• Korean Chemical Engineering Research
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• 제54권4호
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• pp.568-573
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• 2016

본 연구에서는 고체 입자인 유리상 탄소입자와 액체인 수용액적을 이용한 접촉충전 비교 실험을 수행하여 액적 접촉충전 현상에 적용했던 완전도체 이론 적용의 적합성 및 고체 도체의 접촉충전 특성을 살펴보았다. 동일한 실험 장치내에서 비슷한 크기의 수용액적과 유리상 탄소입자를 이용해 가해준 전기장의 세기와 입자의 크기를 변화시키며 충전량을 측정하고 완전도체 이론과의 비교를 통해 충전 특성을 분석하였다. 유리상 탄소입자의 접촉충전 현상은 기본적으로 완전 도체 이론으로 설명이 가능하였으나 실제 충전되는 충전량은 이론치 대비 70~80% 수준으로 측정되었으며 이는 고체 입자가 전극과 접촉하여 전하가 전달되는 과정 중 전극과 오일 사이 오일 필름의 형성으로 주어진 짧은 시간 내에 충분한 전하의 전달이 이루어지지 못해 나타난 것으로 추정된다. 본 연구 결과는 고체 도체의 접촉충전 특성에 대한 이해를 높여 향후 이 분야에 중요한 기초 정보를 제공할 수 있을 것으로 기대된다.

• 한국물환경학회지
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• 제22권1호
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• pp.51-58
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• 2006

The effluent limitations for individual industry based on the best available technology economically achievable (BAT) have been required to achieve effective regulation. BAT assessment criteria that are suitable for the circumstances of Korean industry were developed in the previous study. The criteria were applied to determine the BAT for leather tanning and finishing industry. For the evaluation BAT, a subcategorization for the industry considering wastewater characteristics, source equipments, raw material and so on should be suggested. Three subcategories: A) Unharing, Chrome Tan, Retan-Wet Finish, B) Chrome Tan, Retan-Wet Finish, and C) Furskins were proposed in this study. Wastewater discharged from the each category contains high concentration of COD, chrome, nitrogen and sulfide. In particular, the concentration of nitrogen from the subcategory A is significantly greater. Twenty sites were surveyed and wastewater qualities were analyzed. Therefore, six different technologies were applied to the subcategory A for the end-of-pipe treatment technology, and a technology was used in the subcategory B and C, respectively. The technology candidates were evaluated in terms of environmental impacts, economically achievability, treatment performance and economical reasonability. As the result, the technology options for each subcategories: A) primary chemical precipitation + modified Ludzack-Ettinger process (MLE) + secondary chemical precipitation, B) chemical precipitation + typical activated-sludge process + Fenton oxidation, C) chemical precipitation + typical activated-sludge process + batch Fenton oxidation or batch activated carbon treatment were selected as the BAT, respectively.

• Korean Chemical Engineering Research
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• 제59권3호
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• pp.443-449
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• 2021

전분과 구연산의 에스테르화 반응을 통한 가교화로 내수성 및 도포성이 우수한 생분해성 비산 방지용 박막소재를 제조하고 특성을 분석하였다. 이들 소재의 박막 형성 및 물성을 향상하기 위하여 PVA과 글리세린 등을 첨가하여 도포된 박막의 유연성을 확보하였다. 또한 원재료 및 첨가재의 농도, 온도 및 반응 시간에 따른 물에 대한 팽윤도 및 용해도와 같이 재료 기능성을 최적화하는 조건을 분석하였다. FT-IR 분석으로 전분과 구연산의 가교 반응을 확인하였으며, 이들 반응과정에서 단일 및 다중 에스테르화 반응이 동시에 일어남을 알 수 있었다. 가교된 전분-구연산 박막재료는 토양매립 후 12주가 지났을 때 95%가량 분해되었어 생분해성이 우수함을 알 수 있다.

• Ocean and Polar Research
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• 제36권4호
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• pp.423-435
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• 2014

Verifying the similarity of environmental characteristics between an artificial impact site and a preserved or reference site is necessary to quantitatively and qualitatively evaluate the environmental impact of mining activity. Although an impact site (BIS station) and a preserved site (called KOMO station) that have been selected in the Korea manganese nodule contract area may share similar environmental characteristics, similarities in terms of the water column environment between both sites has not been investigated. In this study, we compared the chemical properties of the water columns and sinking particle fluxes between BIS and KOMO stations through two observations (August 2011 and September 2012). Additionally, we observed particle fluxes at the KOMO station for five years (July 2003~July 2008) to understand long-term natural variability. Vertical distributions of water column properties such as dissolved oxygen, inorganic nutrients (N, P, Si), total organic carbon below surface layer (within the depth range of 200 m) were not considerably different between the two sites. Especially, values of water column parameters in the abyssopelagic zone from 4000 m to bottom layer (~5000 m) were very similar between the BIS and KOMO sites. Sinking particle fluxes from the two sites also showed similar seasonality. However, natural variation of particle flux at the KOMO site varied from 3.5 to $129.9mg\;m^{-2}day^{-1}$, with a distinct temporal variation originating from ENSO events (almost forty times higher than a minimum value). These results could provide valuable information to more exactly evaluate the environmental impact of mining activity on water columns.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2009년도 하계학술발표대회 논문집
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• pp.1476-1483
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• 2009

In present work, experiments conducted to investigate the heat transfer characteristics and relationship between operating parameters and production of fresh water as output of the system. Plate Heat Exchanger (PHE) applied in vacuum evaporator for product fresh water that system intended to efficiently use low grade heat. PHE have become popular in chemical, power, food and refrigeration industries due to the efficient heat transfer performance, extremely compact design and flexibility of extend or modify to suit changed duty. The heat transfer part contains corrugated plates with 60 degree of chevron angle which verified by many researchers and commonly apply. Fresh water can be produced from saline water under near vacuum pressure by operating ejector. Consequently, evaporating temperature stay around $51-57^{\circ}C$ so it is possible to use any low grade heat source or renewable source. The maximum fresh water produced by freshwater generator with plat heat exchanger applied in the study was designed as 1.0 Ton/day.

• 한국물환경학회지
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• 제37권5호
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• pp.344-354
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• 2021

Optical methods such as UV and fluorescence spectrophotometers can be applied not only in the qualitative analysis of dissolved organic matter (DOM), but also in real-time quantitative DOM monitoring for wastewater and natural water. In this study, we measure the UV₂₅₄ and fluorescence excitation emission spectra for a sewage treatment plant influent and effluent, and river water before and after sewage effluent flows into the river to examine the composition and origin of DOM. In addition, a correlation analysis between quantified DOM characteristics and dissolved organic carbon (DOC) was conducted. Based on the fluorescence excitation emission spectra analysis, it was confirmed that the protein-type tryptophan-like DOM was the dominant substance in the influent, and that the organic matter exhibited relatively more humic properties after biological treatment. However, DOM in river water showed the fluorescence characteristics of terrestrial humic-like and algal tyrosine-like (protein-like) organic matter. In addition, a correlation analysis was conducted between the DOC and optical indices such as UV₂₅₄, the fluorescence intensity of protein-like and humic-like organic matter, then DOC prediction models were suggested for wastewater and river monitoring during non-rainfall and rainfall events. This study provides basic information that can improve the understanding of the contribution of DOC concentration by DOM components, and can be used for organic carbon concentration management in wastewater and natural water.

• 생태와환경
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• 제40권4호
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• pp.503-510
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• 2007

The purposes of the study were to analyze the seasonal effects on the fish fauna and compositions including trophic guilds and tolerance guilds. For the study, we collected fish samples twice in June as premonsoon period and early September 2007 as monsoon periods in five sampling sites of the Gap Stream, and then biological oxygen demand (BOD), nutrients (TN, TP) and suspended solids (SS) were compared with the guild data along the gradient of upstream-to-downstream. Chemical water quality, based on BOD, TP, and TN degraded gradually from the upstream to downstream reach and there were about 3 fold difference between S1 and S5. Water quality was worse in the premonsoon than the monsoon, and the heavy monsoon resulted in a dilution of the polluted river by rain water, especially, in the downstream reach. Total number of fish species, based on the catch per unit effort (CPUE), showed a distinct difference between the two seasons; 30 species were sampled in premonsoon, but 23 species were sampled in the monsoon, indicating a seasonal difference in the fish fauna. Tolerant species dominated the fish community (48.3%) in the stream, and the proportions prior to physical disturbance by the monsoon rain were evidently greater in the downstream reach than the upstream. This reflected the characteristics of urban stream polluted by nutrient enrichment as shown in the BOD and TP values. Sensitive species in the premonsoon decreased from the gradient of upstream-to-downstream reach. Such seasonal modifications in the trophic and tolerance guilds were evident. In the analysis of trophic guild and habitat guild, during the premonsoon the proportion of insectivore and riffle-benthic species were largely greater in the upstream reach than the downstream, whereas the proportions were opposite along the gradient of the stream in monsoon. Thus, the patterns of chemical water quality along the longitudinal gradients reflected the premonsoon conditions of insectivores and tolerant species, indicating that summer monsoon data of fish may not match with water quality due to large physical disturbance by flow regime. Seasonal monsoon in this region as well as the chemical pollution may act as a key role influencing the fish compositions of trophic and tolerance guilds and fauna. The data collected during the premonsoon rather than the monsoon, thus, may be better predictor for a diagnosis of stream health conditions.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표회 논문집(I)
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• pp.197-202
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• 1998

The corrosion of steel reinforcements in concrete is of much concern in recent years. The mechanism of corrosion, however, is not clear yet. This study is focused on the corrosion of steel induced by internal chlorides in concrete at early ages. To examine the critical concentration of steel, half-cell potential, chemical composition of expressed pore solutions of mortars and rate of corrosion area were observed with respect to additions of chlorides, types of binders, water-binders ratio.

• 환경위생공학
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• 제14권4호
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• pp.41-49
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• 1999

The water treatment by was performed to remove VOC and organic substances in the multi-stage ozone contactor. Ozone is mainly utilized to change the chemical structures of organic substance, of which finally has the purpose to degrad them. The removal efficiency of VOC has 20~60% at the ozone concentration of 3 ppm, in case of trichloroethylene, its efficiency is reduced by 85% at the ozone contact time of 8 min. Design factors such as the number of stage, ozone concentration, zone contact time are determined for optimal treatment in the multi-stage contactor.

• 한국화재소방학회:학술대회논문집
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• 한국화재소방학회 2005년도 공동추계학술논문발표회 논문집
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• pp.143-149
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• 2005