• Title/Summary/Keyword: stability phase diagram

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Solid-liquid phase equilibria on the GdBa2Cu3O7-δ stability phase diagram in low oxygen pressures (1 - 100 mTorr)

  • Lee, J.W.;Lee, J.H.;Moon, S.H.;Yoo, S.I.
    • Progress in Superconductivity and Cryogenics
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    • v.14 no.4
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    • pp.28-31
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    • 2012
  • We report the solid-liquid phase equilibria on the $GdBa_2Cu_3O_{7-{\delta}}$ (GdBCO) stability phase diagram in low oxygen pressures ($PO_2$) ranging from 1 to 100 mTorr. On the basis of the GdBCO stability phase diagram experimentally determined in low oxygen pressures, the isothermal sections of three different phase fields on log $PO_2$ vs. 1/T diagram were schematically constructed within the $Gd_2O_3-Ba_2CuO_y-Cu_2O$ ternary system, and the solid-liquid phase equilibria in each phase field were described. The invariant points on the phase boundaries include the following three reactions; a pseudobinary peritectic reaction of $GdBCO{\leftrightarrow}Gd_2O_3$ + liquid ($L_1$), a ternary peritectic reaction of $GdBCO{\leftrightarrow}Gd_2O_3+GdBa_6Cu_3O_y$ + liquid ($L_2$), and a monotectic reaction of $L_1{\leftrightarrow}GdBa_6Cu_3O_y+L_2$. A conspicuous feature of the solid-liquid phase equilibria in low $PO_2$ regime (1 - 100 mTorr) is that the GdBCO phase is decomposed into $Gd_2O_3+L_1$ or $Gd_2O_3+GdBa_6Cu_3O_y+L_2$ rather than $Gd_2BaCuO_5+L$ well-known in high $PO_2$ like air.

Effects of Wire speed Fluctuation on Arc Stability in GMA Welding (GMAW에서 와이어 송급속도의 변동이 아크안정성에 미치는 영향에 관한 연구)

  • 신현욱;최용범;성원호;장희석
    • Journal of Welding and Joining
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    • v.13 no.4
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    • pp.85-102
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    • 1995
  • Weld quality of GMA welding processes is closely related to arc stability. Although many researches on arc stability have been performed, real-time estimation of arc stability has not been attempted. For instance, Mita proposed a off-line statistical method in which short circuiting and arcing time, and voltage and current wave forms were sampled to assess arc stability. But this method is not suitable to assess arc stability for GMA welder which employ inverter power source due to its controlled current and voltage wave forms. In this paper, the relationship between are stability and wire feed rate fluctuation is analyzed to propose new criterion for inverter power source. When arc voltage and arc current and arcing time are analyzed, we can assess arc stability only for short circuit transfer mode. When wire feed rate is analyzed, we can estimate arc stability udner the condition of spray transfer mode as well. Hence, the wire feed rate is chosen for monitoring process variable to cover possible metal transfer modes in GMAW. Through this research, it has been identified that arc stability in GMA welding processes is closely related to wire fed rate. When inverter power source is used, conventional statistical method of estimating arc stability, such as Mita index, is no longer valid due to its controlled voltage and current wave forms. Arc stability has been also examined in phase plane diagram.

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A simplified phase diagram in the ternary system $Y_2O_3-Ta(Nb)_2O_5-ZrO_2$ ($Y_2O_3-Ta(Nb)_2O_5-ZrO_2$ 삼성분계 상태도)

  • 이득용;김대준;장주웅;이명현
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.3
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    • pp.377-383
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    • 1997
  • Yttria-stabilized TZP alloyed with pentavalent oxides $(Ta_2O_5,\;Nb_2O_5)$ were fabricated by the conventional sintering method at $1500^{\circ}C$ in air to construct the simplified ternary phase diagram. The phase stability of tetragonal -$ZrO_2$ from the quasi-binary system $ZrO_2-YTa(Nb)O_4$, which do not transform to monoclinic-$ZrO_2$ even for a wide range of grain size and annealing temperature, was investigated to determine composition region of the non-transformable $t-ZrO_2$ solid solution$(NT_{ss})$. Phase stability of $NT_{ss}$ was probably due to the enhanced stability of $_YTa(Nb)O4$ having the tetragonal fergusonite structure. It was experimentally found that mixtures having $NT_{ss}$ alloyed with $T_{ss}$ by weight%% showed both excellent phase stability of $t-ZrO_2$ and fracture toughness even though the calculated composition of the mixture /was located outside $NT_{ss}$ composition region.

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Effect of Phase Stability on the Microstructure Development of α-SiAlON Ceramics

  • Kim, Joosun;Lee, Hae-Weon;Chen, I-Wei
    • Journal of Powder Materials
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    • v.10 no.2
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    • pp.118-122
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    • 2003
  • Alpha-SiAlON ceramics having various compositions and modifying cations were investigated with respect to their phase stability, transformation kinetics. and resulting microstructures. Each composition was heat treated at 150$0^{\circ}C$ for 1h and measured the $\alpha$-SiAlON transformation. The phase-boundary composition in the single-phase $\alpha$-SiAlON region showed sluggish transformation from $\alpha$-$Si_3N_4$ to $\alpha$-SiAlON compared to the phase-center composition in the diagram. Using the different rare earth modifying cations, dependence of transformation kinetics on the phase stability in a fixed composition was also explained. By changing size of the stable u-phase region with exchanging cations, systematic change in transformation was observed. Transformation rate of $\alpha$-SiAlON at low temperature has an important role on controlling the final microstructure. Less transformation gives more chances to develop elongated grain in the microstructure.

STUDY ON THE INFLUENCE OF POLYOL ON MICROEMULSION GEL SYSTEM (Microemulsion gel system에 있어서 Polyol의 효과에 관한 연구)

  • Youn, J.;Jin, P.K.
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.18 no.1
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    • pp.132-149
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    • 1992
  • This study relates to a microemulsion gel which is applied in various cosmetic preparations because of good appearance, superior stability and a thin, uniform, non-greasy fi Am on the skin. Main object of this study is to elucidate the influence of polyol(clarifying agent and/or coupling agent in microemulsion) on microemulsion and to establish the optimum conditions for microemulsion gel formation in the view of superior consistency, stability, clarity and pick-up from a container. The constituents of the system are composed of water, polar ester oi1, nonionic surfactant and polyol. Using the three-component phase diagram and the tetrahedral-phase diagram, we have investigated the changes of transparence regions, consistency and resonance effect by an impact in microemulsion gel varying in polyol ratio. The results of this study showed that the variation in the content of water and couple ins agent has major influence on the microemulsion gel and the optimum formation region of microemulsion gel is the widest when the ratio of glycerine(coupling agent) to water is 63-75% It is believed that optimum use of polyol seems to be helpful to obtain the microemulsion gel containing maximum amount of oil phase with minimum amount of surfactant which is recently one of the major problems of cosmetic chemists.

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Rotating Shaft Vibration Analysis of 200 kW, 15,000 rpm 3 Phase Induction Motor (200 kW급 15,000 rpm 3상 유도전동기의 회전축 진동해석)

  • Hong, D.K.;Koo, D.H.;Woo, B.C.;Hong, S.S.;Kwon, Y.S.;Kang, H.C.;Ahn, C.W.
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2006.05a
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    • pp.262-265
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    • 2006
  • The purpose of this study is to design 200 kW, 15,000 rpm 3 phase induction motor. This research deals with natural frequency and mode shape of rotating shaft of 3 phase induction motor with bearing stiffness by finite element analysis. We present natural frequency characteristic variation of rotating shaft according to change bearing stiffness. Also we are verified stability of rotating shaft from backward and forward critical speed by campbell diagram.

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Development of Lecithin Organogel to Improve Solubility of Genistein (레시틴 오가노겔을 이용한 난용성 제니스테인의 용해도 향상)

  • Lee, Su Jin;Kim, Jung A;Kang, Nae Gyu;Park, Sun Gyoo;Lee, Cheon Koo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.41 no.3
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    • pp.201-208
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    • 2015
  • Organogels are semi-solid systems that consist of an apolar solvent as the liquid phase within a three-dimensional networked structure. In this study, we developed a stable and skin penetration-enhanced Lecithin Organogel (LO) containing genistein, which is one of the poorly soluble active ingredients in both polar and apolar phase. After screening of various components (type of gelators, organic and aqueous phase), hydrogenated lecithin (HL), sunflower oil (SO), dipropylene glycol (DPG), and polyethylene glycol (PEG) were mainly used in this formulation. Phase ternary diagram was employed for optimization of the composition in the LO. The formulated LO were evaluated for its organoleptic characteristics, stability, pH, rheology, phase transition temperatures, microscopic analysis and skin penetration. The optimized stable LO system can be utilized as an effective and stable cosmetic formulation that can carry poorly soluble active ingredients at high concentration for topical dermal delivery.

DTERMINATION OF STBLE-UNSTABLE REGIONS OF THE SLOSH MOTION IN SPINNING SPACE VEHICLE BY PERTURBATION TECHNIQUE (PERTURBATION 방법을 이용한 회전안정화 우주비행체 내부 유동의 안정-불안정 영역 결정)

  • Kang, Ja-Young
    • Journal of Astronomy and Space Sciences
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    • v.22 no.4
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    • pp.513-526
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    • 2005
  • The objectives of this study are to perform extensive analysis on internal mass motion for a wider parameter space and to provide suitable design criteria for a broader applicability for the class of spinning space vehicles. In order to examine the stability criterion determined by a perturbation method, some numerical simulations will be performed and compared at various parameter points. In this paper, Ince-Strutt diagram for determination of stable-unstable regions of the internal mass motion of the spinning thrusting space vehicle in terms of design parameters will be obtained by an analytical method. Also, phase trajectories of the motion will be obtained for various parameter values and their characteristics are compared.

A Study on Improvement of Dynamic Characteristics and Stability of PM Stepping Motor (PM 스텝 모우터의 동특성 개선 및 안정화에 관한 연구)

  • Kim, Do-Hyung
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.23 no.6
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    • pp.888-894
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    • 1986
  • In this paper, a phase locked loop control system is designed to have high performance and stability in a 2-phase bifilar winding PM step motor. The BODE diagram analysis method is used to improve the stability and dynamic characteristic of the closed loop control system. Also, a PLL servo is used to accomplish high-precision speed and to attain smooth ness. In applying the PLL control to the step motor, a new design method is suggested to solve the control problem which occurs as a result of the limited maximum acceleration of the step motor. A simple design method is suggested without using the complicated multi-step characteirstic of the step motor in constant voltage driving. Computer simulation results agree clorelg with experiments, indicating that the PLL servo system of the step motor designed is very useful.

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Phase Stability of Laser-ablated $SmBa_2Cu_3O_{7-y}$ thin Films Investigated by Raman Scattering Spectroscopy

  • Kim, G.;Jeong, A.R.;Jo, W.;Park, D.Y.;Cheong, H.;Tsukada, A.;Hammond, R.H.;Beasley, M.R.
    • Progress in Superconductivity
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    • v.11 no.2
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    • pp.141-146
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    • 2010
  • Phase stability diagram and boundary of a- and c-axis orientation of $SmBa_2Cu_3O_{7-y}$ (SmBCO) thin films grown by pulsed laser deposition (PLD) were reported with studies based on x-ray diffraction [1]. Four different samples are systematically analyzed: normal c-axis oriented orthorhombic $SmBa_2Cu_3O_{7-y}$, a-axis oriented $SmBa_2Cu_3O_{7-y}$, c-axis oriented orthorhombic $SmBa_2Cu_3O_{7-y}$ with $Sm_2BaCuO_5$ phase, and a mixture with c-axis oriented orthorhombic $SmBa_2Cu_3O_{7-y}$ and anomalously long-c tetragonal $SmBa_2Cu_3O_x$. Raman scattering spectroscopy equipped with polarization analysis elucidates the crystal orientation and the origin of the growth of the materials. It indicates that the technique can be used for quality control of conductor manufacturing processes as well as for enhancement of the materials properties.