• Title/Summary/Keyword: 분산처리구조

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Characterizations of Adhesion Property, Morphology and Cure Reaction of Epoxy/Polyamide/MPD Reactive Blend with Imidazole(2E4MZ-CN) Catalyst (이미다폴(2E4MZ-CN) 촉매 첨가에 의한 에폭시/폴리아미드/MPD 반응성 블렌드의 경화 반응, 형태학적 특징 및 접착력 향상 연구)

  • Song, Hyun-Woo;Kang, Hak-Su;Kim, Won-Ho;Marzi, Stephan;Kim, Byung-Min;Choe, Young-Son
    • Polymer(Korea)
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    • v.33 no.4
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    • pp.290-296
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    • 2009
  • The morphology and mechanical properties of epoxy/polyamide/MPD/2E4MZ-CN reactive blends with various amount of catalyst were investigated. The cure behaviors, mechanical strengths, and morphological changes of the epoxy blend systems were analyzed by using DSC, UTM, and SEM, respectively. The amount of catalyst ranged from 0 to 3 phr, and the cure reaction occurred at $170^{\circ}C$ for 30 min. The maximum peaks in heat flow during cure reactions appeared at slightly lower temperature with increasing catalyst content, indicating that the cure reactions start at lower temperature by adding catalyst and polyamide rarely hinders the cure reaction paths. The co-continuous morphology was found in epoxy/polyamide(20 phr) blends and by adding catalyst to the blends much clearer and uniform co-continuous phase was observed. The surface tension of the mechanical test specimen was increased due to the AP plasma surface treatment, and then adhesion strength was increased by over 20% by adding 2 phr of catalyst to the blends. When considering morphological tuning of the blends by means of catalyst incorporation, it is expected that the increased elongation and adhesion strength can be achieved in the structural adhesive systems.

Hybrid Nanostructure-dependent Mechanical Properties and Crystallization Behaviors of Polypropylene/Clay Nanocomposites (폴리프로필렌/점토 나노복합체의 하이브리드 나노구조에 따른 기계적 성질 및 결정화거동 변화)

  • Choi, Ki-Woon;Lee, Han-Sup;Kang, Bok-Choon;Yang, Hoi-Chang
    • Polymer(Korea)
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    • v.34 no.4
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    • pp.294-299
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    • 2010
  • Clay-loaded polypropylene (PP) nanocomposites were fabricated via melt-compounding of two molecular weight ($M_w$) PPs (140 and 410 kg/mol) and octadecylammine-treated clay (C18MMT), with the assistance of maleic anhydride-grafted PP(PP-MAH), respectively, at $170^{\circ}C$ and $190^{\circ}C$. At both melt-compounding temperatures, the low-$M_w$ PP tends to easily diffuse into silicate layers, especially in the presence of the mobile PP-MAH, resulting in a marked increase in silicate layer spacing (above 58 $\AA$), when compared to 27 $\AA$ in the high-$M_w$ PP-based system. Due to relatively lower melt-viscosity of the low-$M_w$ PP-based system, however, there existed quasi-stacked clay aggregates with a thickness of 60~80 nm, while the high-$M_w$ PP-based nanocomposites showed relatively homogeneous dispersion of clays. The different morphologies are mainly related to changes in the viscoelastic properties of PPs, dependent on the processing temperature and their $M_{w}s$. The slight differences in nanocomposites induce discernible crystallization and mechanical behaviors. High-$M_w$ PP-based nanocomposites containing 1~3 wt% C18MMT showed improvement in both tensile strength and modulus, while maintaining the inherent ductility of pure PP.

Surface Wave Method II: Focused on Passive Method (표면파 탐사 II: 수동 탐사법을 중심으로)

  • Cho, Sung Oh;Joung, Inseok;Kim, Bitnarae;Jang, Hanna;Jang, Seonghyung;Hayashi, Koich;Nam, Myung Jin
    • Geophysics and Geophysical Exploration
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    • v.25 no.1
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    • pp.14-25
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    • 2022
  • The passive surface wave method measures seismic signals from ambient noises or vibrations of natural phenomena without using an artificial source. Since passive sources are usually in lower frequencies than artificial ones being able to ensure the information on deeper geological structures, the passive surface wave method can investigate deeper geological structures. In the passive method, frequency dispersion curves are obtained after data acquisition, and the dispersion curves are analyzed by assuming 1D-layered earth, which is like the method of active surface wave survey. However, when computing dispersion curves, the passive method first obtains and analyzes coherence curves of received signals from a set of receivers based on spatial autocorrelation. In this review, we explain how passive surface wave methods measure signals, and make data processing and interpretation, before analyzing field application cases.

Investigation on the Mechanical Properties of High-Strength Recycled Fine Aggregate Mortar Made of Nanosilica Dispersed by Sonication (나노실리카 혼입률이 실리카퓸 및 고로슬래그 미분말을 혼입한 4성분계 고강도 순환잔골재 모르타르의 역학적 성능에 미치는 영향)

  • Seong-Woo Kim;Rae-Gyo Moon;Eun-Bi Cho;Chul-Woo Chung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.2
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    • pp.97-104
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    • 2023
  • In order to maximize the utilization of recycled fine aggregate, high strength mortar made of 100 % recycled fine aggregate was prepared, and its physical properties were evaluated to determine the possibility of using recycled fine aggregate as structural aggregate. The effect caused by the amount of nanosilica on the physical properties of w/b 0.2 recycled fine aggregate mortar consisting of cement, silica fume, and blast furnace slag. To improve the dispersion of nanosilica inside mortar, an aqueously dispersed nanosilica solution by ultrasonic tip sonication was prepared, and incorporated into the mortar to evaluate changes in mortar flow, porosity and compressive strength depending on nanosilica content. According to the experimental results, mortar flow decreased as the replacement ratio of nano-silica increased. As the replacement ratio of nanosilica increased up to 0.75 %, the porosity decreased and the compressive strength increased, but, at a replacement ratio of 1 %, the porosity increased and the compressive strength decreased. It was confirmed that the nano-silica replacement ratio of 0.75 % was optimum proportion to maximize the mechanical performance of high-strength recycled fine aggregate mortar.

Study of Adhesion Phenomena of Alkoxysilane-type Consolidants on Fresh Granites (알콕시 실란계 석재 강화제의 화강암 점착 특성 연구)

  • Kim, Eun-Kyung;Son, Seung-Hwan;Won, Jong-Ok;Kim, Jeong-Jin;Kim, Sa-Dug
    • Journal of Conservation Science
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    • v.23
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    • pp.1-10
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    • 2008
  • Consolidants based on tetraethoxysilane (TEOS) such as alkoxysilanes have been widely used for the consolidation of decaying stone heritages. Low-viscosity alkoxysilanes penetrate inside the decaying stone and polymerize within the porous structure of the decaying stone, significantly increasing the cohesion of the material. However, TEOS-based consolidants suffer from practical drawbacks, such as crack formation of the gel during the drying phase due to the developed capillary force, which is typical for TEOS-based consolidants. We prepared new consolidants TEOS-based consolidants containing flexible (3-glycidoxypropyl)trimethoxysilane (GPTMS) and silica nanoparticles (or polyhedral oligomeric silsesquioxanes (POSS)) in order to reduce capillary force development during gel drying. Since the consolidants should have a good interaction with the component of the stone in order to connect the isolate grains of decaying stone, the adhesion interaction of the developed consolidants on the surface of the granite was macroscopically investigated by the ISO 2409 cross cutting test. The adhesion interaction decreased with the addition of silica nanoparticle and POSS while it increased with the addition of GPTMS in TEOS solution.

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Effect of AlF3 on Zr Electrorefining Process in Chloride-Fluoride Mixed Salts for the Treatment of Cladding Hull Wastes (폐 피복관 처리를 위한 염소계-불소계 혼합용융염 내 지르코늄 전해정련공정에서 삼불화알루미늄의 효과 연구)

  • Lee, Chang Hwa;Kang, Deok Yoon;Lee, Sung-Jai;Lee, Jong-Hyeon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.17 no.2
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    • pp.127-137
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    • 2019
  • Zr electrorefining is demonstrated herein using Zirlo tubes in a chloride-fluoride mixed molten salt in the presence of $AlF_3$. Cyclic voltammetry reveals a monotonic shift in the onset of metal reduction kinetics towards positive potential and an increase in intensity of the additional peaks associated with Zr-Al alloy formation with increasing $AlF_3$ concentration. Unlike the galvanostatic deposition mode, a radial plate-type Zr growth is evident at the top surface of the salt during Zr electrorefining at a constant potential of -1.2 V. The diameter of the plate-type Zr deposit gradually increases with increasing $AlF_3$ concentration. Scanning electron microscopy-energy-dispersive X-ray spectroscopy (SEM-EDX) and X-ray photoelectron spectroscopy (XPS) analyses for the plate-type Zr deposit show that trace amount of Al is incorporated as Zr-Al alloys with different chemical compositions between the top and bottom surface of the deposit. Addition of $AlF_3$ is effective in lowering the residual salt content in the deposit and in improving the current efficiency for Zr recovery.

Reinforced Polymer/Clay Nanocomposite Foams with Open Cell Prepared via High Internal Phase Emulsion Polymerization (고내상 에멀션 중합에 의해 제조된 열린 기공을 갖는 고장도 고분자/점토 나노복합 발포체)

  • Song, In-Hee;Kim, Byung-Chul;Lee, Seong-Jae
    • Polymer(Korea)
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    • v.32 no.2
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    • pp.183-188
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    • 2008
  • Reinforced open cell micro structured foams were prepared by the polymerization of high internal phase emulsions incorporating inorganic thickeners. Organoclays were used as oil phase thickener, and sodium montmorillonite was used as aqueous phase thickener. Rheological properties of emulsions increased as oil phase thickener concentration and agitation speed increased, due to the reduced drop size reflecting both competition between continuous and dispersed phase viscosities and increase of shear force. Drop size variation with thickener concentration could be explained by a dimensional analysis between capillary number and viscosity ratio. Upon the foams polymerized by the emulsions, compression properties, such as crush strength and Young's modulus were measured and compared. Among the microcellular foams, the foam incorporated with an organoclay having reactive group showed outstanding properties. It is speculated that the exfoliated silicate layers inside polystyrene matrix, resulting in nanocomposite foam, are the main reason why this foam has enhanced properties.

Development of Realtime Multimedia Streaming Service using Mobile Smart Devices (모바일 스마트 단말을 활용한 실시간 멀티미디어 스트리밍 서비스 개발)

  • Park, Mi-Ryong;Sim, Han-Eug
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.14 no.4
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    • pp.51-56
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    • 2014
  • Thesedays, there are many smart device applications developed, especially on the using various sensors included in the smart device. Smart devices have several sensors which are camera, GPS, mike, and communication module for collecting ubiquitous environment, and many applications are developed by using such sensors. In this paper, we developed the multimedia stream architecture and examined the smart device applications based on open source with front and back-end server clouds for developing the conceptual architecture. Also, we examined the back-end distributed servers, realtime multimedia stream transferring, multi-media store, and media relay for other server and smart devices. We test the examined architecture on the real target environment to collect the SIP initial setup time, media stream delay, and end-to-end play time. The test results show that there have good network operation environment to provide realtime multimedia services, and we need to improve the end-to-end play time by minimizing the initial setup time.

Implementation of CORBA based Spatial Data Provider for Interoperability (상호운용을 지원하는 코바 기반 공간 데이터 제공자의 설계 및 구현)

  • Kim, Min-Seok;An, Kyoung-Hwan;Hong, Bong-Hee
    • Journal of Korea Spatial Information System Society
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    • v.1 no.2 s.2
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    • pp.33-46
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    • 1999
  • In distributed computing platforms like CORBA, wrappers are used to integrate heterogeneous systems or databases. A spatial data provider is one of the wrappers because it provides clients with uniform access interfaces to diverse data sources. The individual implementation of spatial data providers for each of different data sources is not efficient because of redundant coding of the wrapper modules. This paper presents a new architecture of the spatial data provider which consists of two layered objects : independent wrapper components and dependent wrapper components. Independent wrapper components would be reused for implementing a new data provider for a new data source, which dependent wrapper components should be newly coded for every data source. This paper furthermore discussed the issues of implementing the representation of query results in the middleware. There are two methods of keeping query results in the middleware. One is to keep query results as non-CORBA objects and the other is to transform query results into CORBA objects. The evaluation of the above two methods shows that the cost of making CORBA objects is very expensive.

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A PAPR Reduction Method Using the ACE(Active Constellation Extension) in the OFDM Communication System (OFDM 통신 시스템에서 능동 성상도 확장을 이용한 PAPR 감소 기법)

  • Kang Byoung-Moo;Kim Sang-Woo;Ryu Heung-Gyoon
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.16 no.6 s.97
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    • pp.586-593
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    • 2005
  • It is very important to reduce the PAPR(Peak to Average Power Ratio) in the OFDM(Orthogonal Frequency Division Multiplexing) communication system. We propose an ACE(Active Constellation Extension) method that does not require the side information unlike the conventional PTS and SLM method. This ACE method is to clip the OFDM signal for the PAPR reduction. Then, the basic constellation actively moves into the higher level of M-QAM for the constellation extension due to the clipping. The already existing M-QAM system can be available so that it can be easily realized. So, we can get the target PAPR by the extension of the constellation level. In this paper, we can find the PAPR reduction of 4 dB by the 16-QAM extension, and can achieve the target PAPR by the 64-QAM ACE(Active Constellation Extension).