• Title/Summary/Keyword: Effects of Mo

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Design of Advanced Weathering Steel with High Corrosion Resistance for Structural Applications

  • Choi, B.K.;Jung, H.G.;Yoo, J.Y.;Kim, K.Y.
    • Corrosion Science and Technology
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    • v.4 no.4
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    • pp.121-129
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    • 2005
  • Basic design concept of the future steel structure requires environmental compatibility and maintenance free capability to minimize economic burdens. Recent trends in alloy design for advanced weathering steel include addition of various alloying elements which can enhance formation of stable and protective rust layer even in polluted urban and/or high $Cl^{-}$ environment. The effects of Ca, Ni, W, and Mo addition on the corrosion property of Ca-modified weathering steel were evaluated through a series of electrochemical tests (pH measurement and electrochemical impedance spectroscopy: EIS) and structural analysis on rust layer formed on the steel surface. Ca-containing inclusions of Ca-Al-Mn-O-S compound are formed if the amount of Ca addition is over 25 ppm. Steels with higher Ca content results in higher pH value for condensed water film formed on the steel surface, however, addition of Ni, W, and Mo does not affect pH value of the thin water film. The steels containing a high amount of Ca, Ni, W and Mo showed a dense and compact rust layer with enhanced amount of ${\alpha}-FeOOH$. Addition of Ni, W and Mo in Ca-modified weathering steel shows anion-selectivity and contributes to lower the permeability of $Cl^{-}$ ions. Effect of each alloying element on the formation of protective rust layer will be discussed in detail with respect to corrosion resistance.

Extension of Shelf Life of Kimchi by Addition of Encapsulated Mustard Oil

  • Kim, Mi-Jeong;Ha, Jee-Yun;Yun, Ye-Rang;Noh, Jeong-Sook;Song, Yeong-Bok;Song, Yeong-Ok
    • Food Science and Biotechnology
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    • v.15 no.6
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    • pp.884-888
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    • 2006
  • In this study, we have attempted to characterize the effects of encapsulated mustard oil with regard to the extension of the shelf life of kimchi. The quantity of mustard oil or encapsulated mustard oil added to the brined cabbage in this study was 0.05%(w/w). Overall, the fermentation processes in the encapsulated mustard oil-added kimchi (EMO) and mustard oil-added kimchi (MO) occurred at a slower rate than in the controls. The periods during which the MO and EMO kimchi samples were edible were prolonged for more than two weeks, according to measurements of pH, total acidity, and microbial changes. The overall acceptability of EMO was superior to MO throughout the entirety of the fermentation period. Sensory evaluation verified that EMO yielded a more favorable product than the MO and control varieties. Encapsulated mustard oil can be employed as a natural food additive to prolong the shelf life of kimchi, via an induced delay of the fermentation process.

Effects of the Alloying Elements and Special Heat Treatment on the Multi-phase (Ferrite-Bainite-Martensite), Strength and Toughness in Ductile Cast Iron (구상흑연주철(球狀黑鉛鑄鐵)의 혼합조직(混合組織) 및 강인성(强靭性)에 미치는 합금원소(合金元素)와 특수열처리(特殊熱處理)의 영향(影響))

  • Kim, Sug-Won;Lee, Eui-Kweon;Sim, Jae-Hwan
    • Journal of Korea Foundry Society
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    • v.13 no.5
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    • pp.432-440
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    • 1993
  • Ductile cast iron has a good ductility and toughness than those of gray cast iron, because the shape of graphite is spheroidal. Also, it has been reported that, additional strengthening and toughening of the ductile cast iron can be obtainded from the proper combination of matrix structures by the heat treatment and addition of alloying elements. In this study the effect of special heat treatment and addition of alloying elements(Ni, Mo) on the multi-phase(ferrite-bainite-martensite) structures, strength and toughness of ductile cast iron were studied systematically. In water quenching from $770^{\circ}C$, the martensite volume(%) increased, but the ferrite volume(%) decreased with increment of Ni content. In as cast, pearlite volume(%) and hardness increased with increment of Mo and Ni contents. And with the increment of the destabilization austempering holding time, the bainite volume(%) increased but the martensite volume(%) decreased. As destabilization austempering holding time is same, bainite volume(%) decreased, martensite increased with the increment of Ni and Mo contents. The hardness and tensile strength decreased, but impact energy increased with the decrease of Ni and Mo contents, and increment of holding time of destabilization austempering treatment.

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Microstructures and Mechanical Properties of Beryllium(Be)-free Ni-Cr-Mo based Alloys for Metal-Ceramic Crown (베릴륨(Be)이 미 첨가된 치과도재소부용 Ni-Cr-Mo계 합금의 미세조직 및 기계적 성질 특성)

  • Song, Kyung-Woo;Go, Eun-Kyoung;Lee, Jung-Hwan;Jung, Jong-Hyun;Noh, Hak;Han, Jae-Ick
    • Journal of Technologic Dentistry
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    • v.28 no.2
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    • pp.321-329
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    • 2006
  • The popularity of Ni-Cr-Mo based metal alloys for metal-ceramic crown have increased recently because of low price, superior yield strength and rigidity. the use of these alloys give them the potential advantage of thinner copping with the required rigidity for long span bridges. The purpose of this study was to assess the microstructures and mechanical properties of Ni-Cr-Mo-(Si,Al,Nb,Zr,Ti.Cu,Mm) based Alloys not containing beryllium(Be) related toxic effects. The abtained results indicated that as-cast these specimen alloys showed compositional and microstructural differences, and mechanical properties values of Ni69Cr20Mo5Si2Al4 alloy among these specimen alloys was found to be superior to those of commercial Ni-Cr based alloy using in market place today.

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The Effect of Rapid Consolidation of Nanostructured MoSi2-SiC Composite on its Mechanical Properties (나노구조 몰리브덴늄실리사이드-실리콘카바이드 복합재료의 급속소결과 기계적 성질)

  • Ko, In-Yong;Chae, Seung-Myoung;Shon, In-Jin
    • Korean Journal of Metals and Materials
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    • v.48 no.5
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    • pp.417-423
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    • 2010
  • A dense nanostructured MoSi$_{2}$-SiC composite was synthesized by a pulsed current activated combustion synthesis method within 2 min of one step from mechanically activated powders of Mo$_{2}$C and Si. Simultaneous combustion synthesis and consolidation were accomplished under the combined effects of a pulsed current and mechanical pressure. Highly dense MoSi$_{2}$-SiC with a relative density of up to 98% was produced under simultaneous application of an 80 MPa pressure and pulsed current. The average grain size and mechanical properties of the composite were investigated.

Effects of Tungsten Addition on Tensile Properties of a Refractory Nb-l8Si-l0Ti-l0Mo-χW (χ=0, 5, 10 and 15 mot.%) In-situ Composites at 1670 K

  • 김진학;Tatsuo Tabaru;Hisatoshi Hirai
    • Transactions of Materials Processing
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    • v.8 no.3
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    • pp.233-233
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    • 1999
  • To investigate the effect of tungsten addition on mechanical properties, we prepared refractory (62χ)Nb-18Si-l00Mo-l0Ti-χW (χ=0, 5, 10 and 15 mol.%) in-situ composites by the conventional arc-casting technique, and then explored the microstructure, hardness and elastic modulus at ambient temperature and tensile properties at 1670 K. The microstructure consists of relatively fine (Nb, Mo, W, Ti)/sub 5/Si₃, silicide and a Nb solid solution matrix, and the fine eutectic microstructure becomes predominant at a Si content of around 18 mol.%. The hardness of (Nb, Mo, W, Ti(/sub 5/Si₃, silicide in a W-free sample is 1680 GPa, and goes up to 1980 GPa in a W 15 mol.% sample. The hardness, however, of Nb solid solution does not exhibit a remarkable difference when the nominal W content is increased. The elastic modulus shows a similar tendency to the hardness. The optimum tensile properties of the composites investigated are achieved at W 5 mol.% sample, which exhibits a relatively good ultimate strength of 230 MPa and an excellent balance of yield strength of 215 MPa, and an elongation of 3.7%. The SEM fractography generally indicates a ductile fracture in the W-free sample, and a cleavage rupture in W-impregnated ones.

A mesoscale stress model for irradiated U-10Mo monolithic fuels based on evolution of volume fraction/radius/internal pressure of bubbles

  • Jian, Xiaobin;Kong, Xiangzhe;Ding, Shurong
    • Nuclear Engineering and Technology
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    • v.51 no.6
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    • pp.1575-1588
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    • 2019
  • Fracture near the U-10Mo/cladding material interface impacts fuel service life. In this work, a mesoscale stress model is developed with the fuel foil considered as a porous medium having gas bubbles and bearing bubble pressure and surface tension. The models for the evolution of bubble volume fraction, size and internal pressure are also obtained. For a U-10Mo/Al monolithic fuel plate under location-dependent irradiation, the finite element simulation of the thermo-mechanical coupling behavior is implemented to obtain the bubble distribution and evolution behavior together with their effects on the mesoscale stresses. The numerical simulation results indicate that higher macroscale tensile stresses appear close to the locations with the maximum increments of fuel foil thickness, which is intensively related to irradiation creep deformations. The maximum mesoscale tensile stress is more than 2 times of the macroscale one on the irradiation time of 98 days, which results from the contributions of considerable volume fraction and internal pressure of bubbles. This study lays a foundation for the fracture mechanism analysis and development of a fracture criterion for U-10Mo monolithic fuels.

Effect of Welding Heat Input and PWHT Cooling Rate on Mechanical Properties of Welded Region at SAW of 1.25Cr-0.5Mo Steel for Pressure Vessel (압력용기용 1.25Cr-0.5Mo 강의 Submerged Arc Welding시 입열 및 PWHT 냉각속도가 용접부 기계적 성질에 미치는 영향)

  • Lee Dong-Hwan;Park Jong-Jin
    • Journal of Welding and Joining
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    • v.22 no.5
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    • pp.26-31
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    • 2004
  • In order to propose the optimum welding condition for field application, the effects of welding heat input and cooling rate at PWHT on the mechanical properties were investigated. Submerged arc welding of 1.25Cr-0.5Mo steel for pressure vessel was conducted at welding heat inputs of 15.2kJ/cm, 30.9kJ/cm, and 44.8kJ/cm, and cooling rates of 184$^{\circ}C$/hr, 55$^{\circ}C$/hr, and 2$0^{\circ}C$/hr at PWHT. From the test results, as the welding heat input increase up to 30.9kJ/cm, the changes of microstructure and impact toughness were small. At the heat input of 44.8kJ/cm, however, toughness decreased obviously due to the coarsening of coarse-grained HAZ and formation of ferrite at bainite grainboundary of weld metal. On the other hand, cooling rates at PWHT did not effect on the changes in microstructure and mechanical properties. Even though tensile strength and impact toughness at all welding conditions of this study were above the minimum specification requirement, it was confirmed that heat input of 30.9kJ/cm was the optimum welding condition to improve welding performance by higher heat input.

Quantitative Investigation of Grain Growth in Carbide Added(Mo$_2$C, ZrC and WC) to TiC-Ni Matrix Cermets

  • Kim, Soon-Ho
    • International Journal of Precision Engineering and Manufacturing
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    • v.5 no.1
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    • pp.19-26
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    • 2004
  • The growth of solid particles in TiC-XC-2vo1.% and TiC-XC-30vo1.% Ni alloys, (where X=Zr, W or Mo) was fitted to the equation of the form $d^3$-${do}^3$=Kt during the liquid phase sintering at 1,673K. Also, the grain growth behavior decreased markedly with the addition of ${MO}_2$C or WC and increased with the addition of zrC. The contiguity was greater in the alloys with a smaller growth rate constant and especially, decreased by increasing the Ni content in the TiC-${MO}_2$C-Ni alloy. In addition, the effect of the addition of carbide on the grain growth of 2 vo1.% Ni alloys was found to be similar to that of 30vo1.% Ni alloys. Consequently, the grain growth mechanism cannot be explained by the usual solution / reprecipitation process, but can be explained in terms of a new growth velocity equation, which includes the effects of contiguous carbide grain boundaries in restricting the overall grain growth, as well as the area of the solid / liquid interface in the alloy.