• 제목/요약/키워드: silicon content

검색결과 358건 처리시간 0.021초

냉매와 습공기가 교차하는 2중관에서 전열계수 예측을 위한 연구 (The study on the estimation of heat transfer coefficient through the counterflow concentric tube using refrigerant and moisture air)

  • 조권희
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제23권5호
    • /
    • pp.687-694
    • /
    • 1999
  • This study was conducted to develop new drying process for automatic control and marine engi-neering system. Air-water tests were carried out to investigate dryer performance. The dispersed flow in he dryer test apparatuses was also simulated by using a numerical code which solves the Dittus-Boelter equation for continuous liquid phase and the Reynolds equation of droplet motion for continuous liquid phase and the Reynolds equation of droplet motion for dispersed phase to predict droplet removal efficiency. Proper conditions for dehumidification were optimized by response ambient conditions. When the selected indexes were constrained in the range of 85-98% moisture content above $15^{\circ}$ and more than mass flow rates of moist air 750kg/h. The numerical results were compared with the experimental data pertaining to the removal effi-ciency at chamber stage and overall pressure drop along concentric tubes Good agreement was obtained as for the efficiency while relatively poor agreement was obtained for the relative humidity. The results also showed that the efficiency depended strongly on the relative humidity at the inlet condition which indicated the importance of estimating the heat exchanger length. Effects of some design parameters in both removal efficiency and breakthrough onset condition are discussed.

  • PDF

실리콘 기판에 증착된 질소도핑 DLC 박막의 특성 (Characteristic of Nitrogen doped Diamond-Like Carbon film on the Silicon substrates)

  • 반 카오;김태현;김혜성;신동철;김태규
    • 한국기계가공학회지
    • /
    • 제12권2호
    • /
    • pp.34-40
    • /
    • 2013
  • Various depositional conditions, such as substrate, pressure, deposition time, temperature of substrate, power and gas composition, have mainly been studied to attain DLC films using RF sputtering system up to the current. In this study, the $N_2/Ar/CH_4$ gas mixture factored on characteristics of DLC deposited film such as structure, hardness, electrical property were investigated. The concentration of the $N_2$ gas in the sputtering gas may be a significant effect on the growth rate of the doped films, because nitrogen ions react not only with the carbon atoms on the target but also with $C_xH_y$ ions in the plasma on the substrate surface. It was seen from this experimental that the resistance of deposited film is decreased, and the relative intensity ratio of D to G peak is increased as nitrogen content of film deposition is increased.

Preparation and Physical Properties of Silicone Hydrogel Ophthalmic Lens Containing Hydrophilic Monomer

  • Lee, Min-Jae;Sung, A-Young
    • 대한화학회지
    • /
    • 제60권4호
    • /
    • pp.261-266
    • /
    • 2016
  • The major physical characteristics of macromolecules used in silicone hydrogel ophthalmic lenses include optical transmittance, oxygen permeability, water content, and refractive index. For the preparation of highly functional silicone hydrogel lens materials, two silicone monomers were used in the presence of 2-hydroxyethyl methacrylate (HEMA) and hydroxypropyl methacrylate (HPMA). The samples containing HEMA and HPMA had oxygen transmissibility (Dk) values in the range of 73.38–50.98 × 10-11 (cm2/s) (mLO2/mL×mmHg) and 71.94–42.80 × 10-11 (cm2/s) (mLO2/mL×mmHg), respectively. Furthermore, the water contents of samples containing HEMA and HPMA were in the range of 32.73–34.67% and 31.94–33.74%, respectively, and the refractive indices were in the range of 1.4348–1.4364 and 1.4385–1.4407, respectively. Thus, silicone monomers containing HEMA and HPMA are expected to be useful for fabricating high-oxygen-permeability silicon hydrogel ophthalmic lenses.

하이드로퀴논 전해질 중간체에 의한 염료-수화젤 기반 태양전지 효율 향상 (Improvement of Dye-Hydrogel Based Photovoltaics via Hydroquinone Electrolyte Mediators)

  • 구형준
    • 한국수소및신에너지학회논문집
    • /
    • 제27권5호
    • /
    • pp.540-546
    • /
    • 2016
  • Besides high-efficient photovoltaics based on silicon, polymers, dye-sensitization and hybrid perovskite materials, biomimetic solar cells inspired by a leaf in nature has also been actively studied. As one example, a hydrogel based photovoltaics (HGPV) is a low-cost, environmentally friendly device and requires easy fabrication process. In this paper, the effect of hydroquinone additive on the performance of the HGPV is discussed. The photocurrent increases ~14 times upon the addition of hydroquinone into the agarose hydrogel medium. The photocurrent increase is maximum at the optimum dye concentration, while the photovoltage is barely affected by the dye concentration. The effect of the agarose content in the hydrogel and the types of dyes on the photocurrent is also investigated. Finally, it is shown that the photovoltaic performance of HGPV with hydroquinone can be drastically improved when $TiO_2$ film is deposited on the anode electrode.

수광층의 카바이드 함량 변화에 따른 실리콘 이종접합 태양전지 특성 변화 (Enhancing Solar Cell Properties of Heterojunction Solar Cell in Amorphous Silicon Carbide)

  • 김현성;김상호;이영석;정준희;김용준;다오빈 아이;이준신
    • 한국전기전자재료학회논문지
    • /
    • 제29권6호
    • /
    • pp.376-379
    • /
    • 2016
  • In this paper, the efficiency improvement of the heterojunction with intrinsic thin layer (HIT) solar cells is obtained by optimization process of p-type a-SiC:H as emitter. The optoelectronic of p-type a-SiC:H layers including the optical band-gap and conductivity under the methane gas content variation is conducted in detail. A significant increase in the Jsc by $1mA/cm^2$ and Voc by 30 mV are attributed to enhanced photon-absorption due to broader band-gap of p-a-SiC:H and reduced band-offsets at p-side interface, respectively of HIT solar cells.

주조접합법에 의한 TaC 직접합성에 관한 연구 (A Study on the Direct Synthesis of TaC by Cast-bonding)

  • 박홍일;이성열
    • 한국주조공학회지
    • /
    • 제17권4호
    • /
    • pp.371-378
    • /
    • 1997
  • The study for direct synthesis of TaC carbide which was a reaction product of tantalum and carbon in the cast iron was performed. Cast iron which has hypo-eutectic composition was cast bonded in the metal mold with tantalum thin sheet of thickness of $100{\mu}m$. The contents of carbon and silicon of cast iron matrix was controlled to have constant carbon equivalent of 3.6. The chracteristics of microstructure and the formation mechanism of TaC carbide in the interfacial reaction layer in the cast iron/tantalum thin sheet heat treated isothermally at $950^{\circ}C$ for various time were examined. TaC carbide reaction layer was grown to the dendritic morphology in the cast iron/tantalum thin sheet interface by the isothermal heat treatment. The composition of TaC carbide was 48.5 at.% $Ti{\sim}48.6$ at.% C-2.8 at.% Fe. The hardness of reaction layer was MHV $1100{\sim}1200$. The thickness of reaction layer linearly increased with increasing the total content of carbon in the cast iron matrix and isothermal heat treating time. The growth constant for TaC reaction layer was proportional to the log[C] of the matrix. The formation mechanism of TaC reaction layer at the interface of cast iron/tantalum thin sheet was proved to be the interfacial reaction.

  • PDF

Bi 함량에 따른 $SrBi_{2x}Ta_2O_9$ 박막의 전기적 특성 (Electrical properties of S$SrBi_{2x}Ta_2O_9$ thin films with Bi content)

  • 연대중;권용욱;박주동;오태성
    • 한국진공학회지
    • /
    • 제8권3A호
    • /
    • pp.224-230
    • /
    • 1999
  • $SrBi_{2x}Ta_2O_9$ (SBT) thin films were prepared on platinized silicon substrates by MOD process, and their ferroelectric and leakage current characteristics were investigated. The grain size of the MOD derived SBT films increased with increasing the BI/Ta mole ration. Although the SBT films with x of 0.8~1.2 were composed of the equiaxed grains, the elongated grains were also observed for the SBT films with x of 1.4 and 1.6. The SBT film with x of 1.2 exhibited the optimum ferroelectric properties of 2PR : 9.79 $\muC/\textrm{cm}^2$ and Ec : 24.2kV/cm at applied voltage of 5V. The leakage current density of the SBT films increased with increasing the BI/Ta mole ratio. With post annealing process, 2Pr and $E_c$of the SBT film with x of 1.2 increases 11.3 $\muC/\textrm{cm}^2$ and 39.6kV/cm, respectively. decrement of the leakage current density by post annealing process increased remarkably with increasing the Bi/ta mole ratio, and the SBT film with x=1.6 exhibited the lowest leakage current density after post annealing process.

  • PDF

High Performance Materials for Ophthalmic Hydrogel Lens Containing Nanoparticles

  • Kim, Duck-Hyun;Sung, A-Young
    • 통합자연과학논문집
    • /
    • 제9권1호
    • /
    • pp.16-22
    • /
    • 2016
  • The optical and physical and characteristics of hydrogel ophthalmic lens polymerized with addition of 2,6-difluoropyridine, SiPc(silicon 2,9,16,23-tetra-tert-butyl-29H31H-phthalocyanine dihydroxide) and nanodiamond in the basic hydrogel material were evaluated. In particular, the utility of 2,6-difluoropyridine, SiPc and nanodiamond as a hydrogel ophthalmic lens material was investigated. 2,6-difluoropyridine, SiPc and nanodiamond were used as additives. And also, 2-hydroxyethyl methacrylate, acrylic acid, methyl methacrylate and a cross-linker EGDMA were copolymerized in the presence of AIBN as an initiator. The refractive index of 1.4348~1.4361, water content of 33.30~34.02%, UV-B transmittance of 4.77~67.50%, UV-A transmittance of 1.45~89.19% and visible transmittance of 32.12~92.21% were obtained. The results of hydrogel lens containing 2,6-difluoropyridine (add 5%) showed antibiosis for staphylococcus aureus. The produced copolymer is suitable for hydrogel soft ophthalmic lenses with antibiotic and anti-UV effect.

알루미늄 함량에 따른 알루미늄 주철의 내산화성에 관한 연구 (A Study on the Oxidation Resistance of Aluminum Cast Iron by Aluminum Content)

  • 김동혁
    • 한국주조공학회지
    • /
    • 제40권6호
    • /
    • pp.135-145
    • /
    • 2020
  • Aluminum cast iron has excellent oxidation resistance, sulfurization resistance, and corrosion resistance. However, the ductility at room temperature is insufficient, and at temperatures above 600?, the strength drops sharply and practicality is limited. In the case of heat-resistant cast iron, high-temperature materials containing Cr and Ni account for 30 to 50% or more. However, these high-temperature materials are expensive. Aluminum heat-resistant cast iron is considered as a substitute for expensive heat-resistant materials. Oxidation due to the aging temperature and holding time conditions increases more in 0 wt.% Al-cast iron than in 2 and 4 wt.% Al-cast iron according to oxidized weight and gravimetric oxide layer thickness measurements. As a result of observing the cross-section of the oxide layer, it was found to contain 0 wt.% of Al-cast iron silicon oxide-containing SiO2 or Fe2SiO4 oxide film. In cast iron containing aluminum, the thickness of the internal oxide layer due to aluminum increases as the aging temperature and retention time increase, and the amount of the iron oxide layer generated on the surface decreases.

Preparation and Characteristics of Core-Shell Structure with Nano Si/Graphite Nanosheets Hybrid Layers Coated on Spherical Natural Graphite as Anode Material for Lithium-ion Batteries

  • Kwon, Hae-Jun;Son, Jong-In;Lee, Sung-Man
    • Journal of Electrochemical Science and Technology
    • /
    • 제12권1호
    • /
    • pp.74-81
    • /
    • 2021
  • Silicon (Si) is recognized as a promising anode material for high-energy-density lithium-ion batteries. However, under a condition of electrode comparable to commercial graphite anodes with low binder content and a high electrode density, the practical use of Si is limited due to the huge volume change associated with Si-Li alloying/de-alloying. Here, we report a novel core-shell composite, having a reversible capacity of ~ 500 mAh g-1, by forming a shell composed of a mixture of nano-Si, graphite nanosheets and a pitch carbon on a spherical natural graphite particle. The electrochemical measurements are performed using electrodes with 2 wt % styrene butadiene rubber (SBR) and 2 wt.% carboxymethyl cellulose (CMC) binder in an electrode density of ~ 1.6 g cm-3. The core-shell composites having the reversible capacity of 478 mAh g-1 shows the outstanding capacity retention of 99% after 100 cycles with the initial coulombic efficiency of 90%. The heterostructure of core-shell composites appears to be very effective in buffering the volume change of Si during cycling.