• Title/Summary/Keyword: Double layer capacitor

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Electrochemical Properties of Electric Double Layer Capacitor with PolyanilineComposite (Polyaniline Composite 전극을 사용한 전기 이중층 캐패시터의 전기화학적 특성)

  • 강광우;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.370-373
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    • 1999
  • The purpose of this study is to research and develop PAn composite electrode for EDLC. EDLC cell of PAn composite electrode with 1M LiClO$_4$/PC brings out good capacitor performance below 4.0V. The radius of semicircle of PAn composite electrode adding 15wt% SP270 was absolutely small. The total resistance of EDLC cell mainly depended on internal resistance of the electrode. The discharge capacitance of PAn composite with 15wt% SP270 in 1st and 200th cycles was 42 and 42 F/g at current density of 1mA/cm$^2$. The capacitance of PAn composite with 15wt%. SP270 capacitor was larger than that of PAn capacitor without SP270. The coulombic efficiency of EDLC at discharge process of 1 and 200 cycles were 94 and 100% respectively. PAn composite EDLC with 15wt% SP270 content showed good capacitance and stability with cycling.

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Power Balancing Control Method of A Residential Distributed Generation System using Photovoltaic Power Generation and Polymer Electrolyte Fuel Cells (PV와 PEFC를 병용한 가정용 분산 전원 시스템의 전력평준화 제어법)

  • Yoon, Young-Byun;Mun, Sang-Pil;Park, Han-Seok;Woo, Kyung-Il
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.65 no.4
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    • pp.335-339
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    • 2016
  • Output power in photovoltaic systems changes steeply with the change of the sun intensity. The change of output power has influence on the electric power quality of the system. This paper proposes a residential distributed generation system using photovoltaic power generation and polymer electrolyte fuel cells(hybrid systems). In order to level the output power which changes steeply the polymer electrolyte fuel cells are connected to the photovoltaic power generation system in parallel. Thus the generated power of all the system can be leveled. However, the steep generated power in the photovoltaic power generation system can not be leveled. Therefore, the electric double layer capacitor(EDLC) is connected in parallel with the hybrid systems. It is confirmed by the simulation that the proposed distributed generation system is available for a residential supply.

An Accelerated Degradation Test of Electric Double-Layer Capacitors (전기이중층커패시터의 가속열화시험)

  • Jung, Jae-Han;Kim, Myung-Soo
    • Journal of Applied Reliability
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    • v.12 no.2
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    • pp.67-78
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    • 2012
  • An electric double-layer capacitor(EDLC) is an electrochemical capacitor with relatively high energy density, typically hundreds of times greater than conventional electrolytic capacitors. EDLCs are widely used for energy storage rather than as general-purpose circuit components. They have a variety of commercial applications, notably in energy smoothing and momentary-load devices, and energy-storage and kinetic energy recovery system devices used in vehicles, etc. This paper presents an accelerated degradation test of an EDLC with rated voltage 2.7V, capacitance 100F, and usage temperature $-40^{\circ}C{\sim}65^{\circ}C$. The EDLCs are tested at $50^{\circ}C$, $60^{\circ}C$, and $70^{\circ}C$, respectively for 1,750hours, and their capacitances are measured at predetermined times by constant current discharge method. The failure times are predicted from their capacitance deterioration patterns, where the failure is defined as 30% capacitance decrease from the initial one. It is assumed that the lifetime distribution of EDLC follows Weibull and Arrhenius life-stress relationship holds. The life-stress relationship, acceleration factor, and $B_{10}$ life at design condition are estimated by analyzing the accelerated life test data.

Study on Vibration Energy Harvesting with Small Coil for Embedded Avian Multimedia Application

  • Nakada, Kaoru;Nakajima, Isao;Hata, Jun-ichi;Ta, Masuhisa
    • Journal of Multimedia Information System
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    • v.5 no.1
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    • pp.47-52
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    • 2018
  • We have developed an electromagnetic generator to bury in subcutaneous area or abdominal cavity of the birds. As we can't use a solar battery, it is extremely difficult to supply a power for subcutaneous implantation such as biosensors under the skin due to the darkness environment. We are aiming to test the antigen-antibody reaction to confirm an avian influenza. One solution is a very small generator with the electromagnetic induction coil. We attached the developed coil to chickens and pheasants and recorded the electric potential generated as the chicken walked and the pheasant flew. The electric potential generated with physical simulator is equal to or exceeds the 7 V peak-to-peak at maximum by 560/min of flapping of wings. Even if we account for the junction voltage of the diode (200 mV), efficient charging of the double-layer capacitor is possible with the voltage doubler rectifier. If we increase the voltage, other problems arise, including the high-voltage insulation of the double-layer capacitor. For this reason, we believe the power generated to be sufficient for subcutaneous area of birds. The efficiency, magnetic 2 mm in length and coil 15mm in length, if axial direction is rectified, the magnetic flux density given to the coil could calculated to 7.1 % and generated power average 0.47mW. The improvements in size and wire insulation are expected in the future.

Evaluation of Electrochemical Stability of Graphite Current Collector for Electric Double Layer Capacitor Based on Acid Electrolyte (산성 전해질 기반의 전기 이중층 커패시터용 흑연 집전체의 전기화학적 안정성 평가)

  • Park, Sijin;An, Geon-Hyoung
    • Korean Journal of Materials Research
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    • v.31 no.5
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    • pp.272-277
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    • 2021
  • Owing to its low cost, easy fabrication process, and good ionic properties, aqueous supercapacitors are under strong consideration as next-generation energy storage devices. However, the limitation of the current collector is its poor electrochemical stability, leading to low energy storage performance. Therefore, a reasonable design of the current collector and the acidic electrolyte is a necessary, as well as interfacial engineering to enhance the electrochemical performance. In the present study, graphite foil, with excellent electrochemical stability and good electrical properties, is suggested as a current collector of aqueous supercapacitors. This strategy results in excellent electrochemical performance, including a high specific capacitance of 215 F g-1 at a current density of 0.1 A g-1, a superior high-rate performance (104 F g-1 at a current density of 20.0 A g-1), and a remarkable cycling stability of 98 % at a current density of 10.0 A g-1 after 9,000 cycles. The superior energy storage performance is mainly ascribed to the improved ionic diffusion ability during cycling.

Effect of Boric Acid Treatment on the Electrochemical Properties of the Phenol-Based Activated Carbon (페놀계 활성탄소의 전기화학 특성에 미치는 붕산 처리의 영향)

  • Jung, Min-Jung;Yu, Hye-Ryeon;Lee, Dayoung;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.24 no.2
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    • pp.201-207
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    • 2013
  • In this study, the surface of a phenol based activated carbon (AC) used as an electrode in an electric double layer capacitor was modified via boric acid treatment for the capacitance investigation. The effect of boric acid treatment on electrochemical performance was also investigated. The AC surface functional groups ratio of quinone-like (O=C) which is electrochemical active functional groups was increased after the boric acid treatment. And, boric acid treated AC showed an increase in the specific surface area, total pore volume, and micropore volume. In case of optimum boric acid treated AC, its specific capacitance increased by 20% in comparison to that of untreated AC. These results demonstrate that a boric acid treated carbon surface-based electric double layer capacitor electrode effectively enhances specific capacitance.

Synthesis of Mesostructured Conducting Polymer-Carbon Nanocomposites and Their Electrochemical Performance

  • Choi, Moon-Jung;Lim, Byung-Kwon;Jang, Jyong-Sik
    • Macromolecular Research
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    • v.16 no.3
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    • pp.200-203
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    • 2008
  • A conducting polymer layer was introduced into the pore surface of mesoporous carbon via vapor infiltration of a monomer and subsequent chemical oxidative polymerization. The polypyrrole, conducting polymer has attracted considerable attention due to the high electrical conductivity and stability under ambient conditions. The mesoporous carbon-polypyrrole nanocomposite exhibited the retained porous structure, such as mesoporous carbon with a three-dimensionally connected pore system after intercalation of the polypyrrole layer. In addition, the controllable addition of pyrrole monomer can provide the mesoporous carbon-polypyrrole nanocomposites with a tunable amount of polypyrrole and texture property. The polypyrrole layer improved the electrode performance in the electrochemical double layer capacitor. This improved electrochemical performance was attributed to the high surface area, open pore system with three-dimensionally interconnected mesopores, and reversible redox behavior of the conducting polypyrrole. Furthermore, the correlation between the amount of polypyrrole and capacitance was investigated to check the effect of the polypyrrole layer on the electrochemical performance.