• Title/Summary/Keyword: $CO_2$ recovery

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Study on the Performance Characteristics of Exhaust Heat Recovery Device in Automobile (자동차용 배기열 회수 장치의 성능 특성에 관한 연구)

  • Hong, Young-Jun;Choi, Doo-Seuk;Kim, Jong-Il
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.2
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    • pp.78-84
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    • 2012
  • The purpose of this study is to investigate the performance characteristics of new exhaust heat recovery device for the engine's fast warm-up. In this study, two different interior area designed for prototyping and on the exhaust heat recovery device to evaluate the performance compare the performance characteristics were chosen a better product. A company's product and selected prototype-2 were evaluated and compared the performance. This experiment was conducted under the same conditions. The time from starting to warm-up of engine was measured. As a result, the performance characteristics of the prototype-2 was not higher than that of the A company's product. However, in comparison with base system, prototype-2 of the exhaust heat recovery device discover that the warm-up time was shortened.

Comparison of Sampling Filters for Airborne Hexavalent Chromium in Plating Operation (도금공정 공기중 6가 크롬 시료채취여과지 비교에 관한 연구)

  • 이병규;신용철
    • Journal of Environmental Health Sciences
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    • v.29 no.2
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    • pp.69-76
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    • 2003
  • Hexavalent chromium may reduce on polyvinyl chloride (PVC) filter during sampling and storage of sample. Recently, new or modified filters for preventing Cr(VI) from the reduction has been introduced. Thus, this study was performed to compare the reduction behaviors of Cr(VI) on several sampling filters and to find the most appropriate filter for airborne Cr(VI) sampling in plating operation. The results were as follows. 1. There were statistically significant differences among PVC, polytetrafluoroethylene (PTFE). glass fiber (GF) and polyvinylidene fluoride (PVDF) filters in recovery rates of spiked Cr(VI) samples by storage time(p<0.05). There was no significant difference between PVC and PTFE filters(p>0.05). The PVC and PTFE filters showed higher recoveries than GF and PVDF filters(p<0.05). 2. The quartz fiber(QF) filter treated with an alkali solution(2% NaOH/3% Na$_2$CO$_3$, 1% NaOH) showed a significantly higher recovery of Cr(VI) by storage time than other filters(GF and QF filter)(p<0.05). There was no difference in recovery of Cr(VI) between alkali-treated and untreated GF it filters(p>0.05). But the QF filters treated with two alkali solution showed a significantly higher recovery than the untreated QF filter(p<0.05). There was no significant difference in recovery of Cr(VI) between QF filters treated with 1% NaOH and 2% NaOH/3% Na$_2$CO$_3$(p>0.05). In conclusion, treatment of QF fillers with alkali solution was most effective in protecting from the reduction of Cr(VI).

Reprocessing of fluorination ash surrogate in the CARBOFLUOREX process

  • Boyarintsev, Alexander V.;Stepanov, Sergei I.;Chekmarev, Alexander M.;Tsivadze, Aslan Yu.
    • Nuclear Engineering and Technology
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    • v.52 no.1
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    • pp.109-114
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    • 2020
  • This work presents the results of laboratory scale tests of the CARBOFLUOREX (CARBOnate FLUORide EXtraction) process - a novel technology for the recovery of U and Pu from the solid fluorides residue (fluorination ash) of Fluoride Volatility Method (FVM) reprocessing of spent nuclear fuel (SNF). To study the oxidative leaching of U from the fluorination ash (FA) by Na2CO3 or Na2CO3-H2O2 solutions followed by solvent extraction by methyltrioctylammonium carbonate in toluene and purification of U from the fission products (FPs) impurities we used a surrogate of FA consisting of UF4 or UO2F2, and FPs fluorides with stable isotopes of Ce, Zr, Sr, Ba, Cs, Fe, Cr, Ni, La, Nd, Pr, Sm. Purification factors of U from impurities at the solvent extraction refining stage reached the values of 104-105, and up to 106 upon the completion of the processing cycle. Obtained results showed a high efficiency of the CARBOFLUOREX process for recovery and separating of U from FPs contained in FA, which allows completing of the FVM cycle with recovery of U and Pu from hardly processed FA.

A Study on the Release Characteristics of VOCs from Heat Recovery Ventilation System (폐열회수형 환기장치의 휘발성유기화함물 배출 특성에 관한 연구)

  • Kwak, Kyung-Min;Bai, Cheol-Ho;Kim, Jee-Yong;Chu, Euy-Sung
    • Clean Technology
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    • v.13 no.4
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    • pp.281-286
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    • 2007
  • VOCs from the heat recovery ventilation system (total heat exchanger) are measured in this study. Two different types of element (L and M type) from heat recovery ventilating system are tested to study the intial release characteristics of VOCs under KS cooling and heating standard conditions. VOCs are measured for the various flow rates and different operating times. Considering errors in the test method and the measuring instrument, the tested heat recovery ventilating systems was found to release 6 major VOCs, such as acetic acid, 2-butanone (MEK), 2-(methylthio )ethylamine, toluene, styrene, and x-acids (Ion 57). The concentrations of released VOCs are not quite much affected by operating conditions. The results show much larger VOCs concentrations in the cooling mode than in the heating mode, due to the high operating temperatures.

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Fast Responding Gas Sensors Using Sb-Doped SnO2 Nanowire Networks (Sb-첨가 SnO2 나노선 네트워크를 이용한 고속응답 가스센서)

  • Kwak, Chang-Hoon;Woo, Hyung-Sik;Lee, Jong-Heun
    • Journal of Sensor Science and Technology
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    • v.22 no.4
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    • pp.302-307
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    • 2013
  • The Sb-doped $SnO_2$ nanowire network sensors were prepared by thermal evaporation of the mixtures between tin and antimony powders. Pure $SnO_2$ nanowire networks showed high sensor resistance in air ($99M{\Omega}$), similar gas responses to 4 diffferent gases (5 ppm $C_2H_5OH$, CO, $H_2$, and trimethylamine), and very sluggish recovery speed (90% recovery time > 800 s). In contrast, 2 wt% Sb-doped $SnO_2$ showed the selective detection toward $C_2H_5OH$ and trimethylamine, relatively low resistance ($176k{\Omega}$) for facile measurement, and ultrafast recovery speed (90% recovery times: 6 - 18 s). The change of gas sensing charactersitics by Sb doping was discussed in relation to gas sensing mechanism.

Membrane-Based Carbon Dioxide Separation Process for Blue Hydrogen Production (블루수소 생산을 위한 이산화탄소 포집용 2단 분리막 공정 최적화 연구)

  • Jin Woo Park;Joonhyub Lee;Soyeon Heo;Jeong-Gu Yeo;Jaehoon Shim;Jinhyuk Yim;Chungseop Lee;Jin Kuk Kim;Jung Hyun Lee
    • Membrane Journal
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    • v.33 no.6
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    • pp.344-351
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    • 2023
  • The membrane separation process for carbon dioxide capture from hydrogen reformer exhaust gas has been developed. Using a commercial membrane module, a multi-stage process was developed to achieve 90% of carbon dioxide purity and 90% of recovery rate for ternary mixed gas. Even if a membrane module with being well-known properties such as material selectivity and permeability, the process performance of purity and recovery widely varies depending on the stage-cut, the pressure at feed and permeate side. In this study, we verify the limits of capture efficiency at single-stage membrane process under various operating conditions and optimized the two-stage recovery process to simultaneously achieve high purity and recovery rate.

Burst Mode Symbol Timing Recovery for VDL Mode-2 (VDL Mode-2에 적용 가능한 버스트 모드 심벌 타이밍 복원기)

  • Gim, Jong-Man;Choi, Seung-Duk;Eun, Chang-Soo
    • Journal of Advanced Navigation Technology
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    • v.13 no.3
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    • pp.337-343
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    • 2009
  • In this paper, we proposed a burst mode symbol timing recovery unit that is applicable to the VDL Mode-2 using D8PSK modulation. A method that IIR loop filter is used to minimize symbol timing error is hard to apply to burst mode because its convergence time is long. That is, the fast convergence property is important. In this paper, the proposed method takes one sample which has maximum symbol power after the initial synchronization has been achieved by using preambles. The main principle of operation is that the unit moves one sample clock to advance or retard according to symbol power. We verify that the proposed method is operated well in ${\pm}100$ ppm or greater through the test results between Australia ADS Corp. transmitter and the designed receiver.

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Recovery of Rare Metals from the Waste Secondary Lithium Ion Battery Cathode Active Materials Using Lactic Acid and Oxalic acid (젖산과 옥살산을 이용한 폐 이차 리튬이온 전지 양극 활물질로부터 희유금속들의 회수)

  • Kim, Younjung;Han, Ji Sun;Choi, Sik Young;Oh, In-Gyung;Hong, Yong Pyo;Ryoo, Keon Sang
    • Journal of the Korean Chemical Society
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    • v.63 no.6
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    • pp.446-452
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    • 2019
  • We have developed a method that can leach Co, Mn, and Ni in the cathode active material safely using lactic acid. When cathode active material was leached by lactic acid, lactic acid showed the highest efficiency at 2 N than 1 N and above 4 N concentration. When the cathode active material was added incrementally into the solution of lactic acid, the maximum solubility was 30 g/L at 2 N concentration. Oxalic acid was added in the solution of lactic acid and it showed that rare metals represent the most economical recovery efficiency at 4 g/L. Based on this study, it was found that the optimal condition for recovery of rare metals from cathode active material is oxalic acid : cathode active material = 7 : 1 as a ratio of weight. In addition, it was observed that the precipitate produced by oxalic acid is a polynuclear crystalline material bonded with 3 components of Co, Ni, and Mn.

Study on Formation Behaviors of Hydroquinone Clathrates with CO2 and N2 for Application to Selective CO2 Separation/Recovery from Flue Gases (배가스 중 CO2 분리/회수로의 응용을 위한 CO2 및 N2 하이드로퀴논 크러스레이트의 형성 거동 연구)

  • LEE, DONGWON;YOON, JI-HO;LEE, JONG-WON
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.3
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    • pp.289-295
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    • 2019
  • Effects of various reaction factors such as pressure, time, and temperature on clathrate formation were investigated for hydroquinone with $CO_2$ and $N_2$. Experimental and spectroscopic results indicate that $CO_2$ plays more preferential role in forming hydroquinone clathrates than $N_2$. These results can be used in application of selective $CO_2$ separation from flue gases with the formation of clathrate compounds.

Synthesis of Soluble Copolyimides Using an Alicyclic Dianhydride and Their $CO_2/CH_4$ Separation Properties (지환족 다이안하이드라이드를 이용한 용해성 폴리이미드 공중합체 합성 및 메탄/이산화탄소 분리특성)

  • Park, Chae Young;Lee, Yongtaek;Kim, Jeong Hoon
    • Membrane Journal
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    • v.24 no.1
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    • pp.1-9
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    • 2014
  • In this study, four soluble homo- and co-polyimides using 5-(2,5-dioxotetrahydrofuryl)-3-methyl-3-cyclohexene-1,2-dicarboxylic anhydride (DOCDA) and 4,4'-diaminodiphenyl ether (ODA) monomers were synthesized to develop the gas separation membrane with good $CO_2/CH_4$ separation properties. To prepare the copolyimides, 20 mol% of three dianhydrides - (4,4'-(hexafluoroisoproplidene)diphthalic anhydride (6FDA), 4,4'-biphthalic anhydride (BPDA), 3,3',4,4'-benzophenone tetracarboxylic dianhydride (BTDA) - were added in DOCDA-ODA monomer mixture, respectively. All the synthesized homo- and co-polyimides were characterized by FT-IR. Their thermal properties were analyzed with differential scanning calorimeter (DSC). Dense membranes were prepared from these copolyimides to check their gas permeation properties for $CO_2$ and $CH_4$ gases using a time-lag method. The permeation testing results are as follows; DOCDA/ODA homopolymer showed 1.71 barrer of $CO_2$ permeability and 74.35 of $CO_2/CH_4$ selectivity. The three polyimide copolymers (DOCDA/6FDA-ODA, DOCDA/BPDA-ODA, DOCDA/BTDA-ODA) showed lower $CO_2/CH_4$ selectivities and higher $CO_2$ permeabilities than the homopolymer (DOCDA-ODA). DOCDA/6FDA-ODA showed twice times higher $CO_2$ permeabilities without severe $CO_2/CH_4$ selectivity loss than the DOCDA-ODA.