• 폴리머
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• 제31권5호
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• pp.436-441
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• 2007

In this work, the multiwalled carbon nanotubes(MWNTs) were functionalized with sodium dodecylbenzene sulfonate(SDBS) and then MWNTs/Lyocell composite fibers were prepared. The properties of MWNTs, the functionlization on the surface of MWNTs and their dispersion in the cellulose matrix were characterized by TEM, SEM, WAXD and FT-IR. The results showed that SDBS has been coated successfully onto the surface of the MWNTs by functionlization. This can improve effectively the dispersion uniformity of MWNTs in NMMO aqueous solution and is helpful to prepare a spinnable spinning dope. Moreover, the resultant MWNTs/Lyocell composite fibers still have cellulose II crystal structure, and their tensile strength and initial modulus increased with the increasing draw ratio and reached the optimal value with adding 1 wt% MWNTs. The thermal stability of the composite fiber was also improved by the addition of the MWNTs.

• 폴리머
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• 제31권5호
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• pp.385-392
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• 2007

Poly (N-vinylpyrrolidone) (PVP) groups were grafted onto a poly(3-hydroxybutyrate-co-3-hydroryvalerate) (PHBV) backbone in order to modify its properties and synthesize a novel biocompatible copolymer. The crystallization behavior of PHBV and grafted PHBV was investigated by differential scanning calorimetry (DSC) and polarized optical microscopy (POM). During the cooling-induced crystallization process, the crystallization temperature and the crystallization rate of the grafted PHBV decreased with increasing PVP weight fraction. On the heating scans of all grafted PHBV samples, a new crystallization exothermic peak appeared at almost the same temperature, suggesting the operation of a recrystallization process, while the melting temperature ($T_m$) and the apparent enthalpy of fusion (${\Delta}H_f$) were not affected by graft modification. During the isothermal crystallization process at the same temperature, the presence of side PVP groups decreased the spherulitic growth rate and the spherulitic band spacing with increasing PVP weight fraction in samples.

• 한국분말재료학회지
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• 제19권3호
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• pp.177-181
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• 2012

Copper composite materials have attracted wide attention for energy applications. Especially $CuInS_2$ has a desirable direct band gap of 1.5 eV, which is well matched with the solar spectrum. $CuInS_2$ nanoparticles could make it possible to develop color-tunable $CuInS_2$ nanoparticle emitter in the near-infrared region (NIR) for energy application and bio imaging sensors. In this paper, $CuInS_2$ nanoparticles were successfully synthesized by thermo-decomposition methods. Surface modification of $CuInS_2$ nanoparticles were carried out with various semiconductor materials (CdS, ZnS) for enhanced optical properties. Surface modification and silica coating of hydrophobic nanoparticles could be dispersed in polar solvent for potential applications. Their optical properties were characterized by UV-vis spectroscopy and photoluminescence spectroscopy (PL). The structures of silica coated $CuInS_2$ were observed by transmission electron microscopy (TEM).

• 한국환경보건학회지
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• 제26권4호
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• pp.75-81
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• 2000

A matrix modification was studied for the determination of trace manganese in several seaweeds by electrothermal atomic absorption spectrophotometry(ETAAS). The type and quantity of modifiers were investigated to realize the efficient modification. Palladium was chosen as a single modifier. By the addition of palladium(5$\mu\textrm{g}$/$m\ell$) to 2ng/$m\ell$ manganese solution, the temperatures were raised from 1,00$0^{\circ}C$ to 1,20$0^{\circ}C$ for the charring and from 2,10$0^{\circ}C$ to 2,20$0^{\circ}C$ for the atomization as well as the sensitivity and reproducibility were improved. With such optimum conditions, the trace amount of manganese in several seaweeds(laver, tangle and brown seaweed) could be determined by a calibration curve method, and good recoveries of more than 965 were also obtained in the samples in which a given amount of manganese was spiked. The detection limit of this method was about 0.048ng/$m\ell$.

• 대한수학교육학회지:학교수학
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• 제18권3호
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• pp.711-731
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• 2016

본 연구에서는 중등 수학 예비교사가 교과서의 수학 과제(Mathematical task)를 어떻게 변형하는지 그리고 그 과정에서 예비교사들이 어떤 학습 기회를 가지는지 조사하였다. 이를 위하여 교과서의 미분계수 단원에서 과제를 선정하고 5명의 예비교사를 대상으로 과제 변형 활동을 실시하여 분석한 결과, 다음과 같은 결론을 얻을 수 있었다. 첫째, 과제는 인지적 노력 수준을 유지하거나 높이는 방향으로 이루어졌으며 이러한 경향은 예비교사들이 미분계수의 개념적 이해를 추구하는 가운데 나타났다. 둘째, 과제 변형 활동은 예비교사들에게 다양한 학습기회를 제공하였다. 예비교사들은 교육과정과 교과서의 의도를 파악하기 위해 노력하였고, 학생의 반응을 예측하는 것의 중요성을 알게 되었으며, 협업과 반성적 사고의 기회를 가졌다.

• 한국지진공학회논문집
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• 제23권1호
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• pp.71-82
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• 2019

Most school buildings consist of reinforced concrete (RC) moment frames with masonry infills. The longitudinal direction frames of those school buildings are relatively weak due to the short-column effects caused by the partial masonry infills and need to be evaluated carefully. In 'Manual for Seismic Performance Evaluation and Retrofit of School Facilities' published in 2018, response modification factor of 2.5 is applied to non-seismic RC moment frames with partial masonry infills, but sufficient verification of the factor has not been reported yet. Therefore, this study conducted seismic performance evaluation of planar RC moment frames with partial masonry infills in accordance with both linear analysis and nonlinear static analysis procedures presented in the manual. The evaluation results from the different procedures are compared in terms of assessed performance levels and number of members not meeting target performance objectives. Finally, appropriate response modification factors are proposed with respect to a shear-controlled column ratio.

• Toxicological Research
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• 제33권1호
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• pp.1-5
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• 2017

Nuclear factor E2-related factor 2 (Nrf2), a transcription factor, controls the expression of genes encoding cytoprotective proteins, including antioxidant enzymes that combat oxidative and electrophilic stress to maintain redox homeostasis. However, recent studies demonstrated that, in cancer, aberrant activation of Nrf2 by epigenetic alterations promotes high expression of cytoprotective proteins, which can decrease the efficacy of anticancer drugs used for chemotherapy. In this review, we summarize recent findings regarding the relationship between oxidative stress, Nrf2, epigenetic modification, and anticancer drug resistance, which should aid in development of new strategies to improve chemotherapeutic efficacy.

• Bulletin of the Korean Chemical Society
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• 제28권10호
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• pp.1763-1770
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• 2007

Strong solid acid catalysts, NiO/Al2O3-TiO2/WO3 for ethylene dimerization were prepared by the addition of Al2O3 and the modification with WO3. The acid sites and acid strength were increased by the inductive effect of WO3 species bonded to the surface of catalysts. The larger the dispersed WO3 amount, the higher both the acidity and catalytic activity for ethylene dimerization. The addition of Al2O3 to TiO2 up to 5 mol% enhanced acidity and catalytic activity gradually due to the interaction between Al2O3 and TiO2 and consequent formation of Al-O-Ti bond.

• 한국생산제조학회지
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• 제9권2호
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• pp.66-71
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• 2000

Laser induced surface hardening of Tool steel(STC5) can be achieved either with or without surface melting. In trans-formation hardening as the surface is heated to a temperature below its melting point and is rapidly cooled solidified microstructures are usually much finer and stronger than those of the base matals. For this reason surface modification of tool steel by YAG laser irradiation has been studied as a function of processing parameters such as power density pulse width defocusing distance and molten depth. The high energy density changes and refines the microstructure of the near surface layer. In the case of beam passes martensite formed in the melt zone exhibited very high vickers hardness values. Molten depth and width depend on defocusing distance and energy of black color painting is more absorptive than other color painting.

• 한국소음진동공학회논문집
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• 제11권5호
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• pp.123-130
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• 2001

The purpose of this paper is to reduce the level of idling vibration on a steering wheel. In some cases, vibration on steering wheel is amplified due to the resonance between the first natural frequency of T-beam and engine idling speed. Using SDM(structural dynamic modification) technique, T-beam is redesigned to reduce its vibration. This paper used FRF(frequency response function) synthesis technique which is entirely dependent on experiment. But this method requires lots of test efforts to enhance its reliability of design. While combining this method with an analytic method. the experimental burden, the major drawback of FRP synthesis method, can be considerably relieved. Using ana1ytic sensitivity analysis, some effective modification regions are preliminarily chosen as candidate Positions where SDM can be applied to modify T-beam\`s dynamic characteristics.