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Crystal Structure of Fully Dehydrated Partially Cs+-Exchanged Zeolite X, Cs52Na40-X (The Highest Cs+-Exchanged Level Achieved by Conventional Method and Confirmation of Special Site Selectivity)

  • Bae, Myung-Nam
    • Bulletin of the Korean Chemical Society
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    • v.28 no.2
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    • pp.251-256
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    • 2007
  • The crystal structure of fully dehydrated partially Cs+-exchanged zeolite X, [Cs52Na40Si100Al92O384], a = 24.9765(10) A, has been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd3 at 21 °C. The crystal was prepared by flow method for 5 days using exchange solution in which mole ratio of CsOH and CsNO3 was 1 : 1 with total concentration of 0.05 M. The crystal was then dehydrated at 400 °C and 2 × 10-6 Torr for 2 days. The structure was refined to the final error indices, R1 = 0.051 and wR2 (based on F2) = 0.094 with 247 reflections for which Fo > 4σ (Fo). In this structure, about fifty-two Cs+ ions per unit cell are located at six different crystallographic sites with special selectivity; about one Cs+ ion is located at site I, at the centers of double oxygen-rings (D6Rs), two Cs+ ions are located at site I', and six Cs+ ions are found at site II'. This is contrary to common view that Cs+ ions cannot pass sodalite cavities nor D6Rs because six-ring entrances are too small. Ring-opening by the formation of ?OH groups and ring-flexing make Cs+ ions at sites I, I', and II' enter six-oxygen rings. The defects of zeolite frameworks also give enough mobility to Cs+ ions to enter sodalite cavities and D6Rs. Another six Cs+ ions are found at site II, thirty-six are located at site III, and one is located at site III' in the supercage, respectively. Forty Na+ ions per unit cell are located at two different crystallographic sites; about fourteen are located at site I, the centers of D6Rs and twenty-six are also located at site II in the supercage. Cs+ ions and Na+ ions at site II are recessed ca. 0.34(1) A and 1.91(1) A into the supercage, respectively. In this work, the highest exchange level of Cs+ ions per unit cell was achieved in zeolite X by conventional aqueous solution methods and it was also shown that Cs+ ion could pass through the sixoxygen rings.

Development of Automated 3D Modeling System to Construct BIM for Railway Bridge (철도 교량의 BIM 구축을 위한 3차원 모델 생성 자동화 시스템 개발)

  • Lee, Heon-Min;Kim, Hyun-Seung;Lee, Il-Soo
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.31 no.5
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    • pp.267-274
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    • 2018
  • For successful BIM settlement, it is a key technic for engineer to design structures in the 3-dimensional digital space and to work out related design documents directly. Lately many BIM tool has been released and each supports their 3-dimensional object libraries. But it is not easy to apply those libraries to design transportation infra structures that were placed along the route(3-dimensional line). Moreover, in case of design changes, it is so difficult to reflect those changes with the integrated model that was assembled by them. Because of they were developed without consideration for redundancy of parameters between objects that were placed nearby or were related each other. In this paper, a method to develop module for modeling and placing 3-dimensional object for transportation infra structures is presented. The modules are employed by a parametric method and can deal with design changes. Also, for a railroad bridge, through developing user interface of the integrated 3-dimensional model that was assembled by those modules the applicability of them was reviewed.

Developmental disability Diagnosis Assessment Systems Implementation using Multimedia Authorizing Tool (멀티미디어 저작도구를 이용한 발달장애 진단.평가 시스템 구현연구)

  • Byun, Sang-Hea;Lee, Jae-Hyun
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
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    • v.3 no.1
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    • pp.57-72
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    • 2008
  • Serve and do so that graft together specialists' view application field of computer and developmental disability diagnosis estimation data to construct developmental disability diagnosis estimation system in this Paper and constructed developmental disability diagnosis estimation system. Developmental disability diagnosis estimation must supply information of specification area that specialists are having continuously. Developmental disability diagnosis estimation specialist system need multimedia data processing that is specialized little more for developmental disability classification diagnosis and decision-making and is atomized for this. Characteristic of developmental disability diagnosis estimation system that study in this paper can supply quick feedback about result, and can reduce mistake on recording and calculation as well as can shorten examination's enforcement time, and background of training is efficient system fairly in terms of nonprofessional who is not many can use easily. But, as well as when multimedia information that is essential data of system construction for developmental disability diagnosis estimation is having various kinds attribute and a person must achieve description about all developmental disability diagnosis estimation informations, great amount of work done is accompanied, technology about equal data can become different according to management. Because of these problems, applied search technology of contents base (Content-based) that search connection information by contents of edit target data for developmental disability diagnosis estimation data processing multimedia data processing technical development. In the meantime, typical access way for conversation style data processing to support fast image search, after draw special quality of data by N-dimension vector, store to database regarding this as value of N dimension and used data structure of Tree techniques to use index structure that search relevant data based on this costs. But, these are not coincided correctly in purpose of developmental disability diagnosis estimation because is developed focusing in application field that use data of low dimension such as original space DataBase or geography information system. Therefore, studied save structure and index mechanism of new way that support fast search to search bulky good physician data.

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Development of Stand-Alone Risk Assessment Software for Optimized Maintenance Planning of Power Plant Facilities (발전설비 최적 정비를 위한 독립형 위험도 평가 소프트웨어 개발)

  • Choi, Woo Sung;Song, Gee Wook;Kim, Bum Shin;Chang, Sung Ho;Lee, Sang Min
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.11
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    • pp.1169-1174
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    • 2015
  • Risk-Risk-based inspection (RBI) has been developed in order to identify risky equipments that can cause major accidents or damages in large-scale plants. This assessment evaluates the equipment's risk, categorizes their priorities based on risk level, and then determines the urgency of their maintenance or allocates maintenance resources. An earlier version of the risk-based assessment software is already installed within the equipment management system; however, the assessment is based on examination by an inspector, and the results can be influenced by his subjective judgment, rather than assessment being based on failure probability. Moreover, the system is housed within a server, which limits the inspector's work space and time, and such a system can be used only on site. In this paper, the development of independent risk-based assessment software is introduced; this software calculates the failure probability by an analytical method, and analyzes the field inspection results, as well as inspection effectiveness. It can also operate on site, since it can be installed on an independent platform, and has the ability to generate an I/O function for the field inspection results regarding the period for an optimum maintenance cycle. This program will provide useful information not only to the field users who are participating in maintenance, but also to the engineers who need to decide whether to extend the lifecycle of the power machinery or replace only specific components.

Improvement of Microphone Away Performance in the Low Frequencies Using Modulation Technique (변조 기법을 이용한 마이크로폰 어레이의 저주파 대역 특성 개선)

  • Kim, Gi-Bak;Cho, Nam-Ik
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.42 no.4 s.304
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    • pp.111-118
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    • 2005
  • In this paper, we employ the modulation technique for improving the characteristics of beamformer in the low frequencies and thus improving the overall noise reduction performance. In the 1-dimensional uniform linear microphone arrays, we can suppress the narrowband noise component using the delay-and-sum beamforming. But, for the wideband noise signal, the delay-and-sum beamformer does not work well for the reduction of low frequency component because the inter-element spacing is usually set to avoid spatial aliasing at high frequencies. Hence, the beamwidth is not uniform with respect to each frequency and it is usually wider at the low frequencies. In order to obtain the beamwidth independent of frequencies, subarray systems[1][2][3][4] and multi-beamforming[5] have been proposed. However these algorithms need large space and more microphones since they are based on the theory that the size of the array is proportional to the wavelength of the input signal. In the proposed beamformer, we reduce the low frequency noise by using modulation technique that does not need additional sensors or non-uniform spacing. More Precisely, the array signals are split into subbands, and the low frequency components are shifted to high frequencies by modulation and reduced by the delay-and-sum beamforming techniques with small size microphone array. Experimental results show that the proposed technique Provides better performance than the conventional ones, especially in the low frequency band.

Synthesis of Single Crystalline Analcime and Its Single-crystal Structure, |Na0.94(H2O)|[Si2.06Al0.94O6]-ANA: Determination of Cation Sites, Water Positions, and Si/Al Ratios (결정성 아날심(|Na0.94(H2O)|[Si2.06Al0.94O6]-ANA)의 합성 및 단결정구조: 양이온 및 물 분자의 위치, Si/Al 비의 결정)

  • Seo, Sung-Man;Suh, Jeong-Min;Ko, Seong-Oon;Lim, Woo-Taik
    • Journal of the Korean Chemical Society
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    • v.55 no.4
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    • pp.570-574
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    • 2011
  • Large colorless single crystals of analcime with diameters up to 0.20 mm have been synthesized from gels with the composition of $3.00SiO_2$ : $1.50NaAlO_2$ : 8.02NaOH : $454H_2O$ : 5.00TEA. The fully $Na^+$-exchanged analcime have been prepared with aqueous 0.1 M NaCl (pH adjusted from 6 to 11 by dropwise addition of NaOH). The single-crystal structure of hydrated $|Na_{0.94}(H_2O)|[Si_{2.06}Al_{0.94}O_6]$-ANA per unit cell, a=13.703(3) ${\AA}$, has been determined by single-crystal X-ray diffraction technique in the orthorhombic space group Ibca at 294 K. The structure was refined using all intenties to the final error indices (using only the 1,446 reflections for which $F_o$ > $4{\sigma}(F_o))R_1/wR_2$ = 0.054/0.143. About 15 $Na^+$ ions are located at three nonequivalent positions and octahedrally coordinated. The chemical composition is $Na_{0.94}(H_2O)Si_{2.06}Al_{0.94}O_6$. The Si/Al ratio of synthetic analcime is 2.19 determined by the occupations of cations, 14.79, in the single-crystal determination work.

Modelling of Principal Stress Rotation in Ko Consolidated Clay (Ko-압밀점토지반속 주응력회전 현상의 모형화)

  • Hong, Won-Pyo;Kim, Tae-Hyeong;Lee, Jae-Ho
    • Geotechnical Engineering
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    • v.13 no.1
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    • pp.35-46
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    • 1997
  • The isotropic single-hardening constitutive model has been applied to predict the behavior of soils during reorientation of principal stresses in the field. The predicted response by the model agrees well with the measured behavior for a series of torsion shear tests performed on hollow cylinder specimens of Ko consoildated clay along various stress -paths. This indicates that the soil behavior during reorientation of principal stresses can be predicted by using the model with application of simple informations given by isotropic compression tests and conventional consolidated-undxained triaxial compression tests. Isotropic elasto-plastic soil behavior has been served during primary loading from both the torsion shear tests and the predictions by the model. However, the directions of maj or principal strain increment given by the model have not coincided with the directions for tests during stress reversal, such as unloading and reloading, within isotropic yield surface for Ko consolidated stress. This indicates that kinematic hardening model instead of isotropic hardening model should be developed to predict the soil behavior during stress reversal. The experimental strain increment vectors in the work-space have been compared with the directions expected for associated and nonassociated flow rules.

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A Study on Factors Related to the Practice of Breast-feeding (모유수유 실천과 관련 요인)

  • 박천만
    • Korean Journal of Health Education and Promotion
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    • v.19 no.2
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    • pp.23-43
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    • 2002
  • Purpose: The purpose of this study is to examine and analyse factors related to the actual status and practice of breast-feeding during an infant period to grasp elements detrimental to breast-feeding and, therefore, provide basic information useful for its effective practice and encouragement. Method: From April 1 to June 30, 2001, this study was carried out with the mothers of 337 who were 6 months old, as of the surveyed date, of infants born in 2002 and registered in Seongju-gun Public Health Center, Gyeongsangbug-do Province. The method for its survey included both of the visiting and telephone interviews, and questions were mainly about the mothers' general characteristics(3 questions), infants' general characteristics(3 questions), environmental characteristics of infant delivery( 4 questions), support to breast-feeding(4 questions), understanding of breast-feeding(5 questions), and feeding type during the 1 to 6-month period after birth. Result: 1. The feeding type during the I-month period after birth showed that the breast-feeding accounted for 42.4%, which was higher than dry milk-feeding(30%) or mixed milk-feeding(26.8%). However, it began to be lower than the dry milk-feeding from the 2-month period after birth. During the 6-month period, the breast-feeding accounted for 28.6% which was lower than 56.5% of the dry milk-feeding. 2. The mothers who were encouraged by their delivery clinic to and were educated to breast-feed infants accounted for 55.4% and 41.4%, respectively, which were relatively low. The understanding of breast-feeding indicated that the responses were positive from the view point of mother & infant health, but negative from mother's physical form. 3. It was shown that the lower the educational background of mother(p〈0.05) and the higher the unemployment of mother(p〈0.001), the higher the positive understanding of breast-feeding, and that the higher the entire support to breast-feeding, the more positive their understanding. 4. It was also shown that the lower the educational background of mother(p〈0.05), the higher the unemployment of mother(p〈0.001), the more the experience in breast-feeding at a delivery clinic(p〈0.01) and the faster the initial feeding(p〈0.001), the higher the rate of breast-feeding. 5. The factor having an effect on breast-feeding included a delivery clinic's encouragement to breast-feed(p〈0.001), understanding of breast-feeding(p〈0.01), father's comment on feeding method(p〈0.05) and mother's employment(p〈0.05). Discussion: In order to encourage the breast-feeding, as shown above, it is required, fist of all, to offer pregnant women an education about importance and excellence of breast-feeding and its appropriate method before delivery in advance to result in a positive comprehension of the breast-feeding. To do that, both the publicity activities and program development designed to encourage the breast-feeding must be performed in advance at the government level. In addition to that, the mother-infant space as ‘rooming-in’ available for breast-feeding immediately after delivery must be prepared on the basis of legal and administrative support. Finally, female employees' leave after childbirth must be performed for the purpose of productive welfare and circumstances also be prepared for breast-feeding, such as a children's home at work.

Comparison of User's Satisfaction between 4-bedroom and 5/6-bedroom in Single General Hospital (일개 종합병원 4인실과 5/6인실 사용자의 만족도 비교)

  • Lee, Chan Hee;Lim, Hyunsun;Yoon, Soojin;Park, Eun-Cheol;Kang, Jung-Gu
    • Korea Journal of Hospital Management
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    • v.21 no.2
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    • pp.13-23
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    • 2016
  • Purpose: The purpose of this study is to compare the user satisfaction between 4-bedrooms and 5/6-bedrooms in a single general hospital. Methodology: To measure and compare multiple-bed ward user satisfaction between 4-bedrooms and 5/6-bedrooms, questionnaires were collected from 916 inpatients and 129 nurses in a single general hospital. The patient satisfaction questionnaire categories included environmental conditions, protection of privacy, and medical services. The nurse satisfaction questionnaire categories included space, infection control, patient safety, work load and psychologic view point. Findings: Satisfaction of patient who admitted in 4-bedroom to the environmental conditions and protection of privacy was higher than that of 5/6-bedroom group (3.91 vs. 3.25, p<0.001). Satisfaction of nurse who worked in 4-bedroom was higher than that of 5/6-bedroom (3.05 vs. 1.92, p<0.001). By the multiple linear regression analysis, patient satisfaction to the environmental conditions and protection of privacy was related with multi-bedroom type and location of beds; 4-bedrooms were higher than 5/6-bedrooms(p<0.001), window side bed were higher than hallway side bed(p=0.001). There was no satisfaction difference in comparing medical services between the two groups. By the multiple linear mixed regression analysis, nurse satisfaction who were assigned for 4-bedrooms were higher than that of 5/6-bedrooms in all categories(p<0.001). Practical Implications: Even though no difference has shown in medical services satisfaction between the two patient groups, multi-bedroom type may affect patient satisfaction in environmental condition, protection of privacy and may also affect overall nurse satisfaction. This result suggests that to improve multi-bedroom user satisfaction, 4-bedroom is recommended over 5/6-bedroom.

A Study on the Living Conditions of Locals through the Management of Village Common Pastures and Pasturing Activities in Gotjawal located in the Mid-mountain Area of Jeju Island (제주도 중산간 곶자왈 지대의 마을공동목장 운영과 방목활동을 통한 생활상 연구)

  • Bu, Hye-Jin;Kang, Chang-Hwa;Jeong, Kwang-Joong
    • Journal of the Korean association of regional geographers
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    • v.22 no.2
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    • pp.353-368
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    • 2016
  • The importance of Gotjawal located in the mid-mountain area of Jeju Island has been emphasized in various aspects. This study aims to identify the value of Gotjawal as a life-cultural space. This will be illustrated by tracing the locals' previous pasturing activities and the management of village common pastures. Cheongsu Village Common Pasture and Jeoji Village Common Pasture in Cheongsu-Jeoji Gotjawal area, which are the study areas, have been actively used by local farmhouses since the establishment of the pastures in 1930's. In particular cattle were significant means for agriculture and transportation methods in 1960's and 1970's. The farmhouses were needed to breed cattle as one of the main economic means. Pasturing cattle on the village common pastures has developed a unique ranching culture. Furthermore, cooperative work of these farmhouses were performed. These include the establishment of ponds for water supply and the preparation of hay. Ranching facilities for pasturing were built on village common pastures and still remain in Gotjawal area. This has been used in the understanding of the locals' lives in the mid-mountain area of Jeju Island.

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