• Steel and Composite Structures
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• v.46 no.1
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• pp.133-141
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• 2023

Based on the third-order shear deformation theory, the wave propagations in doubly curved spherical- and cylindrical- panels reinforced by carbon nanotubes (CNTs) are firstly investigated in present work. The coupled equations of wave propagation for the carbon nanotubes reinforced composite (CNTRC) doubly curved panels are established. Then, combined with the harmonic balance method, the eigenvalue technique is adopted to simulate the velocity-wave number curves of the CNTRC doubly curved panels. In the end, numerical results are showed to discuss the effects of the impact of key parameters including the volume fraction, different shell types (including spherical (R₁=R₂=R) and cylindrical (R₁=R, R₂=→∞)), wave number as well as modal number on the sensitivity of elastic waves propagating in CNTRC doubly curved shells.

• Journal of Sensor Science and Technology
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• v.27 no.2
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• pp.76-81
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• 2018

Au@ZnO core-shell nanoparticles (NPs) were prepared by a simple method followed by heat-treatment for gas sensor applications. The advantage of the core-shell morphology was investigated by comparing the gas sensing performances of Au@ZnO core-shell NPs with pure ZnO NPs and different wt% of Au-loaded ZnO NPs. The crystal structures, shapes, sizes, and morphologies of all sensing materials were characterized by XRD, TEM, and HAADF-STEM. Au@ZnO core-shell NPs were nearly spherical in shape and Au NPs were encapsulated in the center with a 40-45 nm ZnO shell outside. The gas sensing operating temperature for Au@ZnO core-shell NPs was $300^{\circ}C$, whereas it was $350^{\circ}C$ for pure ZnO NPs and Au-loaded ZnO NPs. The maximum response of Au@ZnO core-shell NPs to 1000 ppm CO at $300^{\circ}C$ was 77.3, which was three-fold higher than that of 2 wt% Au-loaded ZnO NPs. Electronic and chemical effects were the primary reasons for the improved sensitivity of Au@ZnO core-shell NPs. It was confirmed that Au@ZnO core-shell NPs had better sensitivity and stability than Au-loaded ZnO NPs.

• Korean Chemical Engineering Research
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• v.48 no.1
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• pp.98-102
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• 2010

Magnolia kobus leaf extract was used for the synthesis of bimetallic Au core-Ag shell nanoparticles. Gold seeds and silver shells were formed by first treating aqueous solution of $HAuCl_4$ and then $AgNO_3$ with the plant leaf extract as reducing agent. UV-visible spectroscopy was monitored as a function of reaction time to follow the formation of bimetallic nanoparticles. The synthesized bimetallic nanoparticles were characterized with transmission electron microscopy(TEM), energy dispersive X-ray spectroscopy(EDS), and X-ray photoelectron spectroscopy(XPS). TEM images showed that the bimetallic nanoparticles are a mixture of plate(triangles, pentagons, and hexagons) and spherical structures. The atomic Ag contents of the bimetallic Au/Ag nanoparticles determined from EDS and XPS analysis were 34 and 65 wt%, respectively, suggesting the formation of bimetallic Au core-Ag shell nanostructure. This core-shell type nanostructure is expected to have potential for application in surface enhanced Raman spectroscopy and in the sensitive detection of biomolecules.

• Structural Engineering and Mechanics
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• v.19 no.3
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• pp.321-336
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• 2005

The structural feasibility of a variety of non-conventional sludge digesters, in the form of thin shells of revolution constructed in concrete, has formed the subject of investigation of a recent programme of research at the University of Cape Town. Such forms are usually known in the literature as "egg-shaped", and the advantages of these over conventional digesters of the wide-cylindrical type are now well-recognised: superior mixing efficiency, less accumulation of deposits at the bottom, easier removal of bottom deposits and surface crust, reduced heat losses, and so forth. With the aim of exploring the structural feasibility of various non-conventional forms for concrete sludge digesters, and making available usable analytical data and practical guidelines for the design of such thin shell structures, a number of theoretical studies have recently been undertaken, and these have covered conical assemblies, spherical assemblies and parabolic ogival configurations. The purpose of the present paper is to bring together the different analytical approaches employed in each of these studies, summarise the main findings in each case, draw comparisons among the various studied configurations with regard to structural efficiency and functional suitability, and make appropriate conclusions and recommendations.

• Advances in materials Research
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• v.5 no.4
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• pp.205-221
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• 2016

In this article, the buckling responses of functionally graded curved (spherical, cylindrical, hyperbolic and elliptical) shell panels under elevated temperature load are investigated numerically using finite element steps. The effective material properties of the functionally graded shell panel are evaluated using Voigt's micromechanical model through the power-law distribution with and without temperature dependent properties. The mathematical model is developed using the higher-order shear deformation theory in conjunction with Green-Lagrange type nonlinear strain to consider large geometrical distortion under thermal load. The efficacy of the proposed model has been checked and the effects of various geometrical and material parameters on the buckling load are analysed in details.

• Earthquakes and Structures
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• v.13 no.5
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• pp.455-464
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• 2017

This paper develops a new method for analyzing the structural seismic behavior of single-layer reticulated shells based on exponential strain energy density (ESED). The ESED method reveals a characteristic point from a relationship between ESED sum and peak seismic acceleration. Then, the characteristic point leads to an updated concept of structural failure and an ESED-based criterion for predicting structural failure load. Subsequently, the ESED-based criterion and the characteristic point are verified through numerical analysis of typical single-layer reticulated shells with different configurations and a shaking table test of the scale shell model. Finally, discussions further verify the rationality and application of the ESED-based criterion. The ESED method might open a new way of structural analysis and the ESED-based criterion might indicate a prospect for a unified criterion for predicting seismic failure loads of various structures.

• Polymer(Korea)
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• v.26 no.2
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• pp.227-236
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• 2002

The structure of pregel state in thermoreversible poly(vinylidene fluoride)(PVDF) /propylene carbonate(PC) system was investigated by laser light scattering. It was found that the PVDF chain did not exist as a separate chain even in a very dilute concentration(i.e. 100 times more dilute than the gel formation concentration) but as a large spherical aggregate with the radius of gyration $R_G$, of 232 nm and the effective hydrodynamic radius $R_H$= of 407 nm at $40^{\circ}C$. Based upon experimental results such as $R_H/R_G$=ratio of 1.75 and the pattern of scattering intensity with a minimum, a core-shell type sphere model was suggested as a structure of the aggregate. According to this model, the radius of core part was estimated as 215 nm, the shell thickness as 192 nm, and the ratio of monomer density of the shell part to that of the core part as about 0.075.

• Special Issue of the Society of Naval Architects of Korea
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• 2005.06a
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• pp.22-30
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• 2005

Sloshing loads, produced by the violent liquid free-surface motions inside the cargo tank have become an important design parameter in ship building industry since there have been demands for the increased sizes of the cargo containment system of LNG carriers. In this study, sloshing impact pressure acting on the shell of the spherical cargo tank of an LNG carrier as well as dynamic pressure and flow behavior around the pump tower located at the center of the tank have been calculated. Comparative numerical sloshing simulations for a spherical LNG tank using 2-D LR.FLUIDS which is based on the finite difference method and 3-D MSC.DYTRAN which is capable of calculating nonlinear fluid-structure interaction have been carried out. A method of calculating sloshing-induced dynamic loads and the subsequent structural strength analysis for pump tower of a spherical LNG carrier using MSC. DYTRAN and MSC.NASTRAN have been presented.

• Structural Engineering and Mechanics
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• v.74 no.2
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• pp.297-311
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• 2020

The main purpose of this study is to analyze the effects of external pressure on the vibration and buckling of functionally graded (FG) spherical panels resting of elastic medium. The material characteristics of the FG sphere continuously vary through the thickness direction based on the power-law rule. In accordance with first-order shear deformation shell theory and by the use of Ritz formulation the governing equations are presented. In this regard, the beam functions are applied in two-dimensions for different sets of boundary supports. The Winkler and Pasternak models of elastic foundations are also taken into account. In order to show the validity and applicability of the presented formulation, various comparison studies are given. Furthermore, a diverse range of numerical results is reported to check the impacts of geometrical and material parameters along with external pressure on the vibration and buckling analysis of FG spherical panels.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.6 no.4
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• pp.521-531
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• 1996

Inorganic and inorganic/organic microcapsules were prepared by spray drying. $K_{4}SO$ and clay were used as the core and colloidal silica as the shell for the inoroganic microcapsules. Forthe inorganic/organic microcapsules were used the inorganic microcapsule which were mentioned above (core) and ethyl cellulose (shell). To characterize the prepared microcapsule for the practical use, the homogenity of surface and pore volume are the dominent factors. At the volume ratio of 0.3/0.7 of core/shell, the spherical and homogeneous surfaces of inorganic microcapsule could be synthesized. In the case of inorganic/organic microcapsules, the weitht ratio was 0.76/0.24. The pore volume of inorganic/organic microcapsules decreases more than that of inorganic microcapsule. The more the amount of shell (ethyl cellulose) in inorganic/organic microcapsules increases, the more the coating became homogeneous and the pore volume decreased.