• Title/Summary/Keyword: supercritical water

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The heat transfer and pressure drop characteristics of $CO_2$ during supercritical region in a horizontal tube (초임계 영역에서 수평관내 $CO_2$ 열전달과 압력강하)

  • 이동건;오후규;김영률;손창효
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.3
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    • pp.500-508
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    • 2004
  • The heat transfer coefficients during gas cooling process of carbon dioxide in a horizontal tube were investigated. The experiments are conducted without oil in the refrigerant loop. The main components of the refrigerant loop are a receiver, a variable-speed pump, a mass flow meter, a pre-heater, and a gas cooler(test section). The water loop consists of a variable-speed pump, an isothermal tank, and a flow meter. The gas cooler is a counterflow heat exchanger by cooled water flowing in the annulus. The $CO_2$ flows in the horizontal stainless steel tube. which is 9.53mm in O.D. and 7.75mm in I.D. The gas cooler is 6 [m] in length. which is divided into 12 subsections, respectively. The experimental conditions considered in the study are following range of variables : refrigerant temperature is between 20 and $100^{\circ}C$. mass fluxes ranged from 200 to 400kg/($m^2$.s), average pressure varied from 7.5 to 10.0MPa. The main results were summarized as follows : The friction factors of $CO_2$ in the gas cooler show a relatively good agreement with those predicted by Blasius' correlation. The local heat transfer coefficient in the gas cooler has compared with most of correlations, which are the famous ones for forced convection heat transfer of turbulent flow. The results show that the local heat transfer coefficient of gas cooler agrees well with the correlation by Bringer-Smith except that at the region near pseudo critical temperature. while that at the near pseudo critical temperature is higher than the correlation.

Toward the multiscale nature of stress corrosion cracking

  • Liu, Xiaolong;Hwang, Woonggi;Park, Jaewoong;Van, Donghyun;Chang, Yunlong;Lee, Seung Hwan;Kim, Sung-Yup;Han, Sangsoo;Lee, Boyoung
    • Nuclear Engineering and Technology
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    • v.50 no.1
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    • pp.1-17
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    • 2018
  • This article reviews the multiscale nature of stress corrosion cracking (SCC) observed by high-resolution characterizations in austenite stainless steels and Ni-base superalloys in light water reactors (including boiling water reactors, pressurized water reactors, and supercritical water reactors) with related opinions. A new statistical summary and comparison of observed degradation phenomena at different length scales is included. The intrinsic causes of this multiscale nature of SCC are discussed based on existing evidence and related opinions, ranging from materials theory to practical processing technologies. Questions of interest are then discussed to improve bottom-up understanding of the intrinsic causes. Last, a multiscale modeling and simulation methodology is proposed as a promising interdisciplinary solution to understand the intrinsic causes of the multiscale nature of SCC in light water reactors, based on a review of related supporting application evidence.

Chemical Features of Solid Residues Obtained from Supercritical Water Treatment of Populus alba×glandulosa (현사시나무 목분의 초임계수 처리 공정으로부터 유래한 미분해 고형성분의 화학적 특성)

  • Kim, Kwang Ho;Eom, In Yong;Lee, Soo Min;Lee, Oh Kyu;Meier, D.;Choi, Joon-Weon
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.4
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    • pp.372-380
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    • 2009
  • After supercritical water treatment of poplar wood meals (passed through 60 mesh) for 60s between 325 and $425^{\circ}C$ at the fixed pressure at $220{\pm}10atm$, some solid residues were present in the degradation products. They mainly consisted of chemically modified lignin and fibrous materials. Glucose and xylose were identified as main sugar components of fibrous materials, and the highest ratio of glucose/xylose was achieved at the highest reaction temperature. As reaction temperature was elevated, the portion of fibrous materials decreased in the solid residues, while lignin was further accumulated. The H : G : S ratio of lignin in solid residues was estimated by analytical pyrolysis. Irrespective of reaction temperatures, the H:G:S ratios were not significantly changed in the lignin in solid residues. Compared to poplar milled wood lignin (MWL), it was remarkable that H type monomers were further lowered, while portion of S type monomers increased. The amount of G type monomers were relative stable. In presence of HCl catalyst, lowering H type as well as enhancing S type was further distinguishable. According to the result of nitrobenzene oxidation (NBO), ca. 265 mg of vanillin and syringaldehyde was yielded from poplar MWL as main products. However, remarkably reduced amount of NBO products were determined from solid residues by raising operating temperature as well as by the addition of HCl catalyst. These results strongly indicate that $\beta$-O-4 linkage could be easily cleaved during supercritical water treatment, so that the lignins in the solid residues seem to be condensed phenol polymers, which are mainly formed by carbon-carbon linkages rather than $\beta$-O-4 linkage.

Laboratory study of $CO_2$ migration in water-saturated anisotropic sandstone, based on P-wave velocity imaging (P-파 속도 영상화에 근거한 물로 포화된 이방성 사암에서의 $CO_2$ 이동에 관한 실험 연구)

  • Xue, Ziqiu;Lei, Xinglin
    • Geophysics and Geophysical Exploration
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    • v.9 no.1
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    • pp.10-18
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    • 2006
  • We measured the changes in P-wave velocity that occur when injecting $CO_2$ in gaseous, liquid, and supercritical phases into water-saturated anisotropic sandstones. P-wave velocities were measured in two cylindrical samples of Tako Sandstone, drilled along directions normal and parallel to the bedding plane, using a piezo-electric transducer array system. The velocity changes caused by $CO_2$ injection are typically -6% on average, with maximum values about -16% for the case of supercritical $CO_2$ injection. P-wave velocity tomograms obtained by the differential arrival-time method clearly show that $CO_2$ migration behaviour is more complex when $CO_2$ flows normal to the bedding plane than when it flows parallel to bedding. We also found that the differences in P-wave velocity images were associated both with the $CO_2$ phases and with heterogeneity of pore distribution in the rocks. Seismic images showed that the highest velocity reduction occurred for supercritical $CO_2$ injection, compared with gaseous or liquid $CO_$ injection. This result may justify the use of the seismic method for $CO_2$ monitoring in geological sequestration.

Anti-atopic Effect of Hot Water and Supercritical Carbon Dioxide Fluid Extract of Persimmon (Diospyros kaki) Peels (감껍질 열수 및 초임계 유체 추출물의 항아토피 효과)

  • Cho, Byoung Ok;Yin, Hong Hua;Fang, Chong Zhou;Shin, Jae Young;Ha, Hye Ok;Kim, Sang Jun;Jeong, Seung Il;Jang, Seon Il
    • Korean Journal of Food Science and Technology
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    • v.47 no.3
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    • pp.394-400
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    • 2015
  • This study aimed to investigate the anti-atopic effect of hot water (PPWE) and supercritical-carbon dioxide fluid extract of persimmon peels (SPPE) on atopic dermatitis (AD)-like skin lesions in hairless mice. Histological analyses demonstrated that SPPE treatment more strongly inhibited the dermal infiltration of inflammatory cells in AD-like skin lesions than that by PPWE. Compared to PPWE, SPPE significantly decreased the dermatitis clinical score and the epidermal thickness and potently suppressed serum IgE and interleukin (IL)-4 production in hairless mice with AD. Furthermore, compared to PPWE, SPPE potently inhibited the production of nitric oxide, prostaglandin $E_2$, and proinflammatory cytokines such as IL-6 and IL-$1{\beta}$ in lipopolysaccharide-stimulated RAW264.7 macrophages. These results suggested that SPPE exhibited anti-atopic dermatitis activity via the regulation of inflammatory responses.

Antioxidative Activity of Pine (Pinus densiflora) Needle Extracts in Rats Fed High-Cholesterol Diet (고콜레스테롤 식이 섭취 흰쥐에 대한 적송잎 추출물의 항산화 효과)

  • Kang, Sung-Rim;Shin, Mee-Ok;Kim, Sung-Gu;Lee, Sang-Hyeon;Kim, Mi-Hyang
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.38 no.4
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    • pp.423-429
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    • 2009
  • This study was conducted to investigate the effects of pine (Pinus densiflora) needle extracts on hepatic antioxidative system in rats fed high-cholesterol diet. Eight-week old Sprague Dawley rats were divided into four groups; normal diet group (CON), 0.5% cholesterol diet group (0.5% CHOL), 0.5% cholesterol diet and pine needle extracts prepared by using hot water group (HOT water), and 0.5% cholesterol diet and pine needle extracts prepared by using sub-supercritical $CO_2$ group (Sub-supercritical). The serum ALP, AST, and ALT activities were increased by 0.5% cholesterol diet supplementation, but treatment with pine needle extracts showed decrease compared with 0.5% CHOL group. The SOD activity in liver at 0.5% cholesterol diet group was more decreased than control group while Sub-supercritical group had significantly higher SOD activity than 0.5% CHOL group. Moreover, groups with pine needle extracts supplementation had higher level of GPx in liver than 0.5% cholesterol diet group. These results suggest that pine needle extracts increased antioxidative activities.

A Study on the Numerical Modeling for the Floodwave Analysis in a River -Huogi Dam-Break Floods (하천에서의 홍수파해석을 위한 수치모형의 개발-효기댐 파괴에 따른 홍수파 해석을 중심으로)

  • 한건연
    • Water for future
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    • v.20 no.4
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    • pp.285-294
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    • 1987
  • The floodwave analysis for unsteady supercritical flow is performed. The numerical model. based on dynamic wave equation is presented by introducing the general Preissmann scheme and fore-sweep algorithm.The model is applied to Buffalo-Creek floods for proving its validity, and the simulation results have good agreements with those computed by DAMBRK and the observed data. It is also applied to Hyogi dam-break. The outflow hydrograph is derived based on the observed data and the analysis for the floodwave propagation is investigated.

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Hydraulic Characteristics of Flows over a Weir (보 월류 흐름의 수리적 특성)

  • Choi, Seongwook;Choi, Sung-Uk
    • Proceedings of the Korea Water Resources Association Conference
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    • 2019.05a
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    • pp.95-95
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    • 2019
  • 보를 월류하는 흐름은 유량에 따라 상이한 흐름특성을 보인다. 즉, 유량이 증가함에 따라 사류 (supercritical flow), 완전도수 (complete hydraulic jump), 수중도수 (submerged hydraulic jump), 그리고 잠긴흐름 (plunge pool)으로 천이한다. 각 흐름영역에 따른 하상전단응력의 변화는 보의 물받이와 하상보호공을 설계하는데 중요하다. 본 연구에서는 계산유체동역학을 이용하여 보를 월류하는 흐름을 수치모의하여 각 흐름의 수리적 특성을 분석하였다. 이를 위하여 Flow3D를 이용하여 RANS 방정식을 수치해석 하였으며, 난류모형으로 RNG $k-{\epsilon}$ 모형을 이용하였다. 수치모의를 통하여 각각의 흐름에 대하여 평균유속, 하상전단응력, 그리고 흐름저항계수의 종방향 분포를 제시하였다.

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Micronization of water-soluble pharmaceuticals with a low-temperature Bubble Dryer

  • Seol , Eun-Young;Jung, Young-Hwan;Kim, Jung-In;Seo, Youn-Mi;Chung, Hye-Shin;Lee, Hee-Yong
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.236.3-237
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    • 2003
  • Fine particles of water-soluble pharmaceuticals were prepared using a new micronization method, Carbon Dioxide Assisted Nebulization in a Bubble Dryer(CAN-BD). The process utilized mixtures of CO$_2$ in aqueous solution at supercritical conditions to form an emulsion. The aerosols were dried with pre-heated nitrogen, and the drying chamber was operated at near atmospheric pressure. The dry particles were collected on membrane filter at the bottom of the drying chamber. Several processing parameters such as flow rate, temperature, pressure, solid concentration and processing scale were accessed using NaCl, human serum albumin, and granulocyte-colony stimulating factor as model pharmaceuticals. (omitted)

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Numerical Simulation of Convection-dominated Flow Using SU/PG Scheme (SU/PG 기법을 이용한 이송이 지배적인 흐름 수치모의)

  • Song, Chang Geun;Seo, Il Won
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.3B
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    • pp.175-183
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    • 2012
  • In this study, Galerkin scheme and SU/PG scheme of Petrov-Galerkin family were applied to the shallow water equations and a finite element model for shallow water flow was developed. Numerical simulations were conducted in several flumes with convection-dominated flow condition. Flow simulation of channel with slender structure in the water course revealed that Galerkin and SU/PG schemes showed similar results under very low Fr number and Re number condition. However, when the Fr number increased up to 1.58, Galerkin scheme did not converge while SU/PG scheme produced stable solutions after 5 iterations by Newton-Raphson method. For the transcritical flow simulation in diverging channel, the present model predicted the hydraulic jump accurately in terms of the jump location, the depth slope, and the flow depth after jump, and the numerical results showed good agreements with the hydraulic experiments carried out by Khalifa(1980). In the oblique hydraulic jump simulation, in which convection-dominated supercritical flow (Fr=2.74) evolves, Galerkin scheme blew up just after the first iteration of the initial time step. However, SU/PG scheme captured the boundary of oblique hydraulic jump accurately without numerical oscillation. The maximum errors quantified with exact solutions were less than 0.2% in water depth and velocity calculations, and thereby SU/PG scheme predicted the oblique hydraulic jump phenomena more accurately compared with the previous studies (Levin et al., 2006; Ricchiuto et al., 2007).