• Journal of the Korean Chemical Society
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• v.42 no.6
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• pp.664-671
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• 1998

Poly pyrrole polymer(ppy) has an excellent electrical conductivity and can be easily polymerized on anode to give various morophology according to doped anion on electroactive sites. To improve the properties of brittleness, ageing and hydrophobisity, poly furan polymer(pfu) having a high initiation potential was anodically implanted in this porous ppy film matrix to get the Pt/ppy/pfu(x)type of polymer composite electrode. Cyclic voltammetry and electrochemical impedance methods were used to these electrode, where $PF_6^-,\; BF_4^-$, and $ClO_4^-$ ions were employed as dopants. The composition of the pfu(x) at the electrode was changed from 0 to 1.10, but the range was useful only at 0.1 to 0.2 as the redox electrode. The polymer composite electrode doped with $PF_6^-$ was better in charge transfer resistance by a factor of 40 times and in double layer capacitance by a factor of 20 times than others. The charge transfer in the polymer film of the electrode was influenced on frequency change and equivalent circuit of this electrode had Warburg impedance including mass transfer.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.20 no.10
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• pp.1935-1940
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• 2016

This paper proposes a phase-locked loop (PLL) to minimize the loop filter output voltage fluctuation by using a comparator including RC time constant circuits. The voltage variation of loop filter is inputted to RC time constant circuits which have two RC time constants, large and small. While a small RC time constant circuit quickly conveys the output voltage variation of loop filter, a large RC time constant circuit conveys slowly the output voltage variation of loop filter and its output looks like constant voltage. The output signal of the comparator controls the sub charge pump and reduces the input voltage variation of voltage-controlled oscillator (VCO). Therefore, the proposed PLL generates a phase noise reduced signal. It has been designed with a 1.8V supply voltage, 0.18um multi - metal and multi - poly layer CMOS process and proved by Hspice simulation.

• Proceedings of the Korean Institute of Communication Sciences Conference
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• 1987.04a
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• pp.140-143
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• 1987

• Ceramist
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• v.20 no.3
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• pp.86-101
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• 2017

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.134-134
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• 2018

반데그라프 발전기는 큰 전위차를 생성하고 입자를 가속시키기 위해 발명된 정전기 발생기이다. 현재 반데그라프 발전기는 사이클로톤의 개발 이후 입자 가속 목적으로 주로 사용되고 있지는 않지만 접촉 전하 생성, 전달, 및 축적을 가능하게 하는 전하 운반 시스템에 기반하여 간단한 구조로 직류를 발생시킬 수 있는 점은 주목할만하다. 특히, 최근 경량성, 고효율 발전 등의 장점으로 에너지 하베스팅 분야에서 많은 관심을 받고 있는 마찰전기 에너지 하베스팅 기술 분야에서는 최근, 높은 에너지 저장 효율을 위해 직류 발생이 가능한 마찰전기 에너지 발전 소자에 대한 연구들이 진행되고 있다. 그러나 전하 운반 시스템을 기반으로 한 마찰 전기 직류 발전기에 대한 연구는 거의 이루어 지지 않았으며, 보고된 몇 연구에서는 저 전류, 고 임피던스 및 저효율과 같은 반데그라프 발전기의 구조적 및 물질적 한계를 극복하지 못했다. 또한 마찰에 의해 발생하는 마모에 의한 출력 감소 또한 해결되지 못한 문제이다. 따라서 뛰어난 마찰전기 특성과 함께 우수한 내마모성을 가지는 폴리머에 기반하여 기존의 한계를 극복 한 전하 운반 시스템 기반 마찰 전기 직류 발전기를 제안한다.

• Journal of the Korean Electrochemical Society
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• v.7 no.3
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• pp.138-142
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• 2004

The polyaniline films of emeraldine base (EB) and leucoemeraldine base (LEB) form doped with cam-phorsulfonic acid (CSA) were prepared by casting the mixed solution of chloroform and m-cresol on ITO (indium tin oxide) electrode. By analyzing UV-vis spectra of the mixed solutions, the effects of the secondary doping by m-cresol were obtained. And the conductivity of polyaniline film was increased with increasing m-cresol content. As the results of analyzing cyclic voltammograms, it was known that the redox peak currents of polyaniline electrode prepared from LEB were larger and more reversible than those of polyaniline eleclrodes prepared from EB. The charge transfer resistances $(R_{ct})$ of polyaniline electrodes were reduced with increasing m-cresol content, showing smaller Rct for LEB/CSA than EB/CSA.

• Polymer Science and Technology
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• v.21 no.5
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• pp.459-465
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• 2010

• Journal of the Korea Institute of Information and Communication Engineering
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• v.17 no.10
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• pp.2387-2394
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• 2013

A low spur phase-locked loop (PLL) with FVCO-sampled feedforward loop-filter has been proposed. Conventional PLL has loop filter made of a resistor and capacitors. The proposed PLL is working stably with the filter consisted of capacitors and a switch. It has been designed with a 1.8V $0.18{\mu}m$ CMOS process and proved by simulation with HSPICE.

• Journal of the Korean Society of Radiology
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• v.9 no.1
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• pp.39-45
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• 2015

$La_2W_3O_{12}:Eu^{3+}$ phosphors were prepared by solid state reaction method. The crystal structure was characterized by XRD pattern and ICSD card (78180). Luminescence properties of $La_2W_3O_{12}:Eu^{3+}$ are investigated by optical and laser-excitation spectroscopy in which emission and excitation spectra and time-resolved spectra are measured. The 1 mol % $Eu^{3+}$-doped $La_2W_3O_{12}$ phosphor exhibits broad excitation band peaking at 286 nm due to the ligand-to-metal charge transfer transition. The excitation lines due to the $^7F_0{\rightarrow}{^5D_4},{^5D_4},{^5L_6},{^5G_4},{^5D_3},{^5D_2}$ transitions of $Eu^{3+}$ are observed in the wavelength region 350-500 nm. The strong line emission is observed at 618 nm corresponding to the due to the $^5D_0{\rightarrow}^7F_2$ transition. The lifetime of 618 nm emission decreases with increasing temperature as 7 K ($114{\mu}s$), 100 K ($94{\mu}s$), 200 K ($10{\mu}s$) and 300 K ($0.5{\mu}s$).

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.05a
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• pp.63-64
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• 2006

본 연구에서는 광에너지를 화학적인 에너지로 변환할 때, 디바이스의 전하전달 매개를 위한 electron transfer mediator로서 널리 이용되는 Viologen이 자기조립화된 수정진동자률 전기화학법의 하나인 순환전압전류법(Cyclic Voltammetry)을 이용하여 산화 환원 반응 (redox reaction) 특성과 주사속도와 피크전류와의 상관관계를 분석하였다. 먼저 수정진동자를 친수 처리한 후, 메탄올 용액과 아세토니트릴 용액을 섞은 용매에 Viologen 분자를 자기조립 (self-assembly)하여, 전해질 용액의 농도 변화에 따른 산화 환원반응 특성과 피크전류의 값을 측정하였다 주사 속도를 2 배씩 증가하여 피크전류와의 상관관계를 조사한 결과, 선형적인 증가를 보였으며, 이를 통해 가역적인 반응(reversible reaction)이 일어났음을 확인할 수 있었다. 또한, 산화 환원 반응과 동시에 측정된 수정진동자의 공진 주파수(resonant frequency) 변화로부터 전하이동(charge transfer) 특성에 의해 반응에 참가한 이온의 질량을 알 수 있었다.