• 제목/요약/키워드: $N_s$

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SnOn, SnO2n, SnO3n (n = 1~4)의 열역학적 안정성과 결합에너지에 대한 DFT 이론 연구 (DFT Study for the Thermodynamic Stability and Binding Energeticsof SnOn, SnO2n, SnO3n (n = 1~4))

  • 김시조;김승준
    • 대한화학회지
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    • 제53권5호
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    • pp.512-520
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    • 2009
  • 본 연구에서는 반응성이 큰 황이 산소와 결합하여 산화황이 되고 이것들이 클러스터를 이루었 을 때의 구조와 결합에너지에 대하여 조사하였다. $S_{n}O_{n},\;S_{n}O_{2n},\;S_{n}O_{3n}\;(n\;=\;1{\sim}4)$까지의 여러 가능한 분자 구조를 B3LYP/6-311G** 이론수준까지 최적화 하였으며, 단량체($SO,\;SO_2,\;SO_3$)가 증가할 때의 결합에너지를 MP2/6-311G** 수준까지 계산하였다. $SnOn\;(n\;=\;1{\sim}4)$의 경우 S-O 단량체 증가에 따라 상대적으로 안정화되는 경향이 강하게 나타났으며, 약 20-25 kcal/mol 정도 증가하는 것으로 예측 되었다. 반면 $S_nO_{2n},\;S_nO_{3n} \;(n\;=\;1{\sim}4)$의 경우에는 $SO_2$$SO_3$ 의 증가에 따른 열역학적 안정성이 상대적으로 덜 안정화 되는 것으로 나타났으며, SO2 단량체가 증가함에 따른 결합에너지 변화는 2.2 kcal/mol, 그리고 $SO_3$ 단량체가 증가함에 따라 흡열반응으로 나타나 열역학적으로 더욱 불안정해질 것으로 예상된다.

SUMMING AND DOMINATED OPERATORS ON A CARTESIAN PRODUCT OF c0 (𝓧) SPACES

  • Badea, Gabriela;Popa, Dumitru
    • 대한수학회지
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    • 제54권3호
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    • pp.967-986
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    • 2017
  • We give the necessary condition for an operator defined on a cartesian product of $c_0(\mathcal{X})$ spaces to be summing or dominated and we show that for the multiplication operators this condition is also sufficient. By using these results, we show that ${\Pi}_s(c_0,{\ldots},c_0;c_0)$ contains a copy of $l_s(l^m_2{\mid}m{\in}\mathbb{N})$ for s > 2 or a copy of $1_s(l^m_1{\mid}{\in}\mathbb{N})$, for any $l{\leq}S$ < ${\infty}$. Also ${\Delta}_{s_1,{\ldots},s_n}(c_0,{\ldots},c_0;c_0)$ contains a copy of $l_{{\upsilon}_n(s_1,{\ldots},s_n)}$ if ${\upsilon}_n(s_1,{\ldots},s_n){\leq}2$ or a copy of $l_{{\upsilon}_n(s_1,{\ldots},s_n)}(l^m_2{\mid}m{\in}\mathbb{N})$ if 2 < ${\upsilon}_n(s_1,{\ldots},s_n)$, where ${\frac{1}{{\upsilon}_n(s_1,{\ldots},s_n})}={\frac{1}{s_1}}+{\cdots}+{\frac{1}{s_n}}$. We find also the necessary and sufficient conditions for bilinear operators induced by some method of summability to be 1-summing or 2-dominated.

평면사각형 혼합 리간드 착물의 합성과 그 특성 (제 2 보) : Ni(II), Pd(II) 및 Pt(II)의 M(S-S)(N-N)형 착물의 친전자성 및 친핵성 반응 (Synthesis and Characterization of Square Planar Mixed-Ligand Complexes (II) : Electrophilic and Nucleophilic Reaction of M(S-S)(N-N) Type Complexes with Ni(II), Pd(II), and Pt(II))

  • 오상오;정덕영
    • 대한화학회지
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    • 제36권1호
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    • pp.81-86
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    • 1992
  • M(S-S,ph)(N-N,H) (M = Ni(II), Pd(II), Pt(II); (S-S,ph) = 1,2-diphenylethylenedithiolate; (N-N,H)=1,10-phenanthroline) 착물의 친전자성 및 친핵성 리간드 반응을 조사하였다. norbornadiene과의 반응성은 중심금속의 역결합의 정도에 의존하며 2,5-dithia-3,4-diphenyl-tricyclo[4,4,1,0]-undeca-3,8-diene을 생성하였다. methyl iodide와의 반응은 (N-N,H) 리간드의 이탈 능력에 지배되며 메틸화된 $M(S-S,ph)_2$ 착물을 생성하였다. 이 반응의 주생성무리은 열 분해에 의해 얻어진 ${\alpha},{\alpha}{\prime}$,-bismethylthiostibene $(CH_3S-SCH_3,ph)$의 구조로부터 M(S-S,CN)(N-N,H)((S-S,CN) = 1,2-dicyanoethylenedithiolate)의 새로운 혼합 리간드 착물을 합성하였다.

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(p)ZnTe/(n)Si 태양전지와 (n)CdS-(p)ZnTe/(n)Si 복접합 박막의 광도전 특성에 관한 연구 (A Study on the Photo-Conductive Characteristics of (p)ZnTe/(n)Si Solar Cell and (n)CdS-(p)ZnTe/(n)Si Poly-Junction Thin Film)

  • 전춘생;김완태;허창수
    • 태양에너지
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    • 제11권3호
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    • pp.74-83
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    • 1991
  • 본 논문은 substrate의 온도를 $200{\pm}1^{\circ}C$ 정도로 유지하며 진공저항 가열 증착법을 이용하여 (p)ZnTe/(n)Si 태양전지와 (n)CdS-(p)ZnTe/(n)Si 복접합 박막을 제작한 후 그 전기적 특성을 조사, 비교하였다. 제작한 (p)ZnTe/(n)Si 태양전지와(n)CdS-(p)ZnTe/(n)Si 복접합 박막에 대하여 $100[mW/cm^2]$의 광조사 하에서 특성을 조사한바 다음과 같은 결과를 얻었다. 단략전류$[mA/cm^2]$ (p)ZnTe/(n)Si:28 (n)CdS-(p)ZnTe/(n)Si:6.5 개방전압[mV] (p)ZnTe/(n)Si:450 (n)CdS-(p)ZnTe/(n)Si:250 충실도, FF (p)ZnTe/(n)Si:0.65 (n)CdS-(p)ZnTe/(n)Si:0.27 변환효율[%] (p)ZnTe/(n)Si:8.19 (n)CdS-(p)ZnTe/(n)Si:2.3 제작된 박막은 열처리에 의해 성능이 향상되지만 (p)ZnTe/(n)Si 태양전지는 약 $470^{\circ}C$ 이상의 온도와 15분 이상의 열처리 시간에서 그리고 (n)CdS-(p)ZnTe/(n)Si 복접합 박막은 약 $580^{\circ}C$ 이상의 온도와 15분 이상의 열처리 시간에서는 박막의 각종 구조결함으로 인한 감소현상을 나타내었다. 열처리 온도의 증가에 따라 박막의 표면저항은 감소하였다.

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The Line n-sigraph of a Symmetric n-sigraph-V

  • Reddy, P. Siva Kota;Nagaraja, K.M.;Geetha, M.C.
    • Kyungpook Mathematical Journal
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    • 제54권1호
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    • pp.95-101
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    • 2014
  • An n-tuple ($a_1,a_2,{\ldots},a_n$) is symmetric, if $a_k$ = $a_{n-k+1}$, $1{\leq}k{\leq}n$. Let $H_n$ = {$(a_1,a_2,{\ldots},a_n)$ ; $a_k$ ${\in}$ {+,-}, $a_k$ = $a_{n-k+1}$, $1{\leq}k{\leq}n$} be the set of all symmetric n-tuples. A symmetric n-sigraph (symmetric n-marked graph) is an ordered pair $S_n$ = (G,${\sigma}$) ($S_n$ = (G,${\mu}$)), where G = (V,E) is a graph called the underlying graph of $S_n$ and ${\sigma}$:E ${\rightarrow}H_n({\mu}:V{\rightarrow}H_n)$ is a function. The restricted super line graph of index r of a graph G, denoted by $\mathcal{R}\mathcal{L}_r$(G). The vertices of $\mathcal{R}\mathcal{L}_r$(G) are the r-subsets of E(G) and two vertices P = ${p_1,p_2,{\ldots},p_r}$ and Q = ${q_1,q_2,{\ldots},q_r}$ are adjacent if there exists exactly one pair of edges, say $p_i$ and $q_j$, where $1{\leq}i$, $j{\leq}r$, that are adjacent edges in G. Analogously, one can define the restricted super line symmetric n-sigraph of index r of a symmetric n-sigraph $S_n$ = (G,${\sigma}$) as a symmetric n-sigraph $\mathcal{R}\mathcal{L}_r$($S_n$) = ($\mathcal{R}\mathcal{L}_r(G)$, ${\sigma}$'), where $\mathcal{R}\mathcal{L}_r(G)$ is the underlying graph of $\mathcal{R}\mathcal{L}_r(S_n)$, where for any edge PQ in $\mathcal{R}\mathcal{L}_r(S_n)$, ${\sigma}^{\prime}(PQ)$=${\sigma}(P){\sigma}(Q)$. It is shown that for any symmetric n-sigraph $S_n$, its $\mathcal{R}\mathcal{L}_r(S_n)$ is i-balanced and we offer a structural characterization of super line symmetric n-sigraphs of index r. Further, we characterize symmetric n-sigraphs $S_n$ for which $\mathcal{R}\mathcal{L}_r(S_n)$~$\mathcal{L}_r(S_n)$ and $$\mathcal{R}\mathcal{L}_r(S_n){\sim_=}\mathcal{L}_r(S_n)$$, where ~ and $$\sim_=$$ denotes switching equivalence and isomorphism and $\mathcal{R}\mathcal{L}_r(S_n)$ and $\mathcal{L}_r(S_n)$ are denotes the restricted super line symmetric n-sigraph of index r and super line symmetric n-sigraph of index r of $S_n$ respectively.

THE FRACTIONAL TOTIENT FUNCTION AND STURMIAN DIRICHLET SERIES

  • Kwon, DoYong
    • 호남수학학술지
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    • 제39권2호
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    • pp.297-305
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    • 2017
  • Let ${\alpha}$ > 0 be a real number and $(s_{\alpha}(n))_{n{\geq}1}$ be the lexicographically greatest Sturmian word of slope ${\alpha}$. We investigate Dirichlet series of the form ${\sum}^{\infty}_{n=1}s_{\alpha}(n)n^{-s}$. To do this, a generalization of Euler's totient function is required. For a real ${\alpha}$ > 0 and a positive integer n, an arithmetic function ${\varphi}{\alpha}(n)$ is defined to be the number of positive integers m for which gcd(m, n) = 1 and 0 < m/n < ${\alpha}$. Under a condition Re(s) > 1, this paper establishes an identity ${\sum}^{\infty}_{n=1}s_{\alpha}(n)n^{-S}=1+{\sum}^{\infty}_{n=1}{\varphi}_{\alpha}(n)({\zeta}(s)-{\zeta}(s,1+n^{-1}))n^{-s}$.

NONLINEAR MIXED *-JORDAN TYPE n-DERIVATIONS ON *-ALGEBRAS

  • Raof Ahmad Bhat;Abbas Hussain Shikeh;Mohammad Aslam Siddeeque
    • 대한수학회논문집
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    • 제39권2호
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    • pp.331-343
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    • 2024
  • Let ℜ be a *-algebra with unity I and a nontrivial projection P1. In this paper, we show that under certain restrictions if a map ψ : ℜ → ℜ satisfies $$\Psi(S_1{\diamond}S_2{\cdot}{\cdot}{\cdot}{\diamond}S_{n-1}{\bullet}S_n)=\sum_{k=1}^nS_1{\diamond}S_2{\diamond}{\cdot}{\cdot}{\cdot}{\diamond}S_{k-1}{\diamond}{\Psi}(S_k){\diamond}S_{k+1}{\diamond}{\cdot}{\cdot}{\cdot}{\diamond}S_{n-1}{\bullet}S_n$$ for all Sn-2, Sn-1, Sn ∈ ℜ and Si = I for all i ∈ {1, 2, . . . , n - 3}, where n ≥ 3, then ψ is an additive *-derivation.

CONSTRUCTIVE PROOF FOR THE POSITIVITY OF THE ORBIT POLYNOMIAL On,2d(q)

  • Lee, Jaejin
    • Korean Journal of Mathematics
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    • 제25권3호
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    • pp.349-358
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    • 2017
  • The cyclic group $C_n={\langle}(12{\cdots}n){\rangle}$ acts on the set $(^{[n]}_k)$ of all k-subsets of [n]. In this action of $C_n$ the number of orbits of size d, for d | n, is $$O^{n,k}_d={\frac{1}{d}}{\sum\limits_{{\frac{n}{d}}{\mid}s{\mid}n}}{\mu}({\frac{ds}{n}})(^{n/s}_{k/s})$$. Stanton and White [6] generalized the above identity to construct the orbit polynomials $$O^{n,k}_d(q)={\frac{1}{[d]_{q^{n/d}}}}{\sum\limits_{{\frac{n}{d}}{\mid}s{\mid}n}}{\mu}({\frac{ds}{n}})[^{n/s}_{k/s}]_{q^s}$$ and conjectured that $O^{n,k}_d(q)$ have non-negative coefficients. In this paper we give a constructive proof for the positivity of coefficients of the orbit polynomial $O^{n,2}_d(q)$.

CONVERGENCE THEOREMS OF THE ITERATIVE SEQUENCES FOR NONEXPANSIVE MAPPINGS

  • Kang, Jung-Im;Cho, Yeol-Je;Zhou, Hai-Yun
    • 대한수학회논문집
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    • 제19권2호
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    • pp.321-328
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    • 2004
  • In this paper, we will prove the following: Let D be a nonempty of a normed linear space X and T : D -> X be a nonexpansive mapping. Let ${x_n}$ be a sequence in D and ${t_n}$, ${s_n}$ be real sequences such that (i) $0\;{\leq}\;t_n\;{\leq}\;t\;<\;1\;and\;{\sum_{n=1}}^{\infty}\;t_n\;=\;{\infty},\;(ii)\;(a)\;0\;{\leq}\;s_n\;{\leq}\;1,\;s_n\;->\;0\;as\;n\;->\;{\infty}\;and\;{\sum_{n=1}}^{\infty}\;t_ns_n\;<\;{\infty}\;or\;(b)\;s_n\;=\;s\;for\;all\;n\;{\geq}\;1\;and\;s\;{\in}\;[0,1),\;(iii)\;x_{n+1}\;=\;(1-t_n)x_n+t_nT(s_nTx_n+(1-s_n)x_n)\;for\;all\;n\;{\geq}\;1.$ Then, if the sequence {x_n} is bounded, then $lim_{n->\infty}\;$\mid$$\mid$x_n-Tx_n$\mid$$\mid$\;=\;0$. This result improves and complements a result of Deng [2]. Furthermore, we will show that certain conditions on D, X and T guarantee the weak and strong convergence of the Ishikawa iterative sequence to a fixed point of T.

COMBINATORIAL PROOF FOR THE POSITIVITY OF THE ORBIT POLYNOMIAL $O^{n,3}_d(q)$

  • Lee, Jae-Jin
    • Journal of applied mathematics & informatics
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    • 제30권3_4호
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    • pp.455-462
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    • 2012
  • The cyclic group $Cn={\langle}(12{\cdots}n){\rangle}$ acts on the set ($^{[n]}_k$) of all $k$-subsets of [$n$]. In this action of $C_n$ the number of orbits of size $d$, for $d|n$, is $$O^{n,k}_d=\frac{1}{d}\sum_{\frac{n}{d}|s|n}{\mu}(\frac{ds}{n})(^{n/s}_{k/s})$$. Stanton and White[7] generalized the above identity to construct the orbit polynomials $$O^{n,k}_d(q)=\frac{1}{[d]_{q^{n/d}}}\sum_{\frac{n}{d}|s|n}{\mu}(\frac{ds}{n})[^{n/s}_{k/s}]{_q}^s$$ and conjectured that $O^{n,k}_d(q)$ have non-negative coefficients. In this paper we give a combinatorial proof for the positivity of coefficients of the orbit polynomial $O^{n,3}_d(q)$.