• 한국재료학회지
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• 제27권5호
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• pp.281-288
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• 2017

In this study, Fe-Ni slag, converter slag and dephosphorization slag generated from the steel industry, and fly ash or bottom ash from a power plant, were mixed at an appropriate mixing ratio and melted in a melting furnace in a mass-production process for glass ceramics. Then, glass-ceramic products, having a basalt composition with $SiO_2$, $Al_2O_3$, CaO, MgO, and $Fe_2O_3$ components, were fabricated through casting and heat treatment process. Comparison was made of the samples before and after the modification of the process conditions. Glass-ceramic samples before and after the process modification were similar in chemical composition, but $Al_2O_3$ and $Na_2O$ contents were slightly higher in the samples before the modification. Before and after the process modification, it was confirmed that the sample had a melting temperature below $1250^{\circ}C$, and that pyroxene and diopside are the primary phases of the product. The crystallization temperature in the sample after modification was found to be higher than that in the sample before modification. The activation energy for crystallization was evaluated and found to be 467 kJ/mol for the sample before the process modification, and 337 kJ/mol for the sample after the process modification. The degree of crystallinity was evaluated and found to be 82 % before the process change and 87 % after the process change. Mechanical properties such as compressive strength and bending strength were evaluated and found to be excellent for the sample after process modification. In conclusion, the samples after the process modification were evaluated and found to have superior characteristics compared to those before the modification.

• 한국세라믹학회지
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• 제31권8호
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• pp.934-940
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• 1994

Fibers of ZrO2-SiO2 system were prepared from the hydrolysis and condensation of Si(OC2H5)4 and Zr(OnC3H7)4 with different H2O/alkoxide molar ratios. It was found that fibers could be drawn in the viscosity range of 1~100 poise from HCl catalyzed solutions with lower water contents of the mole ratio H2O/alkoxide, r 2. The fibrous gels were converted into the corresponding oxide glass fibers by heating at 80$0^{\circ}C$. Mechanical test was performed on E, A and 20ZrO2-80SiO2 glass fibers reinforced cement in order to investigate the flexural strength. The flexural strength value of 20ZrO2-80SiO2 glass fibers reinforced cement was greater than those of E and A. The chemical durability of the fibers in alkaline solutions increased with ZrO2 content. The weight loss due to the corrosion by 2N-NaOH solutions at $25^{\circ}C$ for 160 hours was about 0.31$\times$10-2 mg/dm2 for the 20ZrO2-80SiO2 glass fibers, which was superior to that of Vycor glass.

• 대한기계학회논문집
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• 제17권1호
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• pp.120-130
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• 1993

본 연구에서는 니켈의 가공시 나타나는 공구의 마멸에 대한 정량화 및 절삭변 수와의 연관성에 대한 연구는 그 자체가 마멸에 대한 데이터 베이스 측면에서 중요하 고, 이러한 접근방법으로는 연구가 거의 이루어지지 않았다는 측면에서도 큰 의미를 갖는다. 본 연구는 특히 경도가 큰 공구인 CBN, 소결 다이아몬드(poly crystal dia- mond 이하 PCD), 단결정 다이아몬드(single crystal diamond 이하 SCD)공구를 사용하 여 니켈의 절삭에서 나타나는 공구의 마멸에 대한 분석을 선행한 후 수집한 정보로부 터 절삭속도, 이송, 절삭깊이 및 공구의 nose반경이 공구의 마멸 및 표면의 성상(su- rface quality)에 미치는 영향에 대하여 고찰하였고 절삭조건의 변화에 따라 마멸에 대한 예상 곡선을 구하였다.

• 한국정밀공학회지
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• 제30권12호
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• pp.1237-1243
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• 2013

This study has focused on the effect of ultrasonic vibration table in ELID grinding process of aluminum nitride ceramics. Aluminum nitride ceramics has superior physical and chemical properties and widely used in IC, LSI substrate, package and so on. To achieve the high effective machining of brittle and high strength ceramics as like aluminum nitride, machining method combined ELID grinding and ultrasonic vibration has been adopted in this study. From the experimental results, material removal rate, MRR has been increased maximum 36 percent and spindle resistance has been decreased in using ultrasonic table. Surface roughness of ground surface became a little worse in using ultrasonic table but was somewhat improved in feed direction.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.630-630
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• 2013

Recently, atomically smooth hexagonal boron nitride(h-BN) known as a white graphene has drawn great attention since the discovery of graphene. h-BN is a III-V compound and has a honeycomb structure very similar to graphene with smaller lattice mismatch. Because of strong covalent sp2bonds like graphene, h-BN provides a high thermal conductivity and mechanical strength as well as chemical stability of h-BN superior to graphene. While graphene has a high electrical conductivity, h-BN has a highly dielectric property as an insulator with optical band gap up to 6eV. Similar to the graphene, h-BN can be applied to a variety of field, such as gate dielectric layers/substrate, ultraviolet emitter, transparent membrane, and protective coatings. However, up until recently, obtaining and controlling good quality monolayer h-BN layers have been too difficult and challenging. In this work, we investigate the controlled synthesis of h-BN layers according to the growth condition, time, temperature, and gas partial pressure. h-BN is obtained by using chemical vapor deposition on Cu foil with ammonia borane (BH3NH3) as a source for h-BN. Scanning Transmission Electron Microscopy (STEM, JEOL-JEM-ARM200F) is used for imaging and structural analysis of h-BN layer. Sample's surface morphology is characterized by Field emission scanning electron microscopy (SEM, JEOL JSM-7100F). h-BN is analyzed by Raman spectroscopy (HORIBA, ARAMIS) and its topographic variations by Atomic force microscopy (AFM, Park Systems XE-100).

• 폴리머
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• 제35권1호
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• pp.17-22
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• 2011

본 연구에서는 폴리프로팔렌(PP)/다중벽 탄소나노튜브(MWCNT) 복합체를 이축압출기를 사용하여 펠렛형 MWCNT를 20wt%까지 함량별로 제조하고, MWCNT가 20 wt% 첨가된 복합체를 마스터배치(M/B)로 사용하여 다시 PP와 컴파운딩하여 희석하였다. PP/MWCNT 복합체는 함량 변화에 따라 전기전도도 열전도도, 모폴로지, 열적, 고체 점탄성, 기계적 성질을 조사하였고, 또한 희석된 PP/MWCNT 복합체와 1 단계 PP/MWCNT 복합체 간의 물성을 비교하였다. 전기전도도와 열전도도는 MWCNT의 함량이 3 wt% 일 때 percolation threshold 현상을 보였고 M/B로 제조된 복합체가 더 우수한 전도도를 보였다. 복합체의 MWCNT 함량이 증가하면 비등온 결정화 온도 및 열분해 온도가 증가하였다. 모폴로지를 통하여 M/B로 제조된 복합체의 MWCNT 길이가 짧아진 것을 확인하였고, 이는 기계적 물성의 향상에 도움을 준 것으로 나타났다.

• 공업화학
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• 제27권3호
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• pp.259-264
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• 2016

본 연구에서는 norbonene dialkyl ester 6종을 isoprene rubber에 적용하여 내분비계 교란물질인 DEHP에 대한 대체 가능성을 평가하였다. IR 시편은 isoprene rubber (IR)와 norbonene dialkyl ester, 가황제 등을 배합하여 제작하였으며, 토크값, 스코치 시간, 최적가황시간, 무니점도를 측정하여 가공성을 평가하였고, 경도, 인장강도, 100% modulus, 신율 등물성을 평가하여 이를 DEHP를 적용한 경우와 비교하였다. 그 결과 토크 값의 경우 최저토크, 최대토크 모두 DEHP 보다 낮거나 유사한 값을 나타내었고, 스코치 시간, 최적가황시간은 DEHP보다 같거나 길게 측정되었다. 무니점도는 DEHN이 낮은 값을 나타내어 DEHP를 첨가한 경우보다 가공성이 우수함을 확인하였다. 경도와 열적 특성의 경우 norbornene계 화합물이 DEHP와 같거나 유사한 경향을 보였다. 인장특성의 경우 선형의 알킬기를 가진 norbornene계 화합물을 적용한 경우가 우수함을 확인하였다.

• 한국전기전자재료학회논문지
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• 제30권9호
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• pp.558-565
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• 2017

Hybrid insulators that have the advantages of both porcelain (high mechanical strength and chemical stability) as well as polymer (light weight and high resistance to pollution) insulators, can be used in place of individual porcelain and polymer insulators that are used for both mechanical support as well as electrical insulation of overhead power transmission lines. The most significant feature of hybrid insulators is the presence of porcelain/polymer interfaces where the porcelain and polymer are physically bonded. Individual porcelain and polymer insulators do not have such porcelain/polymer interfaces. Although the interface is expected to affect the mechanical/electrical properties of the hybrid insulator, systematic studies of the adhesion properties at the porcelain/polymer interface and the effect of the interface on the insulation characteristics and electric field distribution of the hybrid insulator have not been reported. In this study, we fabricated small hybrid insulator specimens with various types of interfaces and investigated the effect of the porcelain/polymer interface on the microstructure, insulating characteristics, and electric field distribution of the hybrid insulators. It was observed that the porcelain/polymer interface of the hybrid insulator does not have a significant effect on the insulating characteristics and electric field distribution, and the hybrid insulator can exhibit electrical insulating properties that are similar or superior to those of individual porcelain and polymer insulators.

• KEPCO Journal on Electric Power and Energy
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• 제2권2호
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• pp.285-291
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• 2016

In chemical-looping combustion, pure oxygen is transferred to fuel by solid particles called as oxygen carrier. Chemical-looping combustion process usually utilizes a circulating fluidized-bed process for fuel combustion and regeneration of the reduced oxygen carrier. The performance of an oxygen carrier varies with the active metal oxide and the raw support materials used. In this work, spraydried Mn-based oxygen carriers were prepared with different raw support materials and their physical properties and oxygen transfer performance were investigated to determine that the raw support materials used are suitable for spray-dried manganese oxide oxygen carrier. Oxygen carriers composed of 70 wt% $Mn_3O_4$ and 30 wt% support were produced using spray dryer. Two different types of $Al_2O_3$, ${\gamma}-Al_2O_3$ and ${\alpha}-Al_2O_3$, and $MgAl_2O_4$ were applied as starting raw support materials. The oxygen carrier prepared from ${\gamma}-Al_2O_3$ showed high mechanical strength stronger than commercial fluidization catalytic cracking catalyst at calcination temperatures below $1100^{\circ}C$, while the ones prepared from ${\alpha}-Al_2O_3$ and $MgAl_2O_4$ required higher calcination temperatures. Oxygen transfer capacity of the oxygen carrier prepared from ${\gamma}-Al_2O_3$ was less than 3 wt%. In comparison, oxygen carriers prepared from ${\alpha}-Al_2O_3$ and $MgAl_2O_4$ showed higher oxygen transfer capacity, around 3.4 and 4.4 wt%, respectively. Among the prepared Mn-based oxygen carriers, the one made from $MgAl_2O_4$ showed superior oxygen transfer performance in the chemical-looping combustion of $CH_4$, $H_2$, and CO. However, it required a high calcination temperature of $1400^{\circ}C$ to obtain strong mechnical strength. Therefore, further study to develop new support compositions is required to lower the calcination temperature without decline in the oxygen transfer performance.

• Journal of Welding and Joining
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• 제34권2호
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• pp.1-10
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• 2016

The use of materials for modern lightweight auto-bodies is becoming more complex than hitherto assemblies. The high strength materials nowadays frequently used for more specific fields such as the front and rear sub frames, seat belts and seats are mounted to the assembled body structure using bolt joints. It is desirable to use nuts attached to the assembled sheets by projection welding to decrease the number of loose parts which improves the quality. In this study, nut projection welding was carried out between a nut of both boron steel and carbon steel and ultra-high strength hot-stamped steel sheets. Then, the joints were characterized by optical and scanning electron microscope. The mechanical properties of the joints were evaluated by microhardness measurements and pullout tests. An indigenously designed sample fixture set-up was used for the pull-out tests to induce a tensile load in the weld. The fractography analysis revealed the dominant interfacial fracture between boron steel nut weld which is related to the shrinkage cavity and small size fusion zone. A non-interfacial fracture was observed in carbon steel nut weld, the lower hardness of HAZ caused the initiation of failure and allowed the pull-out failure which have higher in tensile strengths and superior weldability. Hence, the fracture load and failure mode characteristics can be considered as an indication of the weldability of materials in nut projection welding.