• Advances in nano research
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• 제13권2호
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• pp.187-197
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• 2022

The synthesis of organic and hybrid organic-inorganic perovskites directly from solution improves the cost- and energy-efficiency of processing. To date, numerous research efforts have been devoted to investigating the influence of the various solvent parameters for the synthesis of lead halide perovskites, focused on the effects of different single solvents on the efficiency of the resulting perovskites. In this work, we investigated the effect of solvent blends for the first time on the structure and phase of perovskites produced via the Lewis base vapor diffusion method to develop a new synthetic approach for water-stable CsPbBr₃ particles with nanometer-sized dimensions. Solvent blends prepared with DMF and water-miscible solvents with different Gutmann's donor numbers (D_N) affect the Pb ions differently, resulting in a variety of lead bromide species with various colors. The use of a DMF/isopropanol solvent mixture was found to induce the formation of the Ruddlesden-Popper perovskite based on lead bromide. This perovskite undergoes a blue color shift in the solvated state owing to the separation of nanoplatelets. In contrast, the replacement of isopropanol with DMSO, which has a high DN, induces the formation of spherical CsPbBr₃ perovskite nanoparticles that exhibit green emission. Finally, the integration of acetone in the solvent system leads to the formation of lead bromide complexes with a yellow-orange color and the perovskite CsPbBr₃.

• 통합자연과학논문집
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• 제15권1호
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• pp.9-18
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• 2022

This research examines the power of bootstrap two-sample test, and compares it with the powers of two-sample t-test and Wilcoxon rank sum test, through simulation. For simulation work, a positively skewed and heavy tailed distribution was selected as a population distribution, the chi-square distributions with three degrees of freedom, χ²₃. For two independent samples, the fist sample was selected from χ²₃. The second sample was selected independently from the same χ²₃ as the first sample, and calculated d+ax for each sampled value x, a randomly selected value from χ²₃. The d in d+ax has from 0 to 5 by 0.5 interval, and the a has from 1.0 to 1.5 by 0.1 interval. The powers of three methods were evaluated for the sample sizes 10,20,30,40,50. The null hypothesis was the two population medians being equal for Bootstrap two-sample test and Wilcoxon rank sum test, and the two population means being equal for the two-sample t-test. The powers were obtained using r program language; wilcox.test() in r base package for Wilcoxon rank sum test, t.test() in r base package for the two-sample t-test, boot.two.bca() in r wBoot pacakge for the bootstrap two-sample test. Simulation results show that the power of Wilcoxon rank sum test is the best for all 330 (n,a,d) combinations and the power of two-sample t-test comes next, and the power of bootstrap two-sample comes last. As the results, it can be recommended to use the classic inference methods if there are widely accepted and used methods, in terms of time, costs, sometimes power.

• Membrane and Water Treatment
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• 제2권3호
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• pp.187-205
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• 2011

The electric transport of the mixture of hydrochloric and phosphoric acids through strong base (Neosepta ACM) and weak base (Selemion AAV) anion-exchange membranes was investigated. The instantaneous efficiency of HCl removal from the cathode solution, $CE_{Cl}$, with and without $H_3PO_4$ was determined. It was found that $CE_{Cl}$ was 0.8-0.9 if the number of moles of elementary charge passed through the system, $n_F$, did not exceed ca. 80% of the initial number of HCl moles in the cathode solution, $n_{Cl,ca,0}$. The retention efficiency of $H_3PO_4$ in that range was close to one. The transport of acid mixtures was satisfactorily described by a model based on the extended Nernst-Planck and Donnan equations for $n_F$ not exceeding $n_{Cl,ca,0}$. Among the tested model parameters, most important were: concentration of fixed charges, the porosity-tortuosity coefficient, and the partition coefficient of an undissociated form of $H_3PO_4$. For the both membranes, the obtained optimal values of fixed charge concentration, $\bar{c}_m$, were up to 40% lower than the literature values of $\bar{c}_m$ obtained from the equilibrium measurements. Regarding the $H_3PO_4$ equilibria, it was sufficient to consider $H_3PO_4$ as a monoprotic acid.

• 대한전자공학회논문지SD
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• 제41권7호
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• pp.7-12
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• 2004

본 논문에서는 교류전류 집중현상이 고려된 바이폴라 등가모델에서 내부 베이스-컬렉터 캐패시턴스(C/sub μ/)와 외부 베이스-컬렉터 캐패시턴스(C/sub μx/)를 분리해서 추출하는 개선된 방법을 연구하였다. 먼저, 기존 추출방법들의 문제점들을 파악하고, 교류전류 집중 캐패시턴스가 포함된 차단모드 등가회로로부터 개선된 추출방정식들을 유도하였다. 이렇게 추출된 C/sub μx/와 C/sub μx/를 사용하여 모델 된 전류 및 전력이득 주파수 응답곡선들은 기존 추출방법으로 얻어진 곡선보다 측정 데이터와 훨씬 잘 일치되었으며, 이는 개선된 추출방법의 정확도를 증명한다.

• 공업화학
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• 제26권6호
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• pp.743-745
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• 2015

본 연구에서는 실온에서 간단히 염기의 양을 조절함으로서 세 가지 종류의 서로 다른 형태의 비결정질의 cobalt phosphate를 합성하였다. 합성된 샘플의 결정성과 형태를 X-Ray Diffraction (XRD)과, Scanning Electron Microscopy (SEM)를 통하여 확인하였으며, sodium borohydride의 수소발생 불균일 촉매로서 적용하였다. 촉매들 중에서 실온에서 합성한 비결정질의 cobalt phosphate 중에서 염기의 양이 가장 적은 10 nm 이하의 얇은 판상 형태의 촉매가 표면적이 넓어 가장 좋은 수소 발생 촉매활성을 보였다.

• 센서학회지
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• 제28권5호
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• pp.271-276
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• 2019

Pure and 0.5, 1, 2, 5, and 10 at% of Mo-doped $Co_3O_4$ yolk-shell spheres were synthesized by ultrasonic spray pyrolysis of droplets containing Co nitrate, ammonium molybdate, and sucrose and their gas sensing characteristics to 5 ppm trimethylamine (TMA), ethanol, p-xylene, toluene, ammonia, carbon monoxide, and benzene were measured at $225-325^{\circ}C$. The sensor using pure $Co_3O_4$ yolk-shell spheres showed the highest response to p-xylene and very low response to TMA at $250^{\circ}C$, while the doping of Mo into $Co_3O_4$ tended to increase the overall responses of gas sensors. In particular, the sensor using 5 at% Mo-doped $Co_3O_4$ yolk-shell spheres exhibited the high response to TMA with low cross-responses to other interfering gases. The high response and selectivity of Mo-doped $Co_3O_4$ yolk-shell spheres to TMA are attributed to the electronic sensitization by higher valent Mo doping and acid-base interaction between TMA and Mo components.

• 건축역사연구
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• 제19권5호
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• pp.81-98
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• 2010

In the middle of the 8th century, we met the new high-rise building, the 7th storied wooden pagodas in 'Kokubunji' in Japan. I tried to analyze and study this building to show how the wooden pagoda had changed itself because of appearance of new style. The conculusions are as follows; 1. The construction of the foundation was mainly composed namely 'Panchuk'. It was proceeded by two ways. One is the earthen-digging, laying foundations named 'Gulkwangpachuk' and the other is simply laying foundation named 'Jisangpanchuk'. In that period, due to the progress of the technique, we assumed that the main stream is 'Jisangpanchuk'. 2. The elevation of base was mostly the single foundation from archaeological study. The material was stone. The middle case of pagoda had the base of tile-roofed. We knew the just one pagoda had the base of brick, but that was not main stream. 3. The new device had appeared in the central base stone. It was the stone point. But in that period the existing method, a hole style and the new style was used in the central base stone. This fact is showed that the central government was not hold the reigon(it names 'Kook') in the respect of the technique. 4. The plan scale is classified of 3 group. As a result, the first body is larger, the main-unit and the sub-unit is a equal unit. But smaller, the length of main-unit is longer than the one of sub-unit. And the very small pagoda was build in that period.

• 융합정보논문지
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• 제9권12호
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• pp.147-156
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• 2019

동심 이중관에서 기본유체 물과 나노입자 산화알미늄의 혼합인 나노유체를 적용한 대향유동을 유한체적법의 수치적 방법으로 열전달 특성을 규명하였다. 고온유체는 내부 원형관으로 흐르며 열을 외부 환형관으로 흐르는 저온유체로 전달한다. 고온유체와 저온유체의 체적유량 및 나노입자의 체적농도를 변수로 두어 열전달 및 유동 특성을 조사했다. 결과는 나노입자의 체적농도와 체적유량의 증가함에 따라 열전달 성능이 증가함을 보였다. 외부와 내부 관 모두에서 나노유체인 경우가 기본유체보다 나노입자의 체적농도가 8%일 때 나노유체가 열전달 성능이 최대 17% 증가하는 것을 확인했다. 또한 기본유체에 비해 환형관의 대류열전달 계수는 최대 31% 증가함을 보였으며 열교환기의 유용도는 약 20%가 상승함을 확인하였다. 하지만 나노입자의 체적농도가 8%일때 마찰인자가 최대 136% 커지는 것을 확인하였다.

• Nuclear Engineering and Technology
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• 제54권10호
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• pp.3641-3649
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• 2022

A simple solvothermal reaction was used to prepare a 3-aminopropyl-functionalized silica-gel-based adsorbent for adsorbing Pd(II) from the nitric acid solution. Scanning electron microscopy, fourier transform infrared spectroscopy, and thermogravimetry analysis were performed on the as-synthesized adsorbent to demonstrate the successful introduction of Schiff base groups. Batch experiments were used to investigate the effects of contact time, nitric acid concentration, solution temperature, and adsorption capacity. It is worth noting that the prepared adsorbent exhibited a higher affinity toward Pd(II) with the uptake approximately 100% even in a 2 M HNO₃ solution. At an equilibrium time of 5 h, the maximum adsorption capacity of Pd(II) was estimated to be 0.452 mmol/g. The adsorbed Pd(II) could be completely eluted by dissolving 0.2 M thiourea solution in 0.1 M HNO₃. Using a combination of particle-induced X-ray emission analysis and an X-ray photoelectron spectrometer, the adsorbed Pd was found to be uniformly distributed on the surface of the prepared adsorbent and the existing species were Pd(II) and zero-valent Pd(0). Due to the desirable performances, facile preparation method, and abundant raw material source, the prepared adsorbent demonstrated a high application potential in the recovery of Pd(II) from simulated high-level liquid waste treatment.

• Journal of Veterinary Science
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• 제23권6호
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• pp.85.1-85.11
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• 2022

Background: Neonatal calf diarrhea is a major problem in the cattle industry worldwide. Rotavirus and Cryptosporidium parvum are the primary causative agents, especially during the first three weeks of the calf's life. Objectives: This study investigated the differences in acid-base, electrolytes, and biochemical parameters of diarrheic calves with infection of either rotavirus or C. parvum. Methods: A total of 61 Korean native calves (≤ 20 days old) were divided into two groups based on rotavirus or C. parvum infections: rotavirus infection (n = 44) and C. parvum infection (n = 17). The calves with at a specific blood pH range (pH 6.92-7.25) were chosen for comparison. The acid-base, electrolyte, chemistry, and serum proteins were analyzed, Further, fecal examinations were performed. Results: Compared to C. parvum-infected calves, the rotavirus-infected calves showed lower levels of total carbon dioxide, bicarbonate (HCO₃^-), anion gap, total protein, and albumin/globulin ratio, and significantly lower levels of potassium, globulin, and α2-globulin (p < 0.05). The C. parvum-infected calves (r = 0.749) had stronger correlations between pH and HCO₃^- than the rotavirus-infected calves (r = 0.598). Compared to rotavirus-infected calves, strong correlations between globulin and α2-globulin, α2-globulin and haptoglobin were identified in C. parvum-infected calves. Conclusions: This study is the first to investigate acid-base, electrolyte, and biochemical parameters in calves in response to infections of rotavirus and C. parvum. Although rotavirus and C. parvum cause malabsorptive and secretory diarrhea in similar-aged calves, blood parameters were different. This would help establish the diagnostic and treatment strategies.