• 한국전기전자재료학회논문지
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• 제36권1호
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• pp.29-35
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• 2023

Herein we investigated the effect of the conductive agent on the electrochemical performance of the SiOx anode. SiOx anodes have a relatively low volume expansion (~160%) compared to Pure-silicon, but have a problem in that they have a poor electrical conductivity characteristic. In this study, physical and electrochemical measurements were performed using two 0-dimensional amorphous carbon conductive agents with different crystallinity and surface area. The crystal structure of the conductive agents and the local graphitization degree were analyzed through XRD and Raman, and the surface area of the particles was observed through BET. In addition, the electrical performance according to the graphitization degree of the conductive agents was confirmed through a 4-point probe. As a result of the electrochemical cycle and rate performance, it was confirmed that the performance of SiOx using a conductive agent having a low graphitization degree and a high surface area was improved. The results in this study suggest that the graphitization degree and surface area of the amorphous carbon conductive agent may play an important role in the SiOx electrode.

• 한국연소학회:학술대회논문집
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• 한국연소학회 1998년도 제17회 KOSCI SYMPOSIUM 논문집
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• pp.139-154
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• 1998

Under certain circumstance, premixed turbulent flame can be treated as wrinkled thin laminar flame and its motion in a hydrodynamic flow field has been investigated by employing G-equation. Past studies on G-equation successfully described certain aspects of laminar flame propagation such as effects of stretch on flame speed. In those studies, flames were regarded as a passive interface that does not influence the flow field. The experimental evidences, however, indicate that flow field can be significantly modified by the propagation of flames through the volume expansion of burned gas. In the present study, a new method to be used with G -equation is described to include the effect of volume expansion in the flame dynamics. The effect of volume expansion on the flow field is approximated by Biot-Savart law. The newly developed model is validated by comparison with existing analytical solutions of G -equation to predict flames propagating in hydrodynamic flow field without volume expansion. To further investigate the influence of volume expansion, present method was applied to initially wrinkled or planar flame propagating in an imposed velocity field and the average flame speed was evaluated from the ratio of flame surface area and projected area of unburned stream channel. It was observed that the initial wrinkling of flame cannot sustain itself without velocity disturbance and wrinkled structure decays into planar flame as the flame propagates. The rate of decay of the structure increased with volume expansion. The asymptotic change in the average burning speed occurs only with disturbed velocity field. Because volume expansion acts directly on the velocity field, the average burning speed is affected at all time when its effect is included. With relatively small temperature ratio of 3, the average flame speed increased 10%. The combined effect of volume expansion and flame stretch is also considered and the result implied that the effect of stretch is independent of volume release.

• 대한원격탐사학회지
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• 제37권4호
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• pp.665-685
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• 2021

This study focused on the a 20-year evaluation of the dynamism of critical thermal anomalies in Busan metropolitan area prompted by unusual infrastructural development and demographic growth rate. Archived Landsat thermal data derived-LST was the major input for UTFVI and hot spot analysis (Getis-Ord Gi^*). Results revealed that the surface urban heat island-affected area has gradually expanded overtime from 23.32% to 32.36%; while the critical positive thermal anomalies (level-3 hotspots) have also spatially increased from 19.88% in 2000 to 23.56% in 2020, recording a net LST difference of > 5℃ between the maximum level-3 hotspot and minimum level-3 coldspot each year. It is been observed that thermal conditions of Busan have gradually deteriorated with time, which is potentially inherent in the rate of urban expansion. Thus, this work serves as an eye-opener to powers that be, to think and act constructively towards a sustainable thermal conform for city dwellers.

• 대한가정학회지
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• 제19권3호
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• pp.21-32
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• 1981

Clothing must have the individual beauty and the function that one can do one's body movement freely. therefore, from the human engineering view point, the exact measurement of the human body and the analysis of it's results must be applied to clothing because the arm works most. In this study, the skin surface of arm was investigated by shell made of Alginate of each movement. And by sometic method the rate of expansion and contraction of each section, inter-relation among the bust girth, axillary arm girth and scye girth and between the shoulder length right and the under axilla waist length were calculate4d. With these results, cap height, breadth of a sleeve and arm hole girth of existing sleeve pattern have been compared and analysed. The results are as follows; 1) According to the developmental figures of shell, the whole area change was small but that of shape was remarkable in M 4, 9, 13. The change of the Block 1 was particular. 2) Over arm length was contracted in all movements except M6 and under arm length expanded. The changes of sections a, b, c are large, while those of sections d, e are small. 3) In terms of latitudes, change of fore-arm region was small. The rate of scye girth varied from 14.3% of M13 to-5.6% of M2. The breadth of a sleeve expanded in all movements, and especially the front region expanded more than the back. 4) The relation between the shoulder length right and under axilla waist length, in all occasions, was contracted mutually, and one contracted, the other expanded. Therefore, in clothing construction when we consider the function of the arm it is better to widen the arm hole and the breadth of a sleeve at the same time than no widen the shoulder length by lowering the upper part of the upper side seam line.

• 한국초전도ㆍ저온공학회논문지
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• 제13권1호
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• pp.1-5
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• 2011

[ $CeO_2$ ]has been widely used for single buffer layer of coated conductor because of superior chemical and structural compatibility with $ReBa_2Cu_3O_{7-{\delta}}$(Re=Y, Nd, Sm, Gd, Dy, Ho, etc.). But, the surface of $CeO_2$ layer showed cracks because of the large difference in thermal expansion coefficient between metal substrate and deposited $CeO_2$ layer, when thickness of $CeO_2$ layer exceeds 100 nm on the biaxially textured Ni-3%W substrate. The deposition rate has been limited to be less than 6 $\AA$/sec in order to get a good epitaxy. In this research, we deposited $CeO_2$ single buffer layers on biaxially textured Ni-3%W substrate with 2-step process such as thin nucleation layer(>10 nm) with low deposition rate(3 $\AA$/sec) and thick homo epitaxial layer(>240 nm) with high deposition rate(30 $\AA$/sec). Effect of deposition temperature on degree of texture development was tested. Thick homo epitaxial $CeO_2$ layer with good texture without crack was obtained at $600^{\circ}C$, which has ${\Delta}{\phi}$ value of $6.2^{\circ}$, ${\Delta}{\omega}$ value of $4.3^{\circ}$ and average surface roughness(Ra) of 7.2 nm within $10{\mu}m{\times}10{\mu}m$ area. This result shows the possibility of preparing advanced Ni substrate with simplified architecture of single $CeO_2$ layer for low cost coated conductor.

• 자원리싸이클링
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• 제21권6호
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• pp.12-22
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• 2012

본 연구는 제강용도로 사용하기 위해 돌로마이트를 하소후 남은 2 mm 이하의 경소백운석 부산물을 건축용 바닥 몰탈의 기존 팽창재로서 활용 가능성을 검토하고자 하였다. 경소백운석은 $600{\sim}800^{\circ}C$ 정도에서 하소하였을 때 반응성이 높은 준결정상태의 활성 마그네시아로 존재하게 되며, 이 활성화된 마그네시아는 수화초기 Brucite gel을 형성하여 수화물 비율을 상대적으로 줄여 치밀한 조직을 형성하는 원인으로 작용하고, 수화후기에는 결정질의 Brucite가 형성되어 수축 현상을 억제하며 부피가 2배 이상 팽창하여 화학적 수축균열 방지 역할을 하게 되는 것이다. 실험결과 경소백운석은 기존 사용 중인 팽창재 대비 동일량 적용시 압축강도는 우수하게 확인되었으나, 반응성은 기존 팽창재(생석회+무수석고)에 비해 다소 낮게 측정되었다. 하지만 팽창재로서의 역할은 충분한 것으로 확인되었으며, 공사기간 단축 등 부가적인 효과를 나타내었다.

• 청정기술
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• 제10권4호
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• pp.177-187
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• 2004

드라이아이스 스노우 젯(dry ice snow jet)을 액체 이산화탄소의 고압팽창에 의해 만들고 운반기체에 의해 더욱 가속시킬 수 있었다. 코팅의 제거기구는 표면 오염입자의 그것과 크게 다르지 않았다. 코팅의 제거를 Hutchings 식으로 정량적으로 표현할 수 있었다. 이들 식에 의한 plot에서 얻은 두개의 매개변수로 코팅의 제거 속도와 단위 이산화탄소의 질량에 의해 제거된 비 코팅면적을 예측할 수 있었으며 아울러 실험데이터의 신뢰도와 실험 에러의 보정도 가능하게 되었다. 노즐 기판 거리와 노즐길이를 바꾸었을 때 얻어진 이들 plot이 한점에서 만날 수 있음을 알 수 있었으며 이점이 jet plume을 모음에서 얻어진 scar 반경의 증대효과와 jet를 확산시킴에서 얻어진 scar 반경 증대효과가 균형을 맞추는 데서 얻어진 것으로 판단된다.

• Journal of Electrochemical Science and Technology
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• 제13권1호
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• pp.112-119
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• 2022

Molten carbonate fuel cells (MCFCs) are environmentally friendly, large-capacity power generation devices operated at approximately 650℃. If MCFCs are to be commercialized by improving their competitiveness, their cell life should be increased by operating them at lower temperatures. However, a decrease in the operating temperature causes a reduction in the cell performance because of the reduction in the electrochemical reaction rate. The cell performance can be improved by introducing a coating on the cathode of the cell. A coating with a high surface area expands the triple phase boundaries (TPBs) where the gas and electrolyte meet on the electrode surface. And the expansion of TPBs enhances the oxygen reduction reaction of the cathode. Therefore, the cell performance can be improved by increasing the reaction area, which can be achieved by coating nanosized LiCoO₂ particles on the cathode. However, although a coating improves the cell performance, a thick coating makes gas difficult to diffuse into the pore of the coating and thus reduces the cell performance. In addition, LiCoO₂-coated cathode cell exhibits stable cell performance because the coating layer maintains a uniform thickness under MCFC operating conditions. Therefore, the performance and stability of MCFCs can be improved by applying a LiCoO₂ coating with an appropriate thickness on the cathode.

• 대한기계학회논문집B
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• 제24권4호
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• pp.589-598
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• 2000

A pilot-scale Spray Drying Sorber (SDS) system was set up to evaluate the effect of spray characteristics on the desulfurization yield. The size distribution and the Sauter Mean Diameters of slurry droplets were measured in advance using the optical size measurement system, Malvern 2600. The desulfurization yield of the drying chamber by size was measured for the conditions of inlet gas and spray injection. As a reagent, 10% limestone slurry of $Ca(OH)_2$ was treated with flue gas containing $SO_2$, and the combustion gas analyzer and gas detectors were attached to measure the $SO_2$ concentration. With a flow rate of 144 Nm3/h and a temperature range of $200{\sim}300^{\circ}C$, the experiments were performed for the Stoichiometric Ratio (SR) of 1.0 to 3.0 and droplet mean diameter of 6.5 to $34.3{\mu}m$. In case of smaller spray droplets, the desulfurization efficiency improved due to the increase of total droplet surface area, while the reduction in evaporation time reduced the contact time between the droplets and $SO_2$ gas. In some typical region of droplet diameter, this negative effect, reduction of contact time, became dominant and the desulfurization yield decreases the desulfurization yield in spite of the expansion in absorption area. These results revealed that there exists the optimal size of spray droplets for a given state, which is determined by the compromise between the total surface area of slurry droplets and the evaporation time of droplets. The measurements also indicated that the inlet temperature of flue gas changes the optimal injection condition by varying the driving force for evaporation. The results confirm that the effect of the evaporation time of slurry droplets should be considered in analyzing the desulfurization yield as well as the total surface area, for it is a significant aspect of the correlation with the capabilities of $SO_2$ absorption in wet droplets. In conclusion, the optimal condition of spray can be determined based on these results, which might be applied to design or scale-up of SDS system.

• 복식
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• 제56권7호
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• pp.33-45
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• 2006

This study was to provide the fundamental data for a scientific and rational clothing construction by investigating the length variation of the upper arm surface, using the method of surgical tape, and to understand the expansion and contraction of parts of body for the making of clothing adaptable to movement. The subjects were li early elementary schoolgirls in Busan area classified with three somatotypes, and arm-movements consisted of 6 types. The statistical analyses used in this study were mean, standard deviation and the ANOVA and LSD procedure. The results of the analysis of the length of the upper arm surface are as follows: By arm-movements, in the items of horizontal, upper arm length changed more in the front than in the back, and in the items of vertical, represented the opposite of horizontal items. In the items of upper arm, the anterior-posterior axilla length and under arm length were influenced by arm-movements, and the under length of the upper arm represented the maximum rate increase of 74.59%(3.20cm)$\sim$138.72%(4.28cm). In the somatotypes of early elementary schoolgirls, type II was more influenced by arm-movements, and for the making of clothing adaptable to movement, type III needed to reflect more surplus length(2cm) than the other types.