• Title/Summary/Keyword: Electrode density

Search Result 1,175, Processing Time 0.024 seconds

Micro-electrochemical Characteristics of Sensitized 304 Stainless steel Using Micro-droplet cell Techniques (마이크로 드로플릿 셀 기법을 이용한 예민화 된 304 스테인리스강의 미세전기화학 특성)

  • Kim, Kyu-Seop;Lee, Jae-Bong
    • Corrosion Science and Technology
    • /
    • v.9 no.6
    • /
    • pp.300-309
    • /
    • 2010
  • The influences of sensitization on localized corrosion resistance of 304 stainless steel, were investigated, using micro-dropletcell techniques. Micro-droplet cell allows one to align the micro-electrode to the desired spot of the working electrode and measure directly local current with the potentiodynamic polarization, linear polarization and a.c. impedance. Micro-electrochemical tests were carried out inside of the grain and on grain boundaries separately. It was found that sensitization decreased the pitting potential, increasing corrosion current density around grain boundaries. Galvanic current density was also measured between grain and grain boundaries.

Ferroelectric Properties of SBT Capacitors with Annealing Conditions (SBT 커패시터의 열처리 조건에 따른 강유전 특성)

  • Lee, Sung-Ill
    • Journal of the Korean Society of Safety
    • /
    • v.19 no.1
    • /
    • pp.72-76
    • /
    • 2004
  • The $Sr_{0.7}Bi_{2.6}Ta_2O_9$(SBT)thin films are deposited on pt-coated electrode(Pt/$TiO_2/SiO_2/Si$) using a RF magnetron sputtering method. The electrical properties of SBT capacitors with annealing conditions were studied. In the XRD pattern, the SBT thin films in all annealing temperatures had (105) orientation. In the SEM images, Bi-layered perovskite phase was crystallized at $750^{\circ}C$,/TEX> and grains largely grew in oxygen annealing atmosphere. The maximum renanent polarization and the coercive electric field with annealing conditions are 12.40C/$cm^2$ and 30kV/cm, respectively. The dielectric constant and leakage current density with Pt electrode is 340 and 2.13${\times}10^{-10}A/cm^2$, respectively.

Extreme Ultraviolet Plasma and its Emission Characteristics Generated from the Plasma Focus in Accordance with Gas Pressure for Biological Applications

  • Kim, Jin Han;Lee, Jin Young;Kim, Sung Hee;Choi, Eun Ha
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.08a
    • /
    • pp.178.2-178.2
    • /
    • 2013
  • Conventional ultraviolets A,B,C are known to be very important factor of killing, changing surface properties of biological cells and materials. It is of great importance to investigate the influence of extreme ultraviolet (EUV) exposure on the biological cell. Here we have studied high density EUV plasma and its emission characteristics, which have been generated by plasma focus device with hypercycloidal pinch (HCP) electrode under various Ar gas pressures ranged from 30~500 mTorr in this experiment. We have also measured the plasma characteristics generated from the HCP plasma focus device such as electron temperature by the Boltzman plot, plasma density by the Stark broading method, discharge images by open-shuttered pin hole camera, and EUV emission signals by using the photodiode AXUV-100 Zr/C.

  • PDF

Design of Structured Electrode for High Energy Densified and Fast Chargeable Lithium Ion Batteries (전극구조설계 기반 고에너지밀도·고속충전 리튬이온배터리 제작)

  • Park, Sujin;Bae, Chang-Jun
    • Ceramist
    • /
    • v.21 no.4
    • /
    • pp.406-415
    • /
    • 2018
  • Lithium ion batteries have been widely adopted as energy storage and the LIB global market has grown fastest. However, LIB players have struggled against maximizing energy density since commercial monolithic electrodes are limited by electrolyte depletion caused by long and tortuous Li-ion diffusion pathways. Recently, new strategies designing the structure of battery electrodes strive for creating fast Li-ion path and alleviating electrolyte depletion problem in monolithic electrodes. In this paper, given the fundamental and experimental approaches, we compare the monolithic to structured electrodes and demonstrate the ways to fabricate high energy, fast chargeable Lithium ion battery.

Electrocatalytic Reduction of Carbon Dioxide on Sn-Pb Alloy Electrodes

  • Choi, Song Yi;Jeong, Soon Kwan;Park, Ki Tae
    • Journal of Climate Change Research
    • /
    • v.7 no.3
    • /
    • pp.231-236
    • /
    • 2016
  • Electrocatalytic reduction can produce useful chemicals and fuels such as carbon monoxide, methane, formate, aldehydes, and alcohols using carbon dioxide, the green house gas, as a reactant through the supply of electrical energy. In this study, tin-lead (Sn-Pb) alloy electrodes are fabricated by electrodeposition on a carbon paper with different alloy composition and used as cathode for electrocatalytic reduction of carbon dioxide into formate in an aqueous system. The prepared electrodes are measured by Faradaic efficiency and partial current density for formate production. Electrocatalytic reduction experiments are carried out at -1.8 V (vs. Ag/AgCl) using H-type cell under ambient temperature and pressure and the gas and liquid products are analyzed by gas chromatograph and liquid chromatograph, respectively. As results, the Sn-Pb electrodes show higher Faradaic efficiency and partial current density than the single metal electrode. The Sn-Pb alloy electrode which have Sn:Pb molar ratio=2:1, shows the highest Faradaic efficiency of 88.7%.

Ni Foam-Supported Ni Nanoclusters for Enhanced Electrocatalytic Oxygen Evolution Reaction

  • Hoeun Seong;Jinhee Kim;Kiyoung Chang;Hyun-woo Kim;Woojun Choi;Dongil Lee
    • Journal of Electrochemical Science and Technology
    • /
    • v.14 no.3
    • /
    • pp.243-251
    • /
    • 2023
  • Developing oxygen evolution reaction (OER) electrocatalysts is essential to accomplish viable CO2 and water electrolysis. Herein, we report the fabrication and OER performance of Ni-foam (NF)-immobilized Ni6 nanoclusters (NCs) (Ni6/NF) prepared by a dip-coating process. The Ni6/NF electrode exhibited a high current density of 500 mA/cm2 for the OER at an overpotential as low as 0.39 V. Ni6/NF exhibited high durability in an alkaline solution without corrosion. Electrokinetic studies revealed that OER can be easily initiated on Ni6 NC with fast electron-transfer rates. Finally, we demonstrated stable CO2-to-CO electroreduction using an NC-based zero-gap CO2 electrolyzer operated at a current density of 100 mA/cm2 and a full-cell potential of 2.0 V for 12 h.

Analysis of Initial Stage of Copper Electrodeposition for Fine Pattern (미세패턴용 구리도금시 초기 전착 거동 해석)

  • 조차제;최창희;김상겸;박대희
    • The Transactions of the Korean Institute of Electrical Engineers C
    • /
    • v.52 no.4
    • /
    • pp.164-168
    • /
    • 2003
  • The initial stage of copper electrodeposition has been known to be very important role for morphology and physical properties after final growth. The factors affecting the nucleation are electrode, current density, electrolyte and temperature. Current studies has illuminated the initial nucleation of copper electrodeposition in the viewpoint of the surface status of electrode and analyzed using EIS and SEM observation

An Electrolytic Treatment of Shipboard Sewage by Using DSA Electrode (I) -Batch Electrolytic Treatment- (DSA 전극에 의한 선박오폐수의 전해처리(I)-회분식 전해처리-)

  • 김인수;조권희;남청도
    • Journal of the Korean Society of Marine Environment & Safety
    • /
    • v.3 no.2
    • /
    • pp.69-76
    • /
    • 1997
  • Each factor for the most effective electrolytic reaction in treating shipboard sewage was enhanced by means of batch electrolyitc reactor using DSA electrode. The effective clearance was 6mm and pH was 5-6. In such case, more than 20% of sea water concentration was needed to attain 90% of COD removal rate. The suspended solids was effectively removed by electro-floatation in proportion as charged current density. The nitrogen and posporous were effectively removed in the electrolytic device when mixed seawater.

  • PDF

Characteristics of Carbon Thin Film Using Electrochemical Method (Carbon Film 전기적 특성)

  • Lee, Sang-Heon;Choi, Yong
    • Proceedings of the KIEE Conference
    • /
    • 2007.11a
    • /
    • pp.126-127
    • /
    • 2007
  • In this study, the fabrication technique of a plannar field emission structure with DLC were studied Electric properties of carbon film on silicon substrate in methanol solution was carried out with various current density, solution temperature and electrode spacing between anode and cathode. The DLC film deposited on the Si substrate, plannar $SiO_2$ was obtained due to the shape of bottom electrode.

  • PDF