• Title/Summary/Keyword: 5'-Modification

Search Result 2,296, Processing Time 0.027 seconds

Preparation and Characterization of Multiwalled Carbon Nanotubes/Lyocell Composite Fibers (다중벽 탄소나노튜브/리오셀 복합섬유의 제조 및 특성조사)

  • Lu, Jiang;Zhang, Huihui;Shao, Huili;Hu, Xuechao
    • Polymer(Korea)
    • /
    • v.31 no.5
    • /
    • pp.436-441
    • /
    • 2007
  • In this work, the multiwalled carbon nanotubes(MWNTs) were functionalized with sodium dodecylbenzene sulfonate(SDBS) and then MWNTs/Lyocell composite fibers were prepared. The properties of MWNTs, the functionlization on the surface of MWNTs and their dispersion in the cellulose matrix were characterized by TEM, SEM, WAXD and FT-IR. The results showed that SDBS has been coated successfully onto the surface of the MWNTs by functionlization. This can improve effectively the dispersion uniformity of MWNTs in NMMO aqueous solution and is helpful to prepare a spinnable spinning dope. Moreover, the resultant MWNTs/Lyocell composite fibers still have cellulose II crystal structure, and their tensile strength and initial modulus increased with the increasing draw ratio and reached the optimal value with adding 1 wt% MWNTs. The thermal stability of the composite fiber was also improved by the addition of the MWNTs.

Preparation and Crystallization Behavior of Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Grafted with Poly(N-vinylpyrrolidone) (Poly(N-vinylpyrrolidone)이 그래프트된 Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) 공중합체의 합성 및 결정화 거동)

  • Wang, Wei;Zhang, Yu;Chen, Yanmo
    • Polymer(Korea)
    • /
    • v.31 no.5
    • /
    • pp.385-392
    • /
    • 2007
  • Poly (N-vinylpyrrolidone) (PVP) groups were grafted onto a poly(3-hydroxybutyrate-co-3-hydroryvalerate) (PHBV) backbone in order to modify its properties and synthesize a novel biocompatible copolymer. The crystallization behavior of PHBV and grafted PHBV was investigated by differential scanning calorimetry (DSC) and polarized optical microscopy (POM). During the cooling-induced crystallization process, the crystallization temperature and the crystallization rate of the grafted PHBV decreased with increasing PVP weight fraction. On the heating scans of all grafted PHBV samples, a new crystallization exothermic peak appeared at almost the same temperature, suggesting the operation of a recrystallization process, while the melting temperature ($T_m$) and the apparent enthalpy of fusion (${\Delta}H_f$) were not affected by graft modification. During the isothermal crystallization process at the same temperature, the presence of side PVP groups decreased the spherulitic growth rate and the spherulitic band spacing with increasing PVP weight fraction in samples.

Synthesis and Characterization of CuInS2 Semiconductor Nanoparticles and Evolution of Optical Properties via Surface Modification (CuInS2 나노 반도체 합성 및 표면 개질을 통한 광학적 효율 분석 연구)

  • Yang, Hee-Seung;Kim, Yoo-Jin
    • Journal of Powder Materials
    • /
    • v.19 no.3
    • /
    • pp.177-181
    • /
    • 2012
  • Copper composite materials have attracted wide attention for energy applications. Especially $CuInS_2$ has a desirable direct band gap of 1.5 eV, which is well matched with the solar spectrum. $CuInS_2$ nanoparticles could make it possible to develop color-tunable $CuInS_2$ nanoparticle emitter in the near-infrared region (NIR) for energy application and bio imaging sensors. In this paper, $CuInS_2$ nanoparticles were successfully synthesized by thermo-decomposition methods. Surface modification of $CuInS_2$ nanoparticles were carried out with various semiconductor materials (CdS, ZnS) for enhanced optical properties. Surface modification and silica coating of hydrophobic nanoparticles could be dispersed in polar solvent for potential applications. Their optical properties were characterized by UV-vis spectroscopy and photoluminescence spectroscopy (PL). The structures of silica coated $CuInS_2$ were observed by transmission electron microscopy (TEM).

Matrix Modification for Electrothermal Atomic Absorption Spectrophotometric Determination of Trace Manganese in Seaweeds (해조류중 흔적량 망간의 전열원자흡수 분광광도법 정량을 위한 매트릭스 개선에 관한 연구)

  • 최종문;강동수
    • Journal of Environmental Health Sciences
    • /
    • v.26 no.4
    • /
    • pp.75-81
    • /
    • 2000
  • A matrix modification was studied for the determination of trace manganese in several seaweeds by electrothermal atomic absorption spectrophotometry(ETAAS). The type and quantity of modifiers were investigated to realize the efficient modification. Palladium was chosen as a single modifier. By the addition of palladium(5$\mu\textrm{g}$/$m\ell$) to 2ng/$m\ell$ manganese solution, the temperatures were raised from 1,00$0^{\circ}C$ to 1,20$0^{\circ}C$ for the charring and from 2,10$0^{\circ}C$ to 2,20$0^{\circ}C$ for the atomization as well as the sensitivity and reproducibility were improved. With such optimum conditions, the trace amount of manganese in several seaweeds(laver, tangle and brown seaweed) could be determined by a calibration curve method, and good recoveries of more than 965 were also obtained in the samples in which a given amount of manganese was spiked. The detection limit of this method was about 0.048ng/$m\ell$.

  • PDF

Pre-Service Secondary Mathematics Teachers' Modification of Derivative Tasks (중등 수학 예비교사의 미분계수 과제 변형)

  • Kim, Ha Lim;Lee, Kyeong-Hwa
    • School Mathematics
    • /
    • v.18 no.3
    • /
    • pp.711-731
    • /
    • 2016
  • The purpose of this study is to investigate how pre-service secondary mathematics teachers modify mathematical tasks from a textbook and learning opportunities they have during the task modification. In the pursuit of this purpose, tasks was selected from derivative units in a textbook and five pre-service teachers was asked to modify the tasks. The findings from analysis are as follows. First, the cognitive demands of modified tasks were maintained or higher than those of the originals. Pre-service teachers' tendency toward conceptual understanding of derivative seems to make the result. Second, task modification provided a lot of learning opportunities for pre-service teachers. They tried to know intention of curriculum and textbook, realized the importance of predicting students' responses, and had opportunities for cooperation and reflective thinking.

Response Modification Factors for Seismic Performance Evaluation of Non-seismic School Buildings with Partial Masonry Infills (조적허리벽이 있는 비내진 학교시설의 내진성능평가를 위한 반응수정계수)

  • Kim, Beom Seok;Park, Ji-Hun
    • Journal of the Earthquake Engineering Society of Korea
    • /
    • v.23 no.1
    • /
    • pp.71-82
    • /
    • 2019
  • Most school buildings consist of reinforced concrete (RC) moment frames with masonry infills. The longitudinal direction frames of those school buildings are relatively weak due to the short-column effects caused by the partial masonry infills and need to be evaluated carefully. In 'Manual for Seismic Performance Evaluation and Retrofit of School Facilities' published in 2018, response modification factor of 2.5 is applied to non-seismic RC moment frames with partial masonry infills, but sufficient verification of the factor has not been reported yet. Therefore, this study conducted seismic performance evaluation of planar RC moment frames with partial masonry infills in accordance with both linear analysis and nonlinear static analysis procedures presented in the manual. The evaluation results from the different procedures are compared in terms of assessed performance levels and number of members not meeting target performance objectives. Finally, appropriate response modification factors are proposed with respect to a shear-controlled column ratio.

Oxidative Stress, Nrf2, and Epigenetic Modification Contribute to Anticancer Drug Resistance

  • Kang, Kyoung Ah;Hyun, Jin Won
    • Toxicological Research
    • /
    • v.33 no.1
    • /
    • pp.1-5
    • /
    • 2017
  • Nuclear factor E2-related factor 2 (Nrf2), a transcription factor, controls the expression of genes encoding cytoprotective proteins, including antioxidant enzymes that combat oxidative and electrophilic stress to maintain redox homeostasis. However, recent studies demonstrated that, in cancer, aberrant activation of Nrf2 by epigenetic alterations promotes high expression of cytoprotective proteins, which can decrease the efficacy of anticancer drugs used for chemotherapy. In this review, we summarize recent findings regarding the relationship between oxidative stress, Nrf2, epigenetic modification, and anticancer drug resistance, which should aid in development of new strategies to improve chemotherapeutic efficacy.

Effect of Al2O3 Addition and WO3 Modification on Catalytic Activity of NiO/Al2O3-TiO2/WO3 for Ethylene Dimerization

  • Pae, Young-Il;Sohn, Jong-Rack
    • Bulletin of the Korean Chemical Society
    • /
    • v.28 no.10
    • /
    • pp.1763-1770
    • /
    • 2007
  • Strong solid acid catalysts, NiO/Al2O3-TiO2/WO3 for ethylene dimerization were prepared by the addition of Al2O3 and the modification with WO3. The acid sites and acid strength were increased by the inductive effect of WO3 species bonded to the surface of catalysts. The larger the dispersed WO3 amount, the higher both the acidity and catalytic activity for ethylene dimerization. The addition of Al2O3 to TiO2 up to 5 mol% enhanced acidity and catalytic activity gradually due to the interaction between Al2O3 and TiO2 and consequent formation of Al-O-Ti bond.

A Study on the Surfaces Modification of Tool Steel by YAG LASER (YAG LASER에 의한공구강의 표면개질에 관한 연구)

  • 강형식
    • Journal of the Korean Society of Manufacturing Technology Engineers
    • /
    • v.9 no.2
    • /
    • pp.66-71
    • /
    • 2000
  • Laser induced surface hardening of Tool steel(STC5) can be achieved either with or without surface melting. In trans-formation hardening as the surface is heated to a temperature below its melting point and is rapidly cooled solidified microstructures are usually much finer and stronger than those of the base matals. For this reason surface modification of tool steel by YAG laser irradiation has been studied as a function of processing parameters such as power density pulse width defocusing distance and molten depth. The high energy density changes and refines the microstructure of the near surface layer. In the case of beam passes martensite formed in the melt zone exhibited very high vickers hardness values. Molten depth and width depend on defocusing distance and energy of black color painting is more absorptive than other color painting.

  • PDF

Redesign of Steering Wheel Support T-beam Structure to Reduce its Vibration Using Frequency Response Function Synthesis Technique (주파수응답함수 결합법을 이용한 승용차 핸들지지 T 빔의 진동저감 재설계)

  • 변성준;박남규;박윤식
    • Transactions of the Korean Society for Noise and Vibration Engineering
    • /
    • v.11 no.5
    • /
    • pp.123-130
    • /
    • 2001
  • The purpose of this paper is to reduce the level of idling vibration on a steering wheel. In some cases, vibration on steering wheel is amplified due to the resonance between the first natural frequency of T-beam and engine idling speed. Using SDM(structural dynamic modification) technique, T-beam is redesigned to reduce its vibration. This paper used FRF(frequency response function) synthesis technique which is entirely dependent on experiment. But this method requires lots of test efforts to enhance its reliability of design. While combining this method with an analytic method. the experimental burden, the major drawback of FRP synthesis method, can be considerably relieved. Using ana1ytic sensitivity analysis, some effective modification regions are preliminarily chosen as candidate Positions where SDM can be applied to modify T-beam\`s dynamic characteristics.

  • PDF