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A Study on Characterization of Expansion Agent in Mortar with Light Burned Dolomite By-Product

경소백운석(輕燒白雲石) 부산물(副産物)을 활용(活用)한 바닥 몰탈용 팽창재(膨脹材)의 특성검토(特性檢討)

  • Received : 2012.04.02
  • Accepted : 2012.10.10
  • Published : 2012.12.31

Abstract

This study investigated a utilization technology of light burned dolomite. light burned dolomite ($CaMg(CO_3)_2$) generated in furnace (steel manufacturer) is an alternative to quick lime. Using light burned dolomite has an effect on reducing the consumption of fluorite slag MgO concentration in supersaturated solution by prolonging the life of softening effect. Armophous MgO, not containing periclase is formed by firing dolomite under $800^{\circ}C$. It has larger surface area and higher reactivity than periclase, and also shows better expansion effect than quicklime. Due to those effects, therefore, armophous MgO produced from light burned dolomite is used as an alternative expansion agent in mortar. In the experiment, characteristics of light burned dolomite were compared to those of existing expansion agents such as anhydrite and quicklime. Then, each expansion and shrinkage rates were measured over a period of about 3 months in both of 1m Jis mold at labscale and apartment mortar flooring at field scale. In the result, it was observed that light burned dolomite in mortar flooring more compensates for the expansion and shrinkage rates than the existing expansion agents, showing low expansion rate of below 0.05% and also decreases the crack.

본 연구는 제강용도로 사용하기 위해 돌로마이트를 하소후 남은 2 mm 이하의 경소백운석 부산물을 건축용 바닥 몰탈의 기존 팽창재로서 활용 가능성을 검토하고자 하였다. 경소백운석은 $600{\sim}800^{\circ}C$ 정도에서 하소하였을 때 반응성이 높은 준결정상태의 활성 마그네시아로 존재하게 되며, 이 활성화된 마그네시아는 수화초기 Brucite gel을 형성하여 수화물 비율을 상대적으로 줄여 치밀한 조직을 형성하는 원인으로 작용하고, 수화후기에는 결정질의 Brucite가 형성되어 수축 현상을 억제하며 부피가 2배 이상 팽창하여 화학적 수축균열 방지 역할을 하게 되는 것이다. 실험결과 경소백운석은 기존 사용 중인 팽창재 대비 동일량 적용시 압축강도는 우수하게 확인되었으나, 반응성은 기존 팽창재(생석회+무수석고)에 비해 다소 낮게 측정되었다. 하지만 팽창재로서의 역할은 충분한 것으로 확인되었으며, 공사기간 단축 등 부가적인 효과를 나타내었다.

Keywords

Acknowledgement

Supported by : 지식경제부

References

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  1. Mineralogical and Physical Properties of Lime Plaster used in Wall Repair in Temple of Bagan, Myanmar vol.31, pp.4, 2018, https://doi.org/10.9727/jmsk.2018.31.4.267