• Title/Summary/Keyword: specific discharge

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Factors Affecting on Electrochemical Performances for Zn/Air Fuel Cell (Zn/Air Fuel Cell의 전기화학적 성능에 미치는 인자연구)

  • Lee, Chang-Woo;Eom, Seung-Wook;Kim, Hyun-Soo;Moon, Seong-In;Yun, Mun-Soo
    • Proceedings of the KIEE Conference
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    • 2005.07b
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    • pp.1717-1718
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    • 2005
  • Zn/Air 전지는 방전하는 동안에 최종 방전 cut-off 전압에 이르기까지 평탄한 voltage profile의 전기화학적 특성을 보여준다. Air cathode 전극의 경우, 전극의 porosity에 따라 특성변화에 큰 영향을 가지는 것으로 보이며 이의 비교연구를 위해 사용되어지는 활성탄의 종류를 달리함으로써 이러한 인자의 영향을 이해하고자 하였다. 이러한 인자연구는 discharge voltage, specific capacity, 및 energy 등의 연구결과를 바탕으로 고찰되어졌으며 결과적으로 공기 유로를 통한 산소의 원활한 공급 여부가 주요 원인인 것으로 여겨진다.

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Properties Changing depends on Substituents or Dopants of Li-Mn oxide material (Li-Mn계 산화물의 치환 및 첨가에 따른 물성 변화)

  • Lee, Dae-Jin;Ji, Mi-Jung;Choi, Byung-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.289-289
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    • 2007
  • Spinel structured $LiMn_2O_4$ is more economic and environmental friendly to be used as commercial active material for secondary battery compared to Co-oxide material active material, but spinel structure of $LiMn_2O_4$ is unstable and its capacitance decreases with increase of cycle. Therefore, the purpose of our sturdy is to improve the stability of $LiMn_2O_4$ spinel structure and increase its capacitance by using substituents or dopants. $LiMn_2O_4$ powder was synthesized by charging substituents or dopants mole fractions, and temperatures. Crystal state, structure and specific surface area of the synthesized powder were measured and also characteried electrochemically by measuring its impedance, charge-discharge capacitance and etc.

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Fabrication and electrochemical characterization of amorphous vanadium oxide thin films for thin film micro-battery by reactive r.f. sputtering (반응성 r.f. 스퍼터링에 의한 마이크로 박막 전지용 산화바나듐 박막의 제작 및 전기화학적 특성 평가)

  • 전은정;신영화;남상철;윤영수;조원일
    • Journal of the Korean Vacuum Society
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    • v.9 no.1
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    • pp.42-47
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    • 2000
  • The amorphous vanadium oxide thin films for thin-film rechargeable lithium batteries were fabricated by r.f. reactive sputtering at room temperature. As the experimental parameter, oxygen partial pressure was varied during sputtering. At high oxygen partial pressures(>30%), the as-deposited films, constant current charge/discharge characteristics were carried out in 1M $LiPF_6$, EC:DMC+1:1 liquid electrolyte using lithium metal as anode. The specific capacity of amorphous $V_2O_5$ after 200cycles of operation at room temperature was higher compared to crystalline $V_2O_5$. The amorphous vanadium oxide thin film and crystalline film showed about 60$\mu$Ah/$\textrm{cm}^2\mu\textrm{m}$ and about 38$\mu$Ah/$\textrm{cm}^2\mu\textrm{m}$, respectively. These results suggest that the battery capacity of the thin film vanadium oxide cathode strongly depends on the crystallinity.

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A study on evaluation and estimation of the specific discharge (비유량 산정 및 평가에 관한 연구)

  • Kim, Min-Seok;Kang, Won-Sam;Moon, Young-Il;Park, Se-Hun
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.934-934
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    • 2012
  • 우리나라는 계절의 특성상 변동성이 심하고 경향성이 뚜렷한 특징으로 여름철에는 물이 풍부하여 홍수피해를 걱정하고 봄, 겨울에는 물 부족으로 걱정하는 것이 현실이다. 따라서 수자원 확보 및 관리를 위해서 정확한 유량을 측정하고 자료를 관리하는 것은 대단이 중요하다. 하천의 유량 산정시 실측유량을 통해 연속적인 하천의 유량자료를 산정하면 좋으나, 자연적, 외부적인 요건으로 인하여 기간분리가 발생한다. 이러한 경우 비유량을 적용하여 연속적인 유량자료를 생산해 내는 것이 하나의 대안으로 간주된다. 본 연구에서는 낙동강 유역을 중심으로 분석대상지점을 선정하고, 각각의 지점의 실측유량과 비유량을 각각 산정하여 비교분석을 실시하였다. 또한 상 하류간의 유역반응시간을 고려하여 비유량을 적용하고 적합도 평가를 실시함으로써 더욱 신뢰도 높고 안정된 유량자료의 산정과 평가를 실시하였다.

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A Study on the Designation of Nonpoint Pollution Management Region (비점오염원 관리지역 도출에 관한 연구)

  • Choi, Ji Yong
    • Journal of Korean Society on Water Environment
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    • v.23 no.4
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    • pp.434-439
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    • 2007
  • Amended Water Quality Environment Preservation Law enacted that the areas where nonpoint pollution is serious can be designated as Nonpoint Source Management Region. According to Section 54 of Water Quality Environment Preservation Law, corresponding watersheds are areas where runoff from nonpoint pollution source may deteriorate river and lake water quality, residents' health and property, and ecosystem. The criteria are as followings; i) where nonpoint source contribution result in or will result in significant ecological destruction, iii) national or local industrial complexes and cities having population greater than one million where nonpoint source managements are necessary, iv) where specific measurement is necessary because of its geological and stratigraphic characteristics. In this research, detailed designation criteria was developed reflecting current nonpoint source management situation and its discharge characteristics. Depending on the result, target regions were also suggested. In additions, it will be desirable that the target regions are prioritized considering institutional execution availability, stakeholder's agreement, and connection with existing nonpoint source pollution management measures.

Excavated carbon with embedded Si nanoparticles for ultrafast lithium storage

  • An, Geon-Hyoung;Kim, Hyeonjin;Ahn, Hyo-Jin
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.146-152
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    • 2018
  • Due to their excellent mechanical durability and high electrical conductivity, carbon and silicon composites are potentially suitable anode materials for Li-ion batteries with high capacity and long lifespan. Nevertheless, the limitations of the composites include their poor ionic diffusion at high current densities during cycling, which leads to low ultrafast performance. In the present study, seeking to improve the ionic diffusion using hydrothermal method, electrospinning, and carbonization, we demonstrate the unique design of excavated carbon and silicon composites (EC/Si). The outstanding energy storage performance of EC/Si electrode provides a discharge specific capacity, impressive rate performance, and ultrafast cycling stability.

Enhanced performance at an early state of hydrocarbon selective catalyst reduction of NOx by atmospheric pressure plasma

  • Nguyen, Duc Ba;Heo, Il Jeong;Mok, Young Sun
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.372-379
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    • 2018
  • The improvement of $NO_x$ reduction by $Ag/{\gamma}-Al_2O_3$ with a hydrocarbon ($n-C_7H_6$) in the early state was investigated in a packed-bed dielectric barrier discharge plasma reactor. The results revealed that the combination of plasma with the catalyst enhanced $NO_x$ reduction efficiency at low operating temperatures, depending on the temperature and specific input energy. To sum up, the poor performance of the catalytic $NO_x$ reduction at low temperatures in the early stage before reaching thermochemical steady state can be greatly compensated for by using the atmospheric-pressure plasma generated in the catalyst bed.

Development of rotor profile design technology for improving the screw compressor performance (공기압축기 성능향상을 위한 로터 프로파일 설계기술 개발 연구)

  • Kim, Tae-Yoon;Lee, Jae-Young;Lee, Dong-Kyun;Kim, Youn-Jea
    • Proceedings of the KSR Conference
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    • 2009.05b
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    • pp.585-592
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    • 2009
  • The performance of screw compressor depends on lots of design parameters of rotor profile, such as length of seal line, wrap angle, blow hole, suction and discharge port size, number of rotor lobe, etc. The optimum rotor profile makes it possible to increase the compression efficiency with low energy consumption, and to minimize the loss of power. In this research, a new rotor profile design and performance analysis are done by computer simulation. It is expected that the volumetric efficiency is improved because the internal leakage is reduced due to the minimization of blow hole and clearance, and the stiffness of rotors is increased due to the reduction of length to diameter ratio. Also, the specific power consumption will be secured for use ranging from low to high operation speed.

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Electroactive Conjugated Polymer / Magnetic Functional Reduced Graphene Oxide for Highly Capacitive Pseudocapacitors: Electrosynthesis, Physioelectrochemical and DFT Investigation

  • Ehsani, A.;Safari, R.;Yazdanpanah, H.;Kowsari, E.;Shiri, H. Mohammad
    • Journal of Electrochemical Science and Technology
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    • v.9 no.4
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    • pp.301-307
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    • 2018
  • The current study fabricated magnetic functional reduced graphene oxide (MFRGO) by relying on ${FeCl_4}^-$ magnetic anion confined to cationic 1-methyl imidazolium. Furthermore, for improving the electrochemical performance of conductive polymer, hybrid poly ortho aminophenol (POAP)/ MFRGO films have then been fabricated by POAP electropolymerization in the presence of MFRGO nanorods as active electrodes for electrochemical supercapacitors. Surface and electrochemical analyses have been used for characterization of MFRGO and POAP/ MFRGO composite films. Different electrochemical methods including galvanostatic charge discharge experiments, cyclic voltammetry and electrochemical impedance spectroscopy have been applied to study the system performance. Prepared composite film exhibited a significantly high specific capacity, high rate capability and excellent cycling stability (capacitance retention of ~91% even after 1000 cycles). These results suggest that electrosynthesized composite films are a promising electrode material for energy storage applications in high-performance pseudocapacitors.

Ultrahigh supercapacitance in cobalt oxide nanorod film grown by oblique angle deposition technique

  • Kannan, V.;Choi, Jong-Hyeok;Park, Hyun-Chang;Kim, Hyun-Seok
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1399-1402
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    • 2018
  • Nanorod films of cobalt oxide ($Co_3O_4$) have been grown by a unique oblique angle deposition (OAD) technique in an e-beam evaporator for supercapacitor electrode applications. This technique offers a non-chemical route to achieve large aspect ratio nanorods. The fabricated electrodes at OAD $80^{\circ}$ exhibited a specific capacitance of 2875 F/g. The electrochemically active surface area was $1397cm^{-2}$, estimated from the non-Faradaic capacitive current region. Peak energy and power densities obtained for $Co_3O_4$ nanorods were 57.7 Wh/Kg and 9.5 kW/kg, respectively. The $Co_3O_4$ nanorod electrode showed a good endurance of 2000 charge-discharge cycles with 62% retention. The OAD approach for fabricating supercapacitor nanostructured electrodes can be exploited for the fabrication of a broad range of metal oxide materials.