The purpose of this work is to investigate the effect of premixing condition on the combustion and exhaust emission characteristics in a HCCI diesel engine. To form homogeneous charge before intake manifold, the premixed fuel is injected into premixed tank by GDI injection system and the premixed fuel is ignited by direct injected diesel fuel. But in the case of high intake air temperature, premixed fuel is auto-ignited before diesel combustion and soot emission is increased. In the case of light load condition, the BSFC is improved by intake air heating because increased air temperature promoted the combustion of premixed mixture. NOx and smoke concentration of exhaust emissions are reduced compared to conventional diesel engine. The combustion characteristics of the HCCI diesel engine such as combustion pressure, rate of heat release, and exhaust emission characteristics are discussed.

As the environmental pollution becomes serious global problem, the regulation of emission exhausted from automobiles is strengthen. Therefore, it is very important to know how to reduce the NOx and PM simultaneously in diesel engines, which has lot of merits such as high thermal efficiency, low fuel consumption and durability. By this reason, the new concept called as Homogeneous Charge Compression Ignition(HCCI) engines are spotlighted because this concept reduced NOx and P.M. simultaneously. However, it is well known that HCCI engines increased HC and CO. Thus, the investigation of combustion characteristics which consists cool and hot flames for HCCI engines were needed to obtain the optimal combustion condition. In this study, combustion characteristics for direct inject type HCCI engine such as quantity of cool flame and hot flame, ignition timing and ignition delay were investigated to clarify the effects of these parameters on performance. The results revealed that diesel combustion showed the two-stage ignition of cool flame and hot flame, the rate of cool flame increase and hot flame decrease with increasing intake air temperature. On the other hand, the gasoline combustion is the single-stage ignition and ignition timing is near the TDC. In addition mixed fuel combustion showed different phenomenon, which depends on the ratio of gasoline component. Ignition timing of mixed fuel is retarded near the TDC and the ignition delay is increased according to ratio of gasoline.

Diesel particulate trap is a core technology for the reduction of PM from diesel vehicles This study presents the features and the characteristics of DPF system when using pellet type filters. In comparison with wall-flow filter, the pellet filter has the advantages of cracking free during regeneration and shape flexibility. Experiments are conducted in a test bench simulated as diesel engine exhaust condition. Pressure drop and particle loading rate was compared by using two pellet filters having the porosity of 70% and 0%. Also its regeneration was tested.

Diesel-Fueled HCCI(Homogeneous Charge Compression Ignition) Engine is an advanced combustion process explained as a premixed charge of diesel fuel and air is admitted into the cylinder and compression ignited. It has possibility to reduce NOx by spontaneous auto-ignition at multiple points that allows very lean combustion resulting in low combustion temperatures. Also PM could be reduced by the premixed combustion and no fuel-rich zones. But HCCI couldn't be realized because of the difficulties in vaporizing the diesel, control of combustion phase directly. To solve these problems, new fuel injection strategy, explained as the pilot fuel injection to promote ignition near TDC following the main fuel injection at the extremely advanced timing, is applied during the compression ratio is varied from 18.9:1 to 27.7:1 This is not a pilot fuel to promote the ignition but also the direct control method of the combustion phase. Experimental result shows the pilot fuel injection promote the ignition and the compression ignition of the HCCI engine is achieved as compression ratio becomes higher. Also there is an optimal pilot fuel injection timing for the HCCI combustion. NOx is reduced more than 90% compared to DI-Diesel case but PM and THC emission needs more investigation.

A numerical study is carried out to investigate combustion phenomena in a model SCRamjet engine, which has been experimentally studied at the Australian National University using a T3 free-piston shock tunnel. The Mach number is 3.8, the static pressure 110kPa and the static temperature 1100K in the main air flow. The fuel is hydrogen, which is injected in the cavity. Equivalence ratio is set to either 0.25 or 0.5 to access its effect on the fuel-air mixing combustion phenomena. The results show that the cavity generates several recirculation zones, which increase the fuel-air mixing. Self ignition occurs near the point of fuel injection. The flame is anchored by the cavity and generates the precombustion shock on the step. For a high equivalence ratio, the recirculation zones are bigger and the flame is present throughout the combustor.

Numerical analysis was carried out to investigate performance and combustion characteristics of KSR-III liquid rocket engine with several types of baffle. To evaluate the change of performance and combustion characteristics with several types of baffle, the first numerical calculations were performed about baffle tab, radial blade baffle, and hub-and-spoke baffle. Then radial blade and hub-and-spoke baffle were determined to design two types of the KSR-III engine with baffles. Also to investigate the effect of injector arrangements and baffle positions, two types of radial blade baffle were calculated then numerical calculations were carried out with changing axial length of radial blade I, II and hub-and-spoke baffle. While axial length of baffle effected to performance very small, injector arrangement effected to performance largely through calculations of radial blade I, II. From the viewpoint of combustion instability, hub-and-spoke baffle controlled combustion instability effectively and there was the performance of hub-and-spoke baffle between radial blade I and II.

In this research, authors tried to measure the shape of the nozzle throat of KL-3 engines, which is the main engine of KSR-III rocket, to find the increase of nozzle area caused by the thermal ablation. For the purpose, we invented an image-based method instead of the 3D pointer, which is actually inaccessible to such large scale engines. As a result, our equipment showed satisfactory accuracy and performance. Analysing the results of experiments, we find that the pattern of ablation is determined by the spray pattern and that the process of thermal ablation phenomena can be categorized in three regimes - the first regime that the shape of nozzle throat is maintained and ablation is negligible, the second regime that saw-tooth form is developed and ablation is accelerated, and the third regime that the saw-tooth form is already established and the growth of ablation rate is reduced. Also, we find that the ratio of area increase after 60 seconds combustion is +5.82% and conclude that this figure is acceptable and satisfactory.

A general procedure of obtaining reliable one-step kinetics model for hydrocarbon mixture from the fully detailed chemistry is described iin this study. One-step theoretical formulation of the induction parameter model IPM uses a theoretical reconstruction of the induction time database obtained from a detailed kinetics library. Non-dimensional induction time calculations is compared with that of detailed kinetics. The IPM was latter implemented to fluid dynamics code and applied for the numerical simulation of detonation wave propagation. The numerical results including the numerical smoked-foil record show the all the details of the detonation wave propagation characteristics at the cost around 1/100 of the detailed kinetics calculation.

An experimental study on flame lift-off characteristics of propane jet flame highly diluted with nitrogen has been conducted introducing acoustic forcing with a tube resonant frequency. A flame stability curve is attained according to forcing strength and nozzle exit velocity for $N_2$ diluted flames. Flame lift-off behavior with forcing strength and nozzle exit velocity is globally categorized into three; a well premixed behavior caused by a collapsible mixing for large forcing strength, a coexistent behavior of well-premixed and edge flames interacting with well-organized inner fuel vortices for moderate forcing strengths, and edge flame behavior for small forcing strengths. Special focus is concentrated on the coexistent behavior of the flame base in lifted flame since this may give a hint to a possibility which the flame base behaves like a well-mixed premixed flame in highly turbulent lifted flames. It is also shown that the acoustic forcing to self-pulsating laminar lifted flame affects flame lift-off behavior considerably which is closely related to downstream flow velocity, mixture strength, effective fuel Lewis number, and flame stretch.

Diode laser absorption system is advantageous of their non-invasive nature, fast response time, high sensitivity and real-time measurement capability. Furthermore, recent advances in room-temperature, near-IR and visible diode laser sources for telecommunication, optical data storage applications are enabling combustion diagnostics system based on diode laser absorption spectroscopy. So, combined with fiber-optics and high sensitive detection strategies, compact and portable sensor system are now appearing for a variety of applications. The objective of this research is to take advantage of distributed feed-back diode laser and develope new gas sensing system. It experimentally found out that the wavelength, power characteristics as a function of injection current and temperature. In addition to direct absorption and wavelength modulation spectroscopy have been demonstrated in these experiments and have a bright prospect to this diode laser system.

The lift-off characteristics of the triple flame within a diverging duct have been studied experimentally using a multi-slot burner, which can control the concentration gradient and the mean velocity independently. In this experiment the triple flame was stabilized successfully in lift-off condition and flame stabilization with a duct or without a duct, lift-off heights, and some other characteristics were examined for propane flame. It was examined that the effects with various concentration gradient and mean velocity on the triple flame. It was found that minimum value of the lift-off heights exist at a certain concentration gradient for constant mean velocity and flame with a duct is more stable than that without. Moreover the propagation velocity of the flame becomes maximum at a certain concentration gradient regardless of mean velocity.

The extinction of unsteady diffusion flame was experimentally studied in an opposing jet counterflow burner using diluted methane. The stabilized flame was perturbed by linearly varying velocity change that was generated by pistons installed on both sides of the air and fuel stream. As the results, the extinction of unsteady flame is dependent not only on the history of unsteadiness, but also on the initial condition. We found that there are several unsteady effects on the flame extinction. First, the extinction strain rates of unsteady cases are extended well beyond steady state extinction limits. Second, as the slope of the strain rate change increases, the unsteady extinction strain rate becomes larger. Third, the extension of unsteady extinction strain rate becomes smaller as the initial strain rate increases. We also found that the extension of the extinction limit mainly results from the unsteady response of the reaction zone because there is no retardation effect of a mixing layer for our experimental condition.

The control of flame shapes in a laminar pre-mixed flame has been experimentally investigated for propane/air pre-mixed laminar flames. Flames of different size and shapes are observed with heated wires or by controlling the equivalence ratio and flow rate of a mixture. The characteristics of the partitioning of a flame or the merge of flames are analyzed and explained by considering the balance between laminar flame speed and upstream mixture velocity. A combustor might be sized down while maintaining its heat production rate the same by partitioning a flame established in it. When the equivalence ratio of mixture is decreased, individual flames are merged together and the upstream mixture velocity can be practically decreased on a nozzle having opening ratio less than unity. As a result, the flame shape is to he adjusted until the newly established balanced condition is satisfied, and then. the stable combustion can be achieved again.

The present study discusses about the combustion and thermal flow characteristics of a G+R type incinerator, which is under construction for MAPO Incineration system, to evaluate the effects of various operating and design parameters. A bed combustion model is developed to simulate the waste bed combustion on the stoker. The effects of waste composition and primary air distribution are estimated. The results of the waste bed combustion model is applied to CFD(computational fluid dynamics) simulation, which simulates the detail of the thermal flow in the combustion chamber. The effects of bypass damper opening ratio, primary air distribution, and secondary air jet configuration are discussed.

In this study we propose an unsteady I-dimensional model of bed combustion with multiple solid phases, which confers a phase on each solid material. This model can be applied to a variety of bed combustion cases of various configurations and ignition methods. It contains fuel combustion, gaseous reaction, heat transfers between each phase, and geometric changes of the solid particles. An iron ore sintering pot is selected for verifying the model validity and simulation results are compared with the limited experimental data set of various coke contents and air supply rates. They predict the experimental results well and show applicabilities to the various system of the fuel bed with various solid materials.

Numerical study with momentum-balanced boundary conditions has been conducted to grasp chemical effects of added $CO_{2}$ and $H_{2}O$ to fuel- and oxidizer-sides on flame structure and NO emission behavior in $CH_{4}$/Air counterflow diffusion flames. The dilution with $H_{2}O$ results in significantly higher flame temperatures and NO emission, but dilution with $CO_{2}$ has much more chemical effects than that with $H_{2}O$. Maximum reaction rate of principal chain branching reaction due to chemical effects decreases with added $CO_{2}$. but increases with added $H_{2}O$. The NO emission behavior is closely related to the production rate of OH, CH and N. The OH radical production rate increases with added $H_{2}O$ but those of CH, N decrease. On the other hand the production rates of OR CH and N decrease with added $CO_{2}$. It is found that NO emission behavior is considerably affected by chemical effects of added $CO_{2}$ and $H_{2}O$.

In order to investigate the effect of fuel mixing on PAH and soot formation, four species of methane, ethane, propane and propene have been mixed in counterlfow ethylene diffusion flame. Laser-induced incandescene and laser-induced fluorescene techniques were employed to measure soot volume fraction and polycyclic aromatic hydrocarbon (PAH) concentration, respectively. Results showed that the mixing of ethane (or propane) in ethylene diffusion flame produces more PAHs and soot than those of propene, even though the propene diffusion flame produces more PAHs and soot than that of propane and ethane. Considering that propene directly dehydrogenates to propargyl radical, this behavior implied that the enhancement of PAH and soot formation by the fuel mixing of ethylene and ethane (or propane) cannot be explained by propargyl radical directly dehydrogenated from ethane (or propane).

The synthesis gas generated in waste pyrolysis melting process which consists of pyrolysis of waste and melting process of ash is known to be an alternative fuel. Since the compositopn of synthesis gas is much different from other synthesis gases, the fundamental combustion characteristics are analyzed in this study. The radiation heat heat flux is used to estimate the heat flux from flames made by many combinations of fuel and oxidant supply. The results show that the synthesis gas needs much more amount of oxidant for equivalent heat flux to methane flame and the inverse diffusion flame type for synthesis gas burner is suitable for better radiation heat transfer.

Catalytic Combustion used to be applied to specific conditions because of the characteristics different from flame combustion. However, many researches are focused on widening the applicant range of catalytic combustion with the competences of catalytic combustion. The development of many catalytic combustion appliances is one of the trials to overcome the restrictions of reaction and maximize the merits. In this research, past developments of appliances are depicted and new conceptual system will be introduced - sequential system. Sequential catalytic combustion system is composed of units - existing catalytic heat exchangers. This system is performed with parallel in composition and serially in operation. First, the burden of the preheating can be dramatically reduced. Second, stable operation control is expected. Lastly, Capacity expansion is flexible.

Self-excited noise generation from laminar flames in thin annular jets of methane/air premixture has been investigated experimentally. Various flames were observed in this flow configuration, including conical shape flames, ring shape flames, steady crown shape flames, and oscillating crown shape flames. Self-excited noise with the total sound pressure level of about 70dB was generated from the oscillating crown shape flames for the equivalence ratio larger than 0.95. Sound pressure and $CH^{\ast}$ chemiluminescence were measured by using a microphone and a photomultiplier tube. The frequency of generated noise was measured as functions of equivalence ratio and premixture velocity. A frequency doubling phenomena have also been observed. The measured $CH^{\ast}$ chemiluminescence data were analyzed from which the corresponding sound pressure has been calculated. By comparing the data with those of measured ones, the noise source can be attributed to the flame front fluctuation near the edge of the oscillating crown-shape flames. The flame stability regime was influenced sensitively to the supplying air through the inner tube.

Acoustic characteristics of baffled combustion chamber to elucidate suppressing effect of baffle on combustion instability are numerically investigated by linear acoustic analysis. A hub-blade baffle of 5 blades is selected as a candidate one and five variants of baffles with various configuration are designed. Resonant-frequency shift and damping factor are analyzed quantitatively as damping parameters. When the hub is located radially at the pressure node, the decrease of resonant frequency and increase of damping factor in 1R mode are dominant. But sub-1T mode is formed within hub, therefore, there would be a possibility of initiating 1T mode in unbaffled region, which would occur another problem. For smaller hub size, four kinds of axial baffle length is selected. As the axial baffle length increases, resonant frequency shift and increase of damping factor of transverse acoustic modes is obtained. Especially, two close acoustic modes such as 1L and 1T could be overlapped for a certain axial length, resulting in extreme increase of damping factor. The present study based on linear acoustic analysis is expected to be a useful confirming tool to predict acoustic field and design a passive control devices such as baffle and acoustic cavity.

An experimental study is conducted to investigate the effects of fuel temperature on the spray characteristics of a dual-orifice type swirl injector which is used in gas turbines. The major parameters affecting spray characteristics are fuel temperature and injection pressure entering into the injector. Fuel temperature is shown to have strong influence on the spray characteristics especially at a lower temperature. In this study, fuel temperature is varied from $30^{\circ}C$ to $120^{\circ}C$ and injection pressure is altered from 3 to $7 kg_{f}$ /$cm^{2}$. Two kinds of fuel, which have different surface tension and viscosity, are chosen as an atomizing fluid. As a result, injection instability occurs in the low temperature range due to icing phenomenon and the change of fuel properties. As the injection pressure increases, the kinematic viscosity range for stable atomization becomes wider. The factor controlling the SMD of spray is substantially different depending on the fuel temperature range.

The spray characteristics of dual orifice injector were investigated under two different fuels through measurement of SMD, number density and volume flux by using PDPA system. In this experiment, we found out that the droplet size and spray structure are strongly depend on fuel density and viscosity.

The present study is focused on the subgrid scale combustion model in context with a Large Eddy Simulation. In order to deal with detailed chemical kinetic, the level-set method based on a flamelet model is addressed. In this model, the flame front is treated as an interface, represented by an iso-surface of a scalar field G. This iso-surface is convected by the velocity field and its filtered quantities are include the turbulent burning velocity, which is to be modelled. For modelling the turbulent burning velocity, an equation for the length-scale of the sub-filter flame front fluctuations was developed. The formulations and issues for the turbulent premixed and partially premixed flames are addressed in detail.

The stoichiometric methan/air premixed turbulent flames at the axisymmetric Bunsen burner situation are numerically investigated. To account for the chemistry-turbulence interaction in the turbulent premixed flames, the steady laminar flamelet library method has been adopted. The flame front is tracked by using the Level-Set Approach. Turbulence is represented by the ${\kappa}-{\varepsilon}$ modeling with a Pope's correction. The detailed comparison between prediction and measurement has made for the flame field in terms of velocity, turbulent kinetic energy, and normarlized temperature.

Characteristic of turbulent nonpremixed interacting flames are investigated experimentally 8 or 9 nozzles are arranged in the shape of matrix or circle. When there is no center nozzle, flame is more stable than with center nozzle case. It is shown that these blowout limit enlargements are related with the recirculation of burnt gases. The interacting flame base was not located at the stoichiometric point. NO concentrations of interacting flame are smaller than that of single flame using same area nozzle.

The Saffman-Taylor instability mechanisms in laminar premixed flames in a Hele-Shaw cell are investigated using two-dimensional numerical simulations with Poiseuille assumption for the viscous effect. The baseline calculations considering the Darrieus-Landau and diffusive-thermal instability modes show the results consistent with the classical linear instability theory. With the Saffrnan-Taylor instability mechanism. the overall effect is to enhance the destabilizing mechanism by providing an increased viscous force in the product gas. The linear instability behavior is found to qualitatively similar to the Darrieus-Landau mechanism. However, the results in the nonlinear range demonstrate that there may exist distinct characteristic time scales associated with Darrieus-Landau and Saffman-Taylor mechanisms, such that the latter effect sustains longer in time, contributing to a higher overall flame speed.

Mild combustion or Flameless oxidation(FLOX) have been considered as one of the most prospective clean-combustion technologies to meet both the targets of high process efficiency and low pollutant emissions. A mild combustor with high air preheating and strong internal exhaust gas recirculation is characterized by relatively low flame temperature, low NOx emissions, no visible flame and no sound. In this study, the Steady Flamelet Approach has been applied to numerically analyze the combustion processes and NOx formation in the mild combustor. The detailed discussion has been made for the basic characteristics of mild combustor, numerical results and limitation of the present combustion modeling.

The method of flame hole dynamics is demonstrated as a mean to simulate turbulent flame extinction. The core of the flame hole dynamics involves derivation of a random walk mapping for the flame holes, created by local quenching, between the burning and quenched states provided that the dynamic characteristics of flame edges is known. Then, the random walk mapping is projected to a background turbulent field. The numerical simulations are carried out with the further simplifications of flame string and unconditioned scalar dissipation rate. The simulation results show how the chance of partial quenching is influenced by the crossover scalar dissipation rate. Finally, a list of improvements, necessary to achieve more realistic turbulent flame quenching simulation, are discussed.

In this study, the waste of landfill was treated using advanced enriched oxygen combustion system. The oxygen concentration of this study was 21%, 25%, 30% and 40% and the operating capacity was 200 g/min and the residence time was 10 minutes. As increased the oxygen concentration of combustion air. temperature of the incinerator was increased and the temperature was increased rapidly when the oxygen concentration was 30%. As increased the oxygen concentration, the NOx (ppm) of flue gas increase d for thermal NOx, however the CO (ppm) of flue gas decreased according to the increase of combustion efficiency . The optimum operation condition of incineration was obtained when the oxygen concentration is 30%${\sim}$40%. The unburned carbon of ash decreased from 10% to 4% when the oxygen concentration was increased from 21% to 30%, therefore the high combustion efficiency can be obtained if used the oxygen enriched combustion system.

Numerical simulations are performed at atmospheric pressure in order to understand the effect of additives on flame speed and the NOx formation in freely propagating $H_{2}/O_{2}/N_{2}$ flames with oxygen enrichments. A chemical kinetic mechanism is developed, which involves 26 gas-phase species and 99 reactions. Under several equivalence ratios and oxygen enrichments, flame speeds are calculated and compared with those obtained from the experiments, the results of which is in good agreement. As hydrogen chloride as additive is added into $H_{2}/O_{2}/N_{2}$ flames with low oxygen enrichments, its chemical effect causes the decrease of flame speed, radical concentration, and the NO production rate. It is found that the chemical effect of additive has much more influence on the reduction of EINO than its physical effect. However, in flames with very high flame temperature the physical effect rather than the chemical effect becomes more important on the reduction of EINO.

Burning velocities of conventional methane flame and oxygen-enriched methane flame were determined by experimentally and numerically at atmospheric pressure in order to examine the validity of various detailed reaction mechanisms in oxygen-enriched flame. The schlieren system was adopted to obtain the burning velocity of flame stabilized on a circular nozzle. Premix code was employed to compute the burning velocity. Three reaction mechnisms were tested at several oxygen enrichment level, whose names are GRI 3.0, MB(Miller and Bowman) and LKY(Lee Ki Yong) reaction mechanism. Sensitivity analysis was also performed to discriminate dominantly affecting reaction on burning velociy. The results showed that conventional reaction mechanisms originally based on methane-air flame were underpredict the burning velocity at high oxygen-enrichment level. The modified GRI 3.0 reaction mechanism based on our experimental results was suggested and shows a good agreement in estimating the burning velocity and the NO number density of oxygen-enriched flame.

Characteristics of methane jet diffusion flames using pure oxygen with recirculating $CO_{2}$ as an oxidizer were investigated experimentally. A coflow burner was considered, and the diameter of confinement was larger than that of the coflow. No stabilized flame could be observed over 75% of $CO_{2}$ volume percent. A comparison between air and $O_{2}/CO_{2}$ mixture was made in terms of liftoff velocity, flame liftoff height, and blowout conditions. As results, more stable flame could be observed with $O_{2}/CO_{2}$ mixture for the case of having similar flame temperature.

An experimental study has been conducted to evaluate the effects of $CO_{2}$ on heat transfer from hydrogen oxygen-enriched flame. Experiments were performed on flames stabilized by a co-flow swirl burner, which mounted on top of the furnace. Five composition conditions of oxidizer were chosen with replacing $N_{2}$ with $CO_{2}$. In a steady state, total and radiative heat flux rates from the flame to the wall of furnace has been measured using heat flux meters. Temperature distribution in furnace also has been checked. Increasing $CO_{2}$ ratio in the oxidizer, the dominant heat transfer mode was changed into convection from radiation. Temperature in the furnace decreased but total heat flux increased.

In Korea, the emission standards for air pollutants will be more tighten from Jan. 2005. Especially, the new emission standards is focused on the nitrogen oxide. From this trend of standards, nitrogen oxide emission is hot issue in energy fields. Also, we have a new environmental problem, the carbon dioxide emission, which are related to the global warming. To solve the environmental problems, we must define the situation of clean-up technologies level in Korea and decide the direction of R&D for flue gas cleaning technologies. Now, this paper discus briefly on the De-NOx R&D activities and the large scale testing facility for flue gas clean-up technologies in Korea Institute of Energy Research. These discussions are contribute to the increasing of the R&D activities for flue gas clean-up technologies in Korea.

Eco-Machinery engineering technologies in KIMM for reducing NOx emission were introduced. Combustion technologies such as reburning and fuel staged or air staged combustion have been applied to reduce NOx emission in the field of boiler furnaces. Lean premixed combustion method have been studied in gas turbine combustor. Hybrid system with plasma and SCR being considered as prospective method of De-NOx has been developed. Also, low NOx technologies including common rail system, EGR and DPF in diesel engine have been investigated.