• Title/Summary/Keyword: solidification agent

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Recycling of In-site waste soil material to fill a hollow between PHC pile and Earthen wall

  • Jang, Myung-Houn;Choi, Hee-Bok
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.5
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    • pp.510-517
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    • 2012
  • This study evaluated the recycling potential of in-site waste soil as pile back filling material (PBFM). We performed experiments to check workability, segregation resistance, bond strength, direct shear stress test, and dynamic load test using in-site waste soil in coastal areas. We found that PBFM showed better performance than general cement paste in terms of workability, segregation resistance, and bond strength. On the other hand, the structural performance of PBFM was slightly lower than that of general cement paste due to the skin friction force of pile by Pile Driving Analyzer and direct shear stress. However, because this type of performance degradation in terms of structure can be improved through the use of piles with larger diameter or by changing the type of pile, considering the economics and environment, we considered that recycling of PBFM has sufficient value.

A Study on the Strength at an Early Stage of the Compound Mixed into Polycarboxylate (Polycarboxylate에 혼합 사용된 혼화제의 조기강도 발현성상에 관한 연구)

  • Ryu, Hyun-Gi
    • Journal of the Korea Institute of Building Construction
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    • v.9 no.6
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    • pp.175-181
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    • 2009
  • In this research, experiments were conducted to find out whether polycarboxylate could be used as a crude steel admixture for practical work, depending on the change in the replacement level of the compound mixed into polycarboxylate. Its fluidity was satisfactory, its airspace was a bit smaller than the KS standard, and its unit volume weight was proven to meet the standard. The amount of bleeding was smallest in B2, and in terms of the solidification time, the first and the last solidification was faster in A1, B1, and C1. With regard to the compressive strength in early days as acharacteristic of hardened concrete, all addition rates of 7-day C2 displayed the highest strength value, among which the addition rate of 1.3% had the biggest strength performance tendency. The seal strength also showed the strength performance rate which was about one tenth as big as that of the compressive strength. The length change rate resulting from dryness and contraction was proven to be good, and once the appropriate AE air entraining agent is used, it is evaluated to be a very useful and practical compound out in the field.

Fixation Mechanism and Leachability of Heavy Metal for Sludge Solidified by Silica Fume and Cement (실리카흄을 이용한 중금속함유 유기성 슬러지 시멘트 고화체의 용출특성과 고정화기작에 관한 연구)

  • Jun, Kwan-Soo;Hwang, Byung-Gi
    • Applied Chemistry for Engineering
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    • v.16 no.2
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    • pp.180-186
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    • 2005
  • This paper discusses the development of mixtures for silica fume as a stabilization/solidification agent and a binder for industrial wastewater residue containing organic and heavy metal contaminants. The UCS (unconfined compressive strength) gradually increased to 66.7% as the silica fume content increased to 15%. The leaching of TOC (total organic carbon) and chromium decreased as more OPC (Ordinary Portland Cement) was substituted with the silica fume. When a mixture had 5% silica fume, it retained about 85% TOC, and chromium leached out 0.76 mg-Cr/g-Cr in acidic solution. Also, microstructural studies of the solidified analysis showed that the silica fume caused an inhibition to the ettringite formation which did not contrilbute to setting but coated the cement particles and retarded the setting reactions. The results indicated that the incorporation of silica fume into the cement matrix minimized the detrimental effects of organic materials on the cement hydration reaction and the contaminant leachability.

Acoustic Abosrption Characteristic and Fabrication process of Foamed Aluminum (발포알루미늄의 제조공정 및 흡음특성)

  • Hur, Bo-Young;Ahn, Hyo-Jun;Jeon, Sung-Hwan;Choi, Dae-Choul;Kim, Sang-Youl;Hur, Yoon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.11a
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    • pp.396-402
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    • 2000
  • Porous structures of aluminum foam have been studied. The apparent foam shape, foam hight, density, pore size, shape, and their distributions in various section areas of the experimental samples have been investigated. The sample have been cast into metallic mold, using aluminum foam prepared from a precursor based on pure Al ingot mixed with various amount of 1-2wt% increasing viscosity and foam agent materials. The process provides for flexibility in design of foam structures via relatively easy control over the amount of hydrogen evolution and the drainage processes which occur during foam formation. This is facilitated by manupulating parameters such as the foaming agent, thermal histories during solidification and mix melt viscosities. The acoustical performance of the panel made with the foamed aluminum is considerably improved; its absorption coefficient shows NRC 0.6-0.8. It has been found that the Al foam is very preferable for the compactness of the thermal system.

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Half-degumming Behaviors of Raw Silk Yarns Degummed with Soap and Alkalis (비누와 알칼리에 의한 실크 생사의 반숙정련 거동)

  • Park, Geon-Yong
    • Textile Coloration and Finishing
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    • v.22 no.4
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    • pp.349-355
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    • 2010
  • To investigate the half-degumming of raw silk, the degumming was carried out with soap or sodium carbonate or sodium bicarbonate and some mixed agents at $80^{\circ}C$ for 15 and 30 minutes. With soap of 20~25%o.w.f. degumming losses were about 7~12%. Degumming losses with sodium carbonate of 2~5%o.w.f. were about 6~15%. And about 6~12% wright losses were observed in the degumming with sodium bicarbonate of 20~30%o.w.f. In the degumming with the mixed degumming agents of soap and sodium carbonate, degumming losses were 9~15% with 5%o.w.f. soap and 2~5%o.w.f. sodium carbonate. Sodium carbonate was more effective on the removal of sericin from raw silk than soap. During drying generally half degummed silk yarns stuck together to result in harsh and hard lumps by the adhesion and solidification of the residue sericin of partially degummed silk. Sodium hydrosulfite in degumming agent effectively protected the adhesion of half degummed silk yarns.

The Operation Experience of the Concentrated Waste Drying System with Variation in the Mole Ratio of Boron to Sodium (방사성 폐액중의 붕소와 나트륨의 몰비 변화에 따른 농축폐액건조설비 운전 경험사례)

  • 김영식;김세태;안교수;박진석;박종길
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.220-225
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    • 2003
  • Generally, liquid radioactive wastes generated in nuclear power plant exist in powder form which do not contain moisture through the evaporating process of the Liquid Waste Management System and drying process of the Concentrated Waste Drying System. This powder form wastes are blended homogeneously with paraffin solidification agent and packed in metal drum to ensure its stability during handling and disposal. However, it was experienced that the powder form wastes were not blended homogeneously and separated into two layers in metal drum, on the other hand, a Portion of powder was adhered and solidified to the Inside parts of facility during the blending process. And the flaw of blending process above would come in case the mole ratio of Boron to Sodium in liquid radioactive wastes exceeds 0.2.

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Properties of Compressive Strength of Mortar Mixed with WCP for Soil Pavement (폐콘크리트분말 혼합 흙도로 포장용 모르타르의 압축강도 특성)

  • Moon Han Young;Choi Yun Wang;Song Yong Kyu;Moon Dae Joong;Shin Hwa Cheol;Jung Chul Hee
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.537-540
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    • 2004
  • Recently, for industrial development period, concrete structures in domestics have been increased. They were deteriorated by attack of carbonation, freeze-thaw and corrosion etc. In hence they were demolished and reconstructed, resulted in waste concrete particles. In this paper, waste concrete particles (WCP) by product from different crushing and selecting process were used in soil cement-based pavement in the various recycling. For using WCP in soil cement-based pavement, the Qualities, physical and chemical properties, of WCP should be researched. In the first step, the specified compressive strength of mortar for two types of clay sand soil and clay soil respectively was experimented to be 15 Mpa and then optimum mixing ratio of chemical solidification agent were decided in the range of $1.5\~3.0\%$ in the replacement with cement weight content. In the second step, based on the prior experimental results, recycling possibility of WCP in soil cement-based pavement was studied. In the result of experiment the mixing ratio of WCP were 5, 10, 15 and $20\%$ in the replacement with soil weight and the compressive strength of mortar was somewhat decreased according to the increase of the mixing ratio of WCP.

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Characteristics of Solidified Cement of Electrokinetically Decontaminated Soil and Concrete Waste (동전기 제염 토양 및 콘크리트 폐기물의 시멘트 고화 특성)

  • Koo, Daeseo;Sung, Hyun-Hee;Hong, Sang Bum;Seo, Bum Kyoung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.1
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    • pp.83-91
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    • 2018
  • While using an electrokinetic method to analyze the characteristics of cement solidification of radioactive wastes from decontaminated uranium soil and concrete, the compressive strength, pH, electrical conductivity, irradiation effects, and volume expansion were measured for the solidified cement specimens. The workability of cement solidified from radioactive waste was about 170-190%. After the solidified cement was irradiated, the compressive strength decreased by about 15%, but met the criteria ($34kgf{\cdot}cm^{-2}$) of KORAD (Korea Radioactive Waste Agent). According to the results of SEM-EDS for solidified cement, the aluminum phase was well combined with cement, while the calcium phase was separated from cement. The volume of solidified cement in radioactive wastes was dependent on the waste-to-cement ratio and the amount of water, and increased by about 30% under the conditions used in this study. Therefore, it was concluded that permanent disposal of electrokinetically decontaminated radioactive wastes is appropriate.

Dechlorination/Solidification of LiCl Waste by Using a Synthetic Inorganic Composite with Different Compositions (합성무기복합체 조성변화에 따른 모의 LiCl 염폐기물의 탈염소화/고형화)

  • Kim, Na-Young;Cho, In Hak;Park, Hwan-Seo;Ahn, Do-Hee
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.3
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    • pp.211-221
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    • 2016
  • Waste salt generated from a pyro-processing for the recovery of uranium and transuranic elements has high volatility at vitrification temperature and low compatibility in conventional waste glasses. For this reason, KAERI (Korea Atomic Energy Research Institute) suggested a new method to de-chlorinate waste salt by using an inorganic composite named SAP ($SiO_2-Al_2O_3-P_2O_5$). In this study, the de-chlorination behavior of waste salt and the microstructure of consolidated form were examined by adding $B_2O_3$ and $Fe_2O_3$ to the original SAP composition. De-chlorination behavior of metal chloride waste was slightly changed with given compositions, compared with that of original SAP. In the consolidated forms, the phase separation between Si-rich phase and P-rich phase decreases with the amount of $Al_2O_3$ or $B_2O_3$ as a connecting agent between Si and P-rich phase. The results of PCT (Product Consistency Test) indicated that the leach-resistance of consolidated forms out of reference composition was lowered, even though the leach-resistance was higher than that of EA (Environmental Assessment) glass. From these results, it could be inferred that the change in the content of Al or B in U-SAP affected the microstructure and leach-resistance of consolidated form. Further studies related with correlation between composition and characteristics of wasteform are required for a better understanding.

Numerical Investigation on the Urea Melting Characteristics with Coolant and Electric Heaters (냉각수 및 전기 가열 방식에 따른 요소수 해동 특성에 관한 수치해석 연구)

  • Lee, Seung Yeop;Kim, Man Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.1
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    • pp.1-7
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    • 2016
  • A Urea-SCR(Selective Catalytic Reactor) system, which converts nitrogen oxides into nitrogen and water in the presence of a reducing agent, creates a major exhaust gas aftertreatment system for NOx reduction among other compounds. With regard to vehicle applications, a urea solution was chosen based on its eutectic composition of a 32.5wt% urea-water solution. An important advantage of this eutectic composition is that its melting point of $-11.7^{\circ}C$ is sufficiently low to avoid solidification in cold environments. However, the storage tanks must be heated separately in case of low ambient temperature levels to ensure a sufficient amount of liquid is available during scheduled start ups. In this study, therefore, a numerical investigation of three-dimensional unsteady heating problems analyzed to understand the melting processes and heat transfer characteristics including liquid volume fraction, temperature distributions, and temperature profiles. The investigations were performed using Fluent 6.3 commercial software that modeled coolant and electric heater models based on a urea solution. It is shown that the melting performance with the electric heater is higher than a coolant heater and is more efficient.