• Applied Chemistry for Engineering
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• v.31 no.3
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• pp.341-345
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• 2020

An in situ regeneration of activated carbon bed using an ozonated water was studied in order for avoiding the carbon loss, contaminant emission and time consuming for discharge-regeneration-repacking in a conventional thermal regeneration process. Using phenol and polyethylene glycol (PEG) as adsorbates, the adsorption breakthrough and in situ regeneration with the ozonated water were repeated. These organics were supposed to degrade by the oxidation reaction of ozone, regenerating the bed for reuse. As the number of regeneration increased, the adsorption capacity for phenol was reduced, but the change was stabilized showing no further reduction after reaching a certain degree of decrement. The reduction of adsorption capacity was due to the increase of pore size resulting in the decrease of specific surface area during ozonation. The adsorption capacity of phenol decreased after the ozonated regeneration because the in-pore adsorption was prevalent for small molecules like phenol. However, PEG did not show such decrease and the adsorption capacity was constantly maintained after several cycles of the ozonated regeneration probably because the external surface adsorption was the major mechanism for large molecules like PEG. Since the reduction in the pore size and specific surface area for small molecules were proportional to the duration of contact time with the ozonated water, careful considerations of the solute size to be removed and controlling the contact time were necessary to enhance the performance of the ozonated in situ regeneration of activated carbon bed.

• Architectural research
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• v.26 no.2
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• pp.31-39
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• 2024

The numerical study focuses on the analysis of the structural behavior of concrete beams containing outdated concrete and offers an innovative method of strengthening them using carbon-fiber-reinforced polymer sheets (CFRP). The focus is on modeling and analyzing the performance of aged concrete beams strengthened by CFRP in the flexural direction. This study presents an ultimate load model for CFRP-strengthened RC beams featuring outdated concrete layers. Validation through four-point bending tests and finite element modeling demonstrated the efficacy of the model. Findings indicate that CFRP sheets significantly enhance beam strength, particularly in structures with outdated concrete layers, resulting in increased ultimate load capacity. Moreover, an inverse relationship between ultimate load and concrete layer height was observed, with the CFS-21-15-30 sample exhibiting the most substantial reduction. Validation of the model was achieved using finite element analysis con-ducted in Abaqus software.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.11a
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• pp.45-46
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• 2023

This study examined the curing temperature of concrete with a photothermal insulation sheet to shorten the curing time of concrete as part of construction cost and period reduction. According to the experiment results, the heating performance effect is confirmed through the temperature difference between photothermal insulation sheet and bubble sheet. And it has a high curing temperature in the order of bubble sheet (photo heating material B) > bubble sheet (photo heating material A) > bubble sheet on same layers.

• Journal of Korean Society for Atmospheric Environment
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• v.24 no.4
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• pp.455-469
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• 2008

VOCs (Volatile organic compounds) are known as one of the harmful chemicals, causing cancer and global warming. Therefore, the proper control, removal, and reduction of the emission of VOCs are important tasks for the environmental protection. Among the method of VOCs removal activated carbon bed is the most efficient and economical method. In this study, the adsorption performance of toluene gas was investigated using various activated carbons. To find out the adsorption efficiency, the H/D (Height/Diameter) of the activated carbon and GHSV (Gas Hourly Space Velocity) of the toluene gas were manipulated with various conditions. The effect of the temperature, humidity and toluene-MEK-IPA mixed gas on adsorption were also investigated. As a result, a high adsorption performance was found when GHSV is lower at room temperature and low humidity. It was also found that the adsorption efficiency of toluene-MEK-IPA mixed gas system was lower than that of toluene gas system.

• Tribology and Lubricants
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• v.36 no.2
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• pp.75-81
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• 2020

In this paper, we present an experimental investigation of the leakage and endurance performances of mechanical face seals in a 75-tonf turbopump for the Korea Space Launch Vehicle II first-stage engine. A mechanical face seal is used between the fuel pump and turbine to prevent mixing of the fuel and turbine gas. However, excessive leakage occurs through the carbon attached to the mechanical face seal bellows. To reduce this leakage, we redesign the mechanical face seal such that the contact area between the fuel and carbon is reduced, height of the carbon nose is reduced, and stiffness of the bellows is increased. Then, we conduct static and dynamic leakage tests and endurance tests to compare the performances of the original and modified mechanical face seals. The investigation of the leakage of the old and new mechanical face seals confirms that the leakage performance is significantly improved, by 80%, in the new design in comparison with the old design. The endurance tests demonstrate that the average wear rate of carbon in the new mechanical face seal is 0.1094 ㎛/s. The service lifetime is predicted to be 4,200 s, which is 28 times greater than the requirement. Finally, we present a new mechanical face seal in a 75-tonf turbopump, and perform a validation test in the real-propellant test facility at the NARO Space Center. Based on the test results, we can confirm that the modified mechanical face seal works well under real operating conditions.

• Korean Journal of Materials Research
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• v.28 no.7
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• pp.417-422
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• 2018

The stereotype of flexible MOFs(Amino-MIL-53) and carbonized porous carbon prepared from renewable resources is successfully synthesized for $CO_2$ reduction application. The textural properties of these microporous materials are investigated, and their $CO_2$ storage capacity and separation performance are evaluated. Owing to the combined effects of $CO_2-Amino$ interaction and its flexibility, a $CO_2$ uptake of $2.5mmol\;g^{-1}$ is observed in Amino-MIL-53 at 20 bar 298 K. In contrast, $CH_4$ uptake in Amino-MIL-53 is very low up to 20 bar, implying potential sorbent for $CO_2/CH_4$ separation. Carbonized samples contain a small quantity of metal residues(K, Ca, Mg, S), resulting in naturally doped porous carbon. Due to the trace metal, even higher $CO_2$ uptake of $4.7mmol\;g^{-1}$ is also observed at 20 bar 298 K. Furthermore, the $CH_4$ storage capacity is $2.9mmol\;g^{-1}$ at 298 K and 20 bar. To evaluate the $CO_2$ separation performance, the selectivity based on ideal adsorption solution theory for $CO_2/CH_4$ binary mixtures on the presented porous materials is investigated.

• Journal of Energy Engineering
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• v.21 no.3
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• pp.272-279
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• 2012

The emission quota of 26.9% was allocated to the architectural sector according to the greenhouse gas(GHG) emission reduction goal of the government. It has become inevitable to change the architectural structures in a low-energy consumption and sustainable manner for new and existing house. The introduction of various legal systems and deregulation have been attempted to promote the low carbon emission and sustainable energy conversion. Although overall emission reduction goal has been set for 6.7 million units of existing houses, there has been a lack of standards and directions for the emission reduction measures. This study was intended to present the most economic and effective green technology improvement measures based on the investigation into the current conditions through direct visit to the selected architectural structures and the repeated simulation of relevant technical elements.

• Environmental Engineering Research
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• v.12 no.5
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• pp.224-230
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• 2007

The objectives of this study were to evaluate the change of molecular weight (MW) profiles in natural organic matter (NOM) through various treatment processes (coagulation, granular activated carbon (GAC), and ozonation) using high performance size exclusion chromatography based on ultraviolet absorbance and dissolved organic detection (HPSEC-UVA-DOC). In addition, relationships between MW profiles and disinfection by-production (DBP) formation were evaluated. Each treatment process results in significant different effects on NOM profiles. Coagulation is effective to remove high molecular weight NOM, while GAC is effective to remove low molecular weight NOM. Ozonation removes only a small portion of NOM, while it induces a significant reduction of UV absorbance due to breakdown of the aromatic groups. All treated waters are chlorinated, and chlorination DBPs such as trihalomethanes (THMs) and haloacetic acids (HAAs) are measured under formation potential conditions. Both THM and HAA formation potentials were significantly reduced through the coagulation process. GAC was more effective to reduce THM formation compared to HAA formation reduction, while ozonation showed significant HAA reduction compared to THM reduction.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.50 no.1
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• pp.50-57
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• 2014

The performance of five kind adsorbents, which can reduce nitrogen oxide (NOx) from the diesel engine occupying 85% of the fishing boat, was carried out and the emission reduction filter was manufactured and evaluated in the adsorption efficiency of the emission gas for 240 KW diesel portable generator. As a NOx emission filter made of mordenite which has an excellent cation exchange capacity was manufactured by ball type adsorbents having excellent specific surface area. The adsorption efficiency of mordenite material applying the emission reduction filter began to show up at the operating time 10 minutes in comparison with the activated carbon and zeolite materials, and it was exposed to continue until 100% capability with passing by 20 minutes. So the adsorption efficiency of the NOx reduction filter consistently maintained at the averaged 80%.

• Architectural research
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• v.3 no.1
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• pp.37-44
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• 2001

This study aims to find out sector effects with the appraisal of building energy systems of urban ecosystem considering cost effects and environmental constraints condition such as climatic change factors including $CO_2$ gas which are not dealt in the institutional boundary as components standards and performance standards on energy performance of each part of a building applied on heavy energy spending buildings at present. The results of the appraisal of building energy systems shows that the existing building energy systems are not enough to fulfil the environmental condition under the environmental constraints supposing QELROs(Quantified Emission Limitation and Reduction Objectives) of carbon-dioxide exhaust. Henceforth, it is needed to fulfill the environmental criteria required by the Climatic Change Agreement for improving the adiabatic performance of each part of a building and active using of the solar energy.