of a classical collision operator defined in the phase space. To find an algorithm to compute the collision bracket integrals, we revisit the eigenvalue problem of the Liouville operator and re-examine the method previously reported [Chem. Phys. 1977, 20, 93]. Then we apply the notion and concept of the eigenfunctions of the Liouville operator and knowledge acquired in the study of the eigenfunctions to cast collision bracket integrals into more convenient and suitable forms for numerical simulations. One of the alternative forms is given in the form of time correlation function. This form, on a further manipulation, assumes a form reminiscent of the Chapman- Enskog collision bracket integrals, but for dense gases and liquids as well as solids. In the dilute gas limit it would give rise precisely to the Chapman-Enskog collision bracket integrals for two-particle collision. The alternative forms obtained are more readily amenable to numerical simulation methods than the collision bracket integrals expressed in terms of a classical collision operator, which requires solution of classical Lippmann-Schwinger integral equations. This way, the aforementioned kinetic theory of dense fluids is made fully accessible by numerical computation/simulation methods, and the transport coefficients thereof are made computationally as accessible as those in the linear response theory.

A Study of Mechanical Characteristics at Room/Cryogenic Temperature of Powder Insulation Materials Applied to Type C Fuel Tank (Type C 연료탱크에 적용되는 분말형 단열 소재의 상온/극저온 기계적 특성에 관한 연구)

  • Kim, Tae-Wook;Oh, Jae-Won;Seo, Young-Kyun;Han, Seong-Jong;Lee, Jae-Myung
    • Journal of the Korean Society of Industry Convergence
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    • v.24 no.6_2
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    • pp.787-793
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    • 2021
  • The global demand for Liquefied Natural Gas(LNG) continues to increase and is facing a big cycle. To keep pace with the increase in international demand for LNG, the demand for LNG fueled ships is also increasing. Since LNG fuel tanks are operated in a cryogenic environment, insulation technology is very important, and although there are various types of insulation applied to Type C tanks, multi-layer insulation and vacuum insulation are typically applied. Powder insulation materials are widely used for storage and transportation of cryogenic liquids in tanks with such a complex insulation structure. In this study, compression tests at room and cryogenic temperature were performed on closed perlite, glass bubble, and fumed silica, which are representative powder insulation material candidates. Finally, the applicability to the Type C fuel tank was reviewed by analyzing the experimental results of this study.