• Journal of Ceramic Processing Research
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• 제20권5호
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• pp.484-489
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• 2019

VO2 is an attractive candidate as a transition metal oxide switching material as a selection device for reduction of sneak-path current. We demonstrate deposition of nanoscale VO2 thin films via thermal atomic layer deposition (ALD) with H2O reactant. Using this method, we demonstrate VO2 thin films with high-quality characteristics, including crystallinity, reproducibility using X-ray diffraction, and X-ray photoelectron spectroscopy measurement. We also present a method that can increase uniformity and thin film quality by splitting the pulse cycle into two using scanning electron microscope measurement. We demonstrate an ON / OFF ratio of about 40, which is caused by metal insulator transition (MIT) of VO2 thin film. ALD-deposited VO2 films with high film uniformity can be applied to next-generation nonvolatile memory devices with high density due to their metal-insulator transition characteristic with high current density, fast switching speed, and high ON / OFF ratio.

• STI Policy Review
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• 제1권1호
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• pp.93-109
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• 2010

Over the last decade, some Korean enterprises have emerged to become global players in their specialized products. How have they achieved such tremendous technological progress in a short period of time? This paper explores that question by examining the characteristics of technological innovation activities at major Korean enterprises. The paper begins with a brief review of the stages of economic growth and science and technology development in Korea. Then, the existing literature, explaining the Korean innovation model, is analyzed in order to establish a new framework for the Korean innovation model. Specifically, Korean firms have experienced three sequential phases, and thus, the Korean model, at the firm level, can be coined as "path-following," "path-revealing," and "path-creating." Then, the stylized facts in the first phase (path-following) and the second phase (path-revealing) are discussed, in the context of empirical evidence from the areas of memory chips, automobiles, shipbuilding, and steel. In terms of technology development, the Korean model has evolved as "collective learning" in the first phase, "collective recombination" of existing knowledge and technology in the second phase, and is assumed as "collective creativity" in the third phase. Ultimately, all three can be classified as "collective creation". Korean firms now face a transition in the modes of technological innovation in order to efficiently implement the third phase. To achieve remarkable progress again, as they did in the past, and to sustain the growth momentum, Korean firms should challenge new dimensions such as creative technological ideas, distinctive technological capabilities, and unique innovation systems -- all of which connote 'uniqueness'. Finally, some lessons from the Korean technological innovation experience are addressed.

• ETRI Journal
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• 제38권4호
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• pp.714-723
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• 2016

Considerable attention has been given to processing graph data in recent years. An efficient method for computing the node proximity is one of the most challenging problems for many applications such as recommendation systems and social networks. Regarding large-scale, mutable datasets and user queries, top-k query processing has gained significant interest. This paper presents a novel method to find top-k answers in a node proximity search based on the well-known measure, Personalized PageRank (PPR). First, we introduce a distribution state transition graph (DSTG) to depict iterative steps for solving the PPR equation. Second, we propose a weight distribution model of a DSTG to capture the states of intermediate PPR scores and their distribution. Using a DSTG, we can selectively follow and compare multiple random paths with different lengths to find the most promising nodes. Moreover, we prove that the results of our method are equivalent to the PPR results. Comparative performance studies using two real datasets clearly show that our method is practical and accurate.

• Journal of Power Electronics
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• 제9권5호
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• pp.708-717
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• 2009

In this paper a new zero voltage transition PWM bridgeless PFC is introduced. The auxiliary circuit provides soft switching condition for all semiconductor devices. Also, in the resonant path of the auxiliary circuit, only two semiconductor devices exist. Therefore the resonant conduction losses are low. Furthermore, the auxiliary circuit semiconductor elements consist of only one diode and one switch. The proposed auxiliary circuit is applied to a bridgeless PFC converter to further reduce conduction and switching losses. In this paper, the operating modes of this converter are explained and the resulting ideal and simulation waveforms are shown. The presented experimental results justify the theoretical analysis.

• 한국연소학회지
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• 제7권2호
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• pp.24-33
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• 2002

The morphology of deposits on $15-{\mu}m$ thin SiC filaments has been investigated with SEM in a co-flowing, propane/air laminar diffusion flame. The average size of mature soot particles deposited in the luminous flame edge is strongly dependent on their axial position in a typical heavily sooting flame. The surface growth of liquid-phase PAHs molecules and the transition to soots from fully-developed precursors could be observed in the radial deposition of the flame. Two sooting regimes were found: one is the transition from the condensed-phase precursors; the other is the aggregation of smaller soot particles (or chains of them) to be carried along particle path lines. In the high temperature flame edge outside the soot luminous flame surface, the very thin fiber-like structures, which are about 10 nm thick, were found.

• Bulletin of the Korean Chemical Society
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• 제17권7호
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• pp.653-655
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• 1996

A comparative molecular field analysis (CoMFA) was carried out for the correlation of the transition state structures and the reaction rates for the SN2 reaction of 4-nitrophenyl benzoate and its sulfur analogs with anionic nucleophiles. The CoMFA analysis showed that both steric and electrostatic effects are important, and the steric contribution increased when nucleophiles are alkoxides or arylsulfides. In this study, we have demonstrated that the CoMFA analysis can be expanded beyond the scope of dealing with reactants and products. The reactant complex and transition state conformations generated along the reaction path can be more appropriately used for the correlation of structures and reaction rates.

• International Journal of Naval Architecture and Ocean Engineering
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• 제2권3호
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• pp.119-126
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• 2010

The response of ship roll oscillation under random ice impulsive loads modeled by Poisson arrival process is very important in studying the safety of ships navigation in cold regions. Under both external and parametric random excitations the evolution of the probability density function of roll motion is evaluated using the path integral (PI) approach. The PI method relies on the Chapman-Kolmogorov equation, which governs the response transition probability density functions at two close intervals of time. Once the response probability density function at an early close time is specified, its value at later close time can be evaluated. The PI method is first demonstrated via simple dynamical models and then applied for ship roll dynamics under random impulsive white noise excitation.

• 한국콘텐츠학회논문지
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• 제17권6호
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• pp.514-526
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• 2017

본 연구는 두 여성이 상담자가 되기까지의 진로전환 과정의 경험을 살펴봄으로써 상담자가 되어 가는 진로전환의 경험과 의미를 질적 연구방법의 하나인 내러티브 탐구방법을 통하여 살펴보았다. 이를 위해 상담심리사 자격증을 소지하고, 두 번 이상의 진로전환 경험이 있는 상담심리사 2명을 연구 참여자로 선정하였고, 결과는 다음과 같다. 첫째, 이들은 자신의 흥미나 적성을 생각해볼 기회를 갖지 못한 채 여러 번의 진로경험을 하였다. 둘째, 진로전환이 자신만의 방법으로 적응하는 경험이었다. 셋째, 여러 직업을 거치면서 점차 자신이 원하던 일과 공부를 찾아가게 되었다. 넷째, 자신이 선택한 상담자의 직업에 만족하고, 상담자로서 자신을 통찰해 가고 있었다. 본 연구를 통해 진로전환을 삶의 일부분인 과정으로 받아들이고, 상담 전문가의 길을 걷고 있는 상담자로의 진로전환 경험의 의미를 확인하였다는데 의의가 있다.

• 한국경영과학회지
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• 제33권3호
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• pp.43-58
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• 2008

In this paper, we have presented a dynamic, predictive location update scheme that takes into account each user's mobility patterns. A user's past movement history is used to create two-dimensional transition probability matrix which makes use of two directional consecutive location areas. A mobile terminal utilizes the transition probability to develop a predictive path which consists of several predictive nodes and then the location update is saved as long as a mobile user follows the predictive path. Using continuous-time Markov chain, cost functions of location update and paging are derived and it is shown that the number of predictive nodes can be determined optimally. To evaluate the proposed scheme, simulations are designed and the numerical analysis is carried out. The numerical analysis features user's mobility patterns and regularity, call arrival rates, and cost ratio of location update to paging. Results show that the proposed scheme gives lower total location management cost, compared to the other location update schemes.

• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2343-2353
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• 2007

We report the application of time-dependent density functional theory (TDDFT) to the calculation of potential energy profile relevant to the excited state intramolecular proton transfer (ESIPT) processes in title molecules. The TDDFT single point energy calculations along the reaction path have been performed using the CIS optimized structure in the excited state. In addition to the Stokes shifts, the transition energies including absorption, fluorescence, and 0-0 transition are estimated from the TDDFT potential energy profiles along the proton transfer coordinate. The excited state TDDFT potential energy profile of SA and 3ASA resulted in very flat function of the OH distance in the range ROH = 1.0-1.6 A, in contrast to the relatively deep single minimum function in the ground state. Furthermore, we obtained very shallow double minima in the excited state potential energy profile of SA and 3ASA in contrast to the single minimum observed in the previous work. The change of potential energy profile along the reaction path induced by the substitution of electron donating groups (-NH2 and -OCH3) at different sites has been investigated. Substitution at para position with respect to the phenolic OH group showed strong suppression of excited state proton dislocation compared with unsubstitued SA, while substitution at ortho position hardly affected the shape of the ESIPT curve. The TDDFT results are discussed in comparison with those of CASPT2 method.