• Title/Summary/Keyword: solid density

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Numerical Study on the Motion Characteristics of a Freely Falling Two-Dimensional Circular Cylinder in a Channel (채널 내 자유 낙하하는 2차원 원형 실린더의 운동 특성에 관한 수치적 연구)

  • Jeong, Hae-Kwon;Yoon, Hyun-Sik;Ha, Man-Yeong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.7
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    • pp.495-505
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    • 2009
  • A two-dimensional circular cylinder freely falling in a channel has been simulated by using immersed boundary - lattice Boltzmann method (IB-LBM) in order to analyze the characteristics of motion originated by the interaction between the fluid flow and the cylinder. The wide range of the solid/fluid density ratio has been considered to identify the effect of the solid/fluid density ratio on the motion characteristics such as the falling time, the transverse force and the trajectory in the streamwise and transverse directions. In addition, the effect of the gap between the cylinder and the wall on the motion of a two-dimensional freely falling circular cylinder has been revealed by taking into account a various range of the gap size. As the cylinder is close to the wall at the initial dropping position, vortex shedding in the wake occurs early since the shear flow formed in the spacing between the cylinder and the wall drives flow instabilities from the initial stage of freely falling. In order to consider the characteristics of transverse motion of the cylinder in the initial stage of freely falling, quantitative information about the cylinder motion variables such as the transverse force, trajectory and settling time has been investigate.

Effect of B-Cation Doping on Oxygen Vacancy Formation and Migration in LaBO3: A Density Functional Theory Study

  • Kwon, Hyunguk;Park, Jinwoo;Kim, Byung-Kook;Han, Jeong Woo
    • Journal of the Korean Ceramic Society
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    • v.52 no.5
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    • pp.331-337
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    • 2015
  • $LaBO_3$ (B = Cr, Mn, Fe, Co, and Ni) perovskites, the most common perovskite-type mixed ionic-electronic conductors (MIECs), are promising candidates for intermediate-temperature solid oxide fuel cell (IT-SOFC) cathodes. The catalytic activity on MIEC-based cathodes is closely related to the bulk ionic conductivity. Doping B-site cations with other metals may be one way to enhance the ionic conductivity, which would also be sensitively influenced by the chemical composition of the dopants. Here, using density functional theory (DFT) calculations, we quantitatively assess the activation energies of bulk oxide ion diffusion in $LaBO_3$ perovskites with a wide range of combinations of B-site cations by calculating the oxygen vacancy formation and migration energies. Our results show that bulk oxide ion diffusion dominantly depends on oxygen vacancy formation energy rather than on the migration energy. As a result, we suggest that the late transition metal-based perovskites have relatively low oxygen vacancy formation energies, and thereby exhibit low activation energy barriers. Our results will provide useful insight into the design of new cathode materials with better performance.

A Numerical Study on the Short-term Dispersion of Toxic Gaseous and Solid Pollutant in an Open Atmosphere : Chemical Species, Temperature, Relative Velocity (고-기상 독성오염물질 단기 대기확산에 관한 수치해석적 연구 : 화학종, 온도, 상대속도)

  • 나혜령;이은주;장동순;서영태
    • Journal of the Korean Society of Safety
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    • v.10 no.3
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    • pp.68-80
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    • 1995
  • A series of parametric calculations have been performed in order to investigate the short-term and short-range plume and puff behavior of toxic gaseous and solid pollutant dispersion in an open atmosphere. The simulation is made by the use of the computer program developed by this laboratory, in which a control-volume based finite-difference method is used together with the SIMPLEC algorithm for the resolution of the pressure-velocity coupling appeared In Wavier-Stokes equation. The Reynolds stresses are solved by the standard two-equation k-$\varepsilon$ model modified for buoyancy together with the RNG(Renormalization Group) k-$\varepsilon$ model. The major parameters considered in this calculation are pollutant gas density and temperature, the relative velocity of pollutants to that of the surrounding atmospheric air, and particulate size and density together with the height released. The flow field is typically characterized by the formation of a strong recirculation region for the case of the low density gases such as $CH_4$ and air due to the strong buoyancy, while the flow is simply declining pattern toward the downstream ground for the case of heavy molecule like the $CH_2C1_2$and $CCl_4$, even for the high temperature, $200^{\circ}C$. The effect of gas temperature and velocity on the flow field together with the particle trajectory are presented and discussed in detail. In general, the results are physically acceptable and consistent.

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Mechanical Properties of 2-D Silica-Silica Continuous Fiber-reinforced Ceramic-matrix Composite Fabricated by Sol-Gel Infiltration

  • Kim, Ha-Neul;Kim, Dong-Jun;Kang, Eul-Son;Kim, Do-Kyung
    • Korean Journal of Materials Research
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    • v.19 no.7
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    • pp.391-396
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    • 2009
  • 2-dimensional silica-silica Continuous Fiber-reinforced Ceramic.matrix Composites (CFCCs) were fabricated by a sol-gel infilitration method that has a changing processing condition, such as the repetitions of infilitration. In order to investigate the relationship between the processing condition and the mechanical properties of composites, the mechanical properties of specimens were measured by means of a 4-point flexural strength test while the evidence of strength degradation were microstructurally characterized. There seemed to be a minimum density value that existed at which the delamination between the fabrics would not occur. In the case that the density of silica CFCCs exceeded 1.55 g/$cm^3$, the flexural strength also exceeded approximately 18 MPa at least. By applying the Minimum Solid Area (MSA) analysis of the porous structure, the correlation between the relative density and the mechanical properties of composites will be discussed.

Growth and Characterization of P-type Doping for InAs Nanowires during Vapor-liquid-solid and Vapor-solid Growth Mechanism by MOCVD

  • Hwang, Jeongwoo;Kim, Myung Sang;Lee, Sang Jun;Shin, Jae Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.328.2-328.2
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    • 2014
  • Semiconductor nanowires (NWs) have attracted research interests due to the distinct physical properties that can lead to variousoptical and electrical applications. In this paper, we have grown InAs NWs viagold (Au)-assisted vapor-liquid-solid (VLS) and catalyst-free vapor-solid (VS) mechanisms and investigated on the p-type doping profile of the NWs. Metal-organic chemical vapor deposition (MOCVD) is used for the growth of the NWs. Trimethylindium (TMIn) and arsine (AsH3) were used for the precursor and diethyl zinc (DEZn) was used for the p-type doping source of the NWs. The effectiveness of p-type doping was confirmed by electrical measurement, showing an increase of the electron density with the DEZn flow. The structural properties of the InAs NWs were examined using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). In addition, we characterize atomic distribution of InAs NWs using energy-dispersive X-ray spectroscopy (EDX) analysis.

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A Closed Form Nonlinear Solution for Large Pure Bending Deformation of Solid Plate (고체 평판의 비선형 순수굽힘변형에 대한 수학적 정해)

  • Youngjoo Kwon
    • Journal of the Korean Society for Precision Engineering
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    • v.15 no.12
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    • pp.220-225
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    • 1998
  • 압축성 초탄성 평판의 순수굽힘에 대한 비선형 변형해석의 수학적 정해가 본 논문에 구해져 있다. 이차원 평면 변형도 상태가 해석을 위하여 가정되었으며, 비선형 순수굽힘 변형해석결과는 고전적인 선형 순수굽힘 변형해석결과와 비교되었다. 고전적인 선형굽힘 결과와는 다르게 비선형 순수굽힘 상태에서는 반경방향응력은 영이 아니며 또한 각방향응력도 선형 상태가 아닌 것으로 규명되었다.

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Physical Properties of Diopside-$Al_2O_3$ Solid Solution (Diopside-$Al_2O_3$ 고용체의 물성)

  • 안영필;김복희
    • Journal of the Korean Ceramic Society
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    • v.22 no.5
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    • pp.66-70
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    • 1985
  • This study was to investigate physical properties of the system $Ca(Mg_{1-x}Al_x) (Si_{2-x}Al_x)O_6$ by quenching method. This system $\chi$=0.1 to 0.3 had same crystal phase microstructure and similar properties. Bulk density microhardness thermal expansion coefficient and modulus of rupture of these solid solutions were 2.87~2.95g/cm3 850~900kg/$mm^2$, $7.5~7.8{\times}10^{-6}$/$^{\circ}C$ and 1950~1980kg/$cm^2$ respectively.

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Linear and network structures of polymer electrolyte based on phosphate and polyether copolymers

  • Kim, Jun-Young;Kim, Seong-Hun
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.232-235
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    • 1998
  • ion conducting polymers have been extensively investigated because of their potential application as an electrolyte in solid state batteries [1]. Among the polymer electrolytes, solid polymer electrolytes (SPEs) composed of ion conducting polymer and alkali metal salt have many advantages such as high ionic conductivity, high energy density and light weight. This made them suitable replacement for liquid electrolytes. (omitted)

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Altitude Effects on the Combustion of the Solid Fuel Ramjet

  • Lee, Tae-Ho
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.476-479
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    • 2008
  • The combustion efficiency of the solid fuel ramjet is affected by the inlet air temperature. And this inlet air temperature is dependent on the flight Mach number and the environment air temperature. If the flight altitude is changeable, the inlet air temperature and the air density also vary. The performance efficiency is investigated with this variables related to the combustion efficiency.

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Degradation of All-Solid-State Lithium-Sulfur Batteries with PEO-Based Composite Electrolyte

  • Lee, Jongkwan;Heo, Kookjin;Song, Young-Woong;Hwang, Dahee;Kim, Min-Young;Jeong, Hyejeong;Shin, Dong-Chan;Lim, Jinsub
    • Journal of Electrochemical Science and Technology
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    • v.13 no.2
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    • pp.199-207
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    • 2022
  • Lithium-sulfur batteries (LSBs) have emerged as a promising alternative to lithium-ion batteries (LIBs) owing to their high energy density and economic viability. In addition, all-solid-state LSBs, which use solid-state electrolytes, have been proposed to overcome the polysulfide shuttle effect while improving safety. However, the high interfacial resistance and poor ionic conductivity exhibited by the electrode and solid-state electrolytes, respectively, are significant challenges in the development of these LSBs. Herein, we apply a poly (ethylene oxide) (PEO)-based composite solid-state electrolyte with oxide Li7La3Zr2O12 (LLZO) solid-state electrolyte in an all-solid-state LSB to overcome these challenges. We use an electrochemical method to evaluate the degradation of the all-solid-state LSB in accordance with the carbon content and loading weight within the cathode. The all-solid-state LSB, with sulfur-carbon content in a ratio of 3:3, exhibited a high initial discharge capacity (1386 mAh g-1), poor C-rate performance, and capacity retention of less than 50%. The all-solid-state LSB with a high loading weight exhibited a poor overall electrochemical performance. The factors influencing the electrochemical performance degradation were revealed through systematic analysis.