• 공업화학
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• 제29권6호
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• pp.677-681
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• 2018

본 연구에서는 탄소블럭의 고밀도화를 위하여 불소화 표면처리된 코크스와 바인더피치를 압축성형으로 탄소블럭을 제조하였다. 불소화 표면처리 후 코크스 표면에 불소원소는 XPS 분석을 통하여 최대 24.14 at%가 도입된 것을 확인하였다. 불소화된 코크스와 바인더피치의 젖음성을 반응온도에 따라 평가하였다. 접촉각 측정 결과로부터 불소원소가 코크스 표면에 도입될수록 바인더피치와의 젖음성이 약 64.7% 향상됨을 알 수 있었다. 또한, 불소가 가장 많이 도입된 탄소블럭의 밀도는 미처리된 코크스로부터 제조된 탄소블럭의 밀도 대비 최대 6.8% 증가하였다.

• Elastomers and Composites
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• 제33권5호
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• pp.355-362
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• 1998

전도성 충전제인 카본블랙이 미치는 영향을 올바로 이해하므로서 전도성 카본블랙을 충전하여 도전성 고분자 복합재료를 제조하고자 하였다. 고분자 수지로 ABS(Acrylonitrile Butadiene Styrene copolymer), PC(Polycabonate), PC/ABS 를 사용하여 전도성 카본블랙 3종류를 사용하여 비교하였다. 실험결과 섬유사슬모양의 전도성 카본블랙을 충전한 PC는 상당히 가능성을 보였다.

• 한국건설순환자원학회논문집
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• 제11권4호
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• pp.299-306
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• 2023

현무암폐석을 활용한 투수믈록의 성능을 평가하기 위해 현무암폐석의 치환율을 0, 20, 40, 60 (%) 4가지 수준으로 변화시켜 시멘트 및 무시멘트 기반의 투수블록을 제작하여 휨강도, 압축강도, 투수 계수, 흡수율, 밀도, 이산화탄소 저감, 미세먼지 저감 등에 대하여 평가하였다. 그 결과, 휨강도, 압축강도와 밀도는 현무암 폐석의 치환율이 증가함에 따라 감소하였지만 치환율 20 %에서 휨강도가 KS규격에 만족하는 결과값을 보였다. 흡수율, 투수계수, 이산화탄소 저감. 미세먼지 저감 등은 현무암 폐석의 치환율이 증가함에 따라 증가하는 경향을 보였으며, 투수계수는 모든 치환율에서 KS규격을 만족하는 결과를 나타내었고 미세먼지, 이산화탄소 저감과 흡수율은 모든 치환율에서 높은 값을 나타났다. 따라서 시멘트를 사용하지 않아 시멘트 생산과정에서 바생하는 이산화탄소량을 감소시킬 수 있는 무시멘트 기반 투수블록에서 중요한 지표인 투수계수가 KS규격을 만족하였고 공기질 오염물질 저감 성능이 뛰어나기 때문에 휨강도 기준을 만족하는 현무암 폐석 치환율 20 % 내에서 활용한다면 기존의 투수블록이 가지고 있는 문제점을 해결할 수 있는 방안으로 사용할 수 있을 것으로 판단된다.

• Bulletin of the Korean Chemical Society
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• 제29권10호
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• pp.2047-2050
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• 2008

• 웰빙융합연구
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• 제2권2호
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• pp.19-37
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• 2019

Over the last few decades, the atmospheric carbon dioxide emission has been amplified to a great extent in Turkey. This amplification may cause global warming, climate change and environmental degradation in Turkey. Consequently, ecological condition and human life may suffer in the near future from these indicated threats. Therefore, an attempt was made to test the relationship among a number of expected factors and carbon dioxide emissions in the case of Turkey. The study covers the time series data over the period of 1970-2017. We employed the modern econometric techniques such as Johansen co-integration, ARDL bound testing approach and the block exogeneity. The results of the Johansen co-integration test show that there is a significant long-run relationship between carbon dioxide emissions and expected factors. The long-run elasticities of the ARDL model show that a 1% increase in the GDP per capita, electric consumption, fiscal development and trade openness will increase carbon dioxide emissions by 0.14, 0.52, 0.09 and 0.20% respectively. Further, our findings reveal that the environmental Kuznets curve (EKC) hypothesis and inverted U-shaped relationship between carbon dioxide emission and economic growth prevails. Therefore, the EKC hypothesis is valid and prevailing in the Turkish economy. The diagnostic test results show that the parameters of the ARDL model are credible, sTable and reliable in the current form. Finally, Block exogeneity analysis displays that all the expected factors are contributing significantly to carbon dioxide emissions in the Turkish economy.

• Carbon letters
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• 제15권4호
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• pp.295-298
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• 2014

In this work, nanoporous carbons (NPCs) were prepared by the self-assembly of polymeric carbon precursors and block copolymer template in the presence of tetraethyl orthosilicate and colloidal silica. The NPCs' pore structures and total pore volumes were analyzed by reference to $N_2$/77 K adsorption isotherms. The porosity and elemental mercury adsorption of NPCs were increased by activation with carbon dioxide. It could be resulted that elemental mercury adsorption ability of NPCs depended on their specific surface area and micropore fraction.

• Korean Membrane Journal
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• 제6권1호
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• pp.16-23
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• 2004

The silica containing carbon (C-SiO$_2$) membranes were fabricated using poly(imide siloxane) (PIS) having -CO- swivel group. The characteristics of porous C-SiO$_2$ structures prepared by the pyrolysis of poly(imide siloxane) were related with the micro-phase separation between the imide block and the siloxane block. Furthermore, the nitrogen adsorption isotherms of the CMS and the C-SiO$_2$ membranes were investigated to define the characteristics of porous structures. The C-SiO$_2$ membranes derived from PIS showed the type IV isotherm and possessed the hysteresis loop, which was associated with the mesoporous carbon structures, while the CMS membranes derived from PI showed the type I isotherm. For the molecular sieving probe, the C-SiO$_2$ membranes pyrolyzed at 550, 600, and 700$^{\circ}C$ showed the O$_2$ permeability of 924, 1076, and 367 Barrer (1 ${\times}$ 10$\^$-10/㎤(STP)cm/$\textrm{cm}^2$$.$s$.$cmHg) and O$_2$/N$_2$ selectivity of 9, 8, and 12.

• 공업화학
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• 제28권4호
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• pp.432-436
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• 2017

석유 잔사유로부터 제조된 ${\beta}$-resin 함량이 각각 다른 바인더 피치와 등방코크스를 혼합 후 압축성형을 거쳐 탄소블럭을 제조하였다. 원소분석, FT-IR 및 열중량 분석을 통하여 바인더 피치의 물리적, 화학적 특성 및 열적 거동을 각각 고찰하였다. 또한, 주사전자현미경을 이용하여 측정된 탄소블럭의 파단면으로부터 등방코크스 입자와 바인더 피치의 결합성을 평가하였다. 실험 결과로부터 바인더 피치의 ${\beta}$-resin 함량이 높을수록 코크스와 바인더의 결합성이 향상됨을 알 수 있었다. 또한, 탄소블럭의 탄화 후 밀도는 ${\beta}$-resin 함량이 1.4%에서 20.1%로 증가함으로 인하여 $1.325g/cm^3$에서 $1.383g/cm^3$으로 증가하였다.

• ETRI Journal
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• 제43권4호
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• pp.717-727
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• 2021

In this study, new multiplier and adder method designs with multiplexers are proposed. The designs are based on quaternary logic and a carbon nanotube field-effect transistor (CNTFET). The design utilizes 4 × 4 multiplier blocks. Applying specific rotational functions and unary operators to the quaternary logic reduced the power delay produced (PDP) circuit by 54% and 17.5% in the CNTFETs used in the adder block and by 98.4% and 43.62% in the transistors in the multiplier block, respectively. The proposed 4 × 4 multiplier also reduced the occupied area by 66.05% and increased the speed circuit by 55.59%. The proposed designs are simulated using HSPICE software and 32 nm technology in the Stanford Compact SPICE model for CNTFETs. The simulated results display a significant improvement in the fabrication, average power consumption, speed, and PDP compared to the current bestperforming techniques in the literature. The proposed operators and circuits are evaluated under various operating conditions, and the results demonstrate the stability of the proposed circuits.

• Carbon letters
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• 제9권1호
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• pp.28-34
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• 2008

Multidirectional reinforcement is aimed primarily at overcoming interlaminar weakness, hence a major interest lies in the mechanical properties of multidirectional carbon/carbon composites. Mechanical properties depend on the type of carbon fiber, the size of the fiber bundle, the spacing of the bundles, the angles of the bundles relative to the axes of the block, and matrix formation. In the present studies, PAN based carbon fiber preforms manufactured different size of unit cell have been prepared. Densification of these used high pressure infiltration and carbonization technique with coal tar pitch as matrix precursor was carried out. Scanning electron microscopy has been used to study the fracture behavior of composites. The size of unit cell of the preforms has considerably affected on the flexural properties as well as microstructure of the carbon/carbon composites.