DOI QR코드

DOI QR Code

A study on elemental mercury adsorption behaviors of nanoporous carbons with carbon dioxide activation

  • Received : 2014.09.02
  • Accepted : 2014.10.05
  • Published : 2014.10.31

Abstract

In this work, nanoporous carbons (NPCs) were prepared by the self-assembly of polymeric carbon precursors and block copolymer template in the presence of tetraethyl orthosilicate and colloidal silica. The NPCs' pore structures and total pore volumes were analyzed by reference to $N_2$/77 K adsorption isotherms. The porosity and elemental mercury adsorption of NPCs were increased by activation with carbon dioxide. It could be resulted that elemental mercury adsorption ability of NPCs depended on their specific surface area and micropore fraction.

Keywords

References

  1. Darbha GK, Singh AK, Rai US, Yu E, Yu H, Chandra Ray P. Selective detection of mercury (II) ion using nonlinear optical properties of gold nanoparticles. J Am Chem Soc, 130, 8038 (2008). http://dx.doi.org/10.1021/ja801412b.
  2. An J, Shang K, Lu N, Jiang Y, Wang T, Li J, Wu Y. Performance evaluation of non-thermal plasma injection for elemental mercury oxidation in a simulated flue gas. J Hazard Mater, 268, 237 (2014). http://dx.doi.org/10.1016/j.jhazmat.2014.01.022.
  3. Kim BJ, Bae KM, Park SJ. Elemental mercury vapor adsorption of copper-coated porous carbonaceous materials. Microporous Mesoporous Mater, 163, 270 (2012). http://dx.doi.org/10.1016/j.micromeso.2012.05.038.
  4. Du W, Yin L, Zhuo Y, Xu Q, Zhang L, Chen C. Catalytic oxidation and adsorption of elemental mercury over $CuCl_2$-impregnated sorbents. Ind Eng Chem Res, 53, 582 (2014). http://dx.doi.org/10.1021/ie4016073.
  5. Bae KM, Kim BJ, Rhee KY, Park SJ, Roles of metal/activated carbon hybridization on elemental mercury adsorption. J Nanosci Nanotechnol, 14, 5811 (2014). http://dx.doi.org/10.1166/jnn.2014.8459.
  6. Hou W. Zhou J. Yu C, You S, Gao X, Luo Z, $Pd/Al_2O_3$ Sorbents for elemental mercury capture at high temperatures in syngas. Ind Eng Chem Res, 53, 9909 (2014). http://dx.doi.org/10.1021/ie501292a.
  7. Im JS, Park SJ, Lee YS. Preparation and characteristics of electrospun activated carbon materials having meso- and macropores. J Colloid Interface Sci, 314, 32 (2007). http://dx.doi.org/10.1016/j.jcis.2007.05.033.
  8. Horowitz HM, Jacob DJ, Amos HM, Streets DG, Sunderland EM, Historical mercury releases from commercial products: global environmental implications. Environ Sci Technol. 48, 10242 (2014). http://dx.doi.org/10.1021/es501337j.
  9. Hu Y, Wen Z, Wu X, Jin J. Low-cost shape-control synthesis of porous carbon film on $\beta$″-alumina ceramics for Na-based battery application. J Power Sources, 219, 1 (2012). http://dx.doi.org/10.1016/j.jpowsour.2012.07.025.
  10. Kim BJ, Lee YS, Park SJ. A study on the hydrogen storage capacity of Ni-plated porous carbon nanofibers. Int J Hydrogen Energy, 33, 4112 (2008). http://dx.doi.org/10.1016/j.ijhydene.2008.05.077.
  11. Kim S, Park SJ. Effects of chemical treatment of carbon supports on electrochemical behaviors for platinum catalysts of fuel cells. J Power Sources, 159, 42 (2006). http://dx.doi.org/10.1016/j.jpowsour.2006.04.041.
  12. Fu Y, Ming H, Zhou Q, Jin L, Li X, Zheng J. Nitrogen-doped carbon coating inside porous $TiO_2$ using small nitrogen-containing molecules for improving performance of lithium-ion batteries. Electrochim Acta, 134, 478 (2014). http://dx.doi.org/10.1016/j.electacta.2014.04.130.
  13. Park SJ, Jang YS, Shim JW, Ryu SK. Studies on pore structures and surface functional groups of pitch-based activated carbon fibers. J Colloid Interface Sci, 260, 259 (2003). http://dx.doi.org/10.1016/S0021-9797(02)00081-4.
  14. Park SJ, Kim BJ. Ammonia removal of activated carbon fibers produced by oxyfluorination. J Colloid Interface Sci, 291, 597 (2005). http://dx.doi.org/10.1016/j.jcis.2005.05.012.
  15. Belhachemi M, Jeguirim M, Limousy L, Addoun F. Comparison of $NO_2$ removal using date pits activated carbon and modified commercialized activated carbon via different preparation methods: effect of porosity and surface chemistry. Chem Eng J, 253, 121 (2014). http://dx.doi.org/10.1016/j.cej.2014.05.004.
  16. Park SJ, Kim KD. Adsorption behaviors of $CO_2$ and $NH_3$ on chemically surface-treated activated carbons. J Colloid Interface Sci, 212, 186 (1999). http://dx.doi.org/10.1006/jcis.1998.6058.
  17. Lee HM, Kim HG, An KH, Kim BJ. Effects of pore structures on electrochemical behaviors of polyacrylonitrile-based activated carbon nanofibers by carbon dioxide activation. Carbon Lett, 15, 71 (2014). http://dx.doi.org/10.5714/CL.2014.15.1.071.
  18. Park SJ, Kim KD. Influence of activation temperature on adsorption characteristics of activated carbon fiber composites. Carbon, 39, 1741 (2001). http://dx.doi.org/10.1016/S0008-6223(00)00305-5.
  19. Kim BJ, Lee YS, Park SJ. Novel porous carbons synthesized from polymeric precursors for hydrogen storage. Int J Hydrogen Energy, 33, 2254 (2008). http://dx.doi.org/10.1016/j.ijhydene.2008.02.019.
  20. Park SJ, Kim BJ. Influence of oxygen plasma treatment on hydrogen chloride removal of activated carbon fibers. J Colloid Interface Sci, 275, 590 (2004). http://dx.doi.org/10.1016/j.jcis.2004.03.011.
  21. Im JS, Kwon O, Kim YH, Park SJ, Lee YS. The effect of embedded vanadium catalyst on activated electrospun CFs for hydrogen storage. Microporous Mesoporous Mater, 115, 514 (2008). http://dx.doi.org/10.1016/j.micromeso.2008.02.027.
  22. Adelodun AA, Lim YH, Jo YM. Surface oxidation of activated carbon pellets by hydrogen peroxide for preparation of $CO_2$ adsorbent. J Ind Eng Chem, 20, 2130 (2014). http://dx.doi.org/10.1016/j.jiec.2013.09.042.
  23. Babel K, Janasiak D, Jurewicz K. Electrochemical hydrogen storage in activated carbons with different pore structures derived from certain lignocellulose materials. Carbon, 50, 5017 (2012). http://dx.doi.org/10.1016/j.carbon.2012.06.030.
  24. Park SJ, Park BJ, Ryu SK. Electrochemical treatment on activated carbon fibers for increasing the amount and rate of Cr(VI) adsorption. Carbon, 37, 1223 (1999). http://dx.doi.org/10.1016/S0008-6223(98)00318-2.
  25. Kubota M, Hata A, Matsuda H. Preparation of activated carbon from phenolic resin by KOH chemical activation under microwave heating. Carbon, 47, 2805 (2009). http://dx.doi.org/10.1016/j.carbon.2009.06.024.
  26. Bansal RC, Goyal M. Activated Carbon Adsorption, Taylor & Francis, Boca Raton, FL (2005).
  27. Tang L, Yang GD, Zeng GM, Cai Y, Li SS, Zhou YY, Pang Y, Liu YY, Zhang Y, Luna B. Synergistic effect of iron doped ordered mesoporous carbon on adsorption-coupled reduction of hexavalent chromium and the relative mechanism study. Chem Eng J, 239, 114 (2014). http://dx.doi.org/10.1016/j.cej.2013.10.104.
  28. Peng X, Hu X, Fu D, Lam FLY. Adsorption removal of acid black 1 from aqueous solution using ordered mesoporous carbon. Appl Surf Sci, 294, 71 (2014). http://dx.doi.org/10.1016/j.apsusc.2013.11.157.
  29. Brunauer S, Emmett PH, Teller E. Adsorption of gases in multimolecular layers. J Am Chem Soc, 60, 309 (1938). http://dx.doi.org/10.1021/ja01269a023.
  30. Dubinin MM, Plavnik GM. Microporous structures of carbonaceous adsorbents. Carbon, 6, 183 (1968). http://dx.doi.org/10.1016/0008-6223(68)90302-3.

Cited by

  1. adsorbents vol.19, 2016, https://doi.org/10.5714/CL.2016.19.099