• Title/Summary/Keyword: rhodamine 6G

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Color and COD Removal of Rhodamine B Using Ozone, Photocatalyst and Ozone-Complex Process (오존, 광촉매 및 오존-복합 공정을 이용한 Rhodamine B의 색도와 COD 제거)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.6
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    • pp.662-669
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    • 2007
  • The effect of advanced oxidation processes such as $O_3$, $UV/TiO_2$, $O_3/UV$ and $O_3/UV/TiO_2$ on decolorization and COD removal of Rhodamine B(RhB) wastewater were considered. The results showed that the higher the $O_3$ concentration was, the higher the decolorization observed and the optimum $TiO_2$ dosage was 0.4 g/L in $UV/TiO_2$ and $O_3/UV/TiO_2$ process. $O_3/UV$ process showed the higher initial decolorization rate constant and the shorter termination time for decolorization than those of the $O_3$ process. The decolorization rate constants in various systems followed the order of $O_3/UV/TiO_2>O_3/UV>O_3{\gg}UV/TiO_2$. The decolorization rate of the RhB solution in every processes was more rapid than the mineralization rate identified by COD removal. The latter took longer time for further oxidation. The COD removal rate constants in four systems followed the order of $O_3/UV/TiO_2>O_3/UV>UV/TiO_2{\geqq}O_3$. Among four processes, combined photocatalysis and ozonation$(O_3/UV/TiO_2)$ was the most prospective process for removing color and COD such as dye wastewater.

Assessing the Influence Radius of a Water Treatment System Installed in a Reservoir Using Tracer Experiment and 3D Numerical Simulation (추적자 실험 및 3차원 수치모의를 이용한 저수지 수처리 장치의 영향반경 평가)

  • Park, Hyung Seok;Lee, Eun Ju;Ji, Hyun Seo;Choi, Sun Hwa;Chun, Se Woong
    • Journal of Korean Society of Water Science and Technology
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    • v.26 no.6
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    • pp.3-12
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    • 2018
  • The objective of this study was to evaluate the radius of influence of effluent of water treatment system developed for the purpose of improvement of reservoir water quality using fluorescent dye (Rhodamine-WT) tracer experiment and 3-D numerical model. The tracer experiment was carried out in a medium-sized agricultural reservoir with a storage capacity of $227,000m^3$ and an average depth of 1.6 m. A guideline with a total length of 160 m was installed at intervals of 10 m in the horizontal direction from the discharge part, and a Rhodamine measurement sensor (YSI 6130, measurement range $0-200{\mu}g/L$) was used to measure concentration changes in time, distance, and depth. Experimental design was established in advance through Jet theory and the diffusion process was simulated using ELCOM, a three dimensional hydraulic dynamics model. As a result of the study, the direct effect radius of the jet emitted from the applied water treatment system was about 50-70 m, and the radius of physical effect by the advection diffusion was judged to be 100-120 m. The numerical simulations of effluent advection-diffusion of the water treatment system using ELCOM showed very similar results to those of the impact radius analysis using the tracer experiment and jet flow empirical equations. The results provide valuable information on the spatial extent of the water quality improvement devices installed in the reservoir and the facility layout design.

Rotational Reorientation Dynamics of Rhodamine 6G molecule in $PVP/C_2H_5OH$ and $PVP/C_2H_5OH$ Mixtures ($PVP/C_2H_5OH$$PEG/H_2O$ 혼합 용액에 위치한 rhokamine 6G 분자의 회전 재배열 운동)

  • Ko, Dong-Seob;Jeon, Kye-Jin;Eom, Hyo-Soon;nam, Gi-Jung;Kim, Hyun-Soo;Kim, Ung
    • Korean Journal of Optics and Photonics
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    • v.6 no.1
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    • pp.45-49
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    • 1995
  • 시간 상관 단일 광자 계수법을 사용하여 PVP/C/sub 2/H/sub 5/OH와 PEG/H/sub 2/O 혼합 용매에 위치한 rhodemine 6G 분자의 회전 재배열 시간을 측정하였다. 주어진 온도에서 혼합비를 변화시키면서 측정한 결과, PEG/H/sub 2/O와 PVP/C/sub2/H/sub 5/OH에서 각각 회전 이완 시간이 혼합액의 점성도에 선형적으로 비례하지 않는 것으로 관측되었다. 고분자 주의에 cluster가 형성된다는 관점에서 혼합비에 따른 회전 이완 시간의 변화를 설명하였다.

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Preparation and characterization of g-C3N4/NaTaO3 composite and their photocatalytic activity under simulated solar light (g-C3N4/NaTaO3 복합체의 제조 및 태양광 조사 하에서의 광촉매 특성 평가)

  • Park, Ji-Su;Kim, Tae-Ho;Jo, Yong-Hyeon;Lee, Su-Wan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.264-265
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    • 2014
  • This Paper reports the photocatalytic activity of $g-C_3N_4/NaTaO_3$ hybrid composite photocatalysts synthesized by ball-mill method. The $g-C_3N_4$ and $NaTaO_3$ were individually prepared by Solid state reaction and microwave hydrothermal process, respectively. The $g-C_3N_4/NaTaO_3$ composite showed the enhanced photocatalytic activity for degradation of rhodamine B dye (Rh. B) under simulated solar light irradiation. The results revealed that the band-gap energy absorption edge of hybrid composite samples was shifted to a longer wavelength as compared to $NaTaO_3$ and the 50 wt% $g-C_3N_4/NaTaO_3$ hybrid composite exhibited the highest percentage (99.6 %) of degradation of Rh. B and the highest reaction rate constant ($0.013min^{-1}$) in 4 h which could be attributed to the enhanced absorption of the hybrid composite photocatalyst in the UV-Vis region. Hence, these results suggest that the $g-C_3N_4/NaTaO_3$ hybrid composite exhibits enhanced photocatalytic activity for the degradation of rhodamine B under simulated solar light irradiation in comparison to the commercial $NaTaO_3$.

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Synthesis of Size-Controlled Urchin Ag Nanoparticles and Surfcace Enhanced Raman Spectroscopy (SERS) (크기가 조절된 성게 모양의 실버나노 입자의 합성과 표면 라만 증강)

  • Lee, Young Wook;Shin, Tae Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.6
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    • pp.454-457
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    • 2019
  • Controlling the shape of Ag nanoparticles (NPs) is very difficult. In the present work, urchin Ag NPs with different sizes and pod length control have been synthesized successfully in high yield by the concentration of a reducing agent. Unique Ag NPs were observed by TEM and SEM. These nanocrystals exhibit tunable surface plasmon resonance properties from the visible to near-infrared regions. They were applied to surface-enhanced Raman scattering (SERS) substrates using rhodamine 6G (R6G), benzenethiol (BT), and 4-amino benznethiol (4-ABT) molecules. The enhanced local field effect due to the sharp pod length, size, and surface plasmon of the urchin Ag NPs resulted in enhanced SERS properties and can serve as high-sensitivity substrates for SERS measurements.

Development of Homemade Dye Laser (색소레이저의 국산화 개발에 관한 연구)

  • 오철한;박덕규;이성만
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.34 no.2
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    • pp.56-62
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    • 1985
  • It is desirable to establish a fundamental basis of dye laser technology in korea. Except the special wavelength mirrors, all parts of the dye laser were assembled using domestically available materials and the interior technology. The characteristics of pumping light of Ar discharge tube, fluorescence light of Rhodamine 6G and output pulses of the homemade dye laser were investigated by means of CRO and spectroscopic analysis.

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Surface-enhanced Raman Scattering on Chemically Prepared Silver Film for Trace Analysis

  • Boo, Doo-Wan;Kim, Kwan;Kim, Myung-Soo
    • Bulletin of the Korean Chemical Society
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    • v.7 no.1
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    • pp.55-58
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    • 1986
  • Analytical capability of surface-enhanced Raman scattering has been evaluated. Silver films prepared by homogeneous chemical reduction were used as the substrate. Detection limits for p-nitrobenzoic acid, thiophenol and rhodamine 6G were around $10{\sim}100\;pg$.

Characteristics of Biosurfactant Produced by Pseudomonas sp. G314 (Pseudomonas sp. G314가 생산하는 생물 계면활성제의 특성)

  • Shim, So-Hee;Park, Kyeong-Ryang
    • Journal of Life Science
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    • v.22 no.2
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    • pp.239-244
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    • 2012
  • The purpose of this paper is to analyze the characteristics and chemical components of biosurfactant produced by Pseudomonas sp. G314. Pseudomonas sp. G314 was isolated from soil samples which were contaminated with oil in Daejon area. As such, it produced quality biosurfactant [23]. One type of biosurfactant was kept in a refrigerator, whereas another type of biosurfactant was kept in room temperature. The surface tension activities were then compared. As a result, the biosurfactant from Pseudomonas sp. G314 that was kept at room temperature was stable for 10 days, showing 26.2 dyne/cm of surface tension activity. This result was found to be similar to that of the refrigerator storage. The surface tension of batch culture was 25 dyne/cm, but the culture in the 5 l fermentor was 27 dyne/cm. Therefore, it can be suggested that the large-scale culture is feasible via the fermentor. Biosurfactant from Pseudomonas sp. G314 was estimated to be a kind of glycolipid because it dissolved in acetone and methanol much better than in benzene and toluene [23]. A spot was detected through the elution of silica gel column and the spread of TLC, and the Rf value was 0.58. This spot has a positive reaction with Bail's reagent and rhodamine 6G. Hence, we can conclude that biosurfactant from Pseudomons sp. G314 was a glycolipid containing carbohydrate and lipid.

Continuous pulse width variable quenched dye laser (펄스폭 연속가변 Quenched Dye Laser)

  • 황선우;이영주;김성훈;최종운
    • Korean Journal of Optics and Photonics
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    • v.10 no.2
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    • pp.152-156
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    • 1999
  • We have developed the pulse-width variable Quenched Dye Laser (QDL). QDL consisted of the dye cell of 5 mm length containing a $2.5{\times}10^{-3}$[mol/l] solution of Rhodamine 6G and the cylindrical lens focal length of 150 mm and quenching mirror. QDL system was pumped by s XeCl excimer laser with 150 mJ pulse energy in a 20 ns pulse at 1 Hz repetition rate. Pulse-width of QDL was measured by a noncollinear intensity autocorrelator. The focused thckness was measured by changing the position of the focusing cylindrical lens. Pulse-width of QDL as a function of the focused thickness (273.0${\mu}{\textrm}{m}$~845.0${\mu}{\textrm}{m}$) varied continuously from 86 ps to 201 ps.

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SERS Immunoassay Using Microcontact Printing for Application of Sensitive Biosensors

  • Hong, Won-Jin;Seo, Hyeong-Kuyn;Jung, Young-Mee
    • Bulletin of the Korean Chemical Society
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    • v.32 no.12
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    • pp.4281-4285
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    • 2011
  • We introduced a promising patterned substrate by using a microcontact printing method that can be used for SERS immunoassays based on antigen-antibody binding. SERS spectrum of the Raman reporter with antibody, which is rhodamine 6G (R6G) adsorbed on colloidal gold nanoparticles, was observed only for the surfaces in which prostate-specific antigen (PSA) is present on the substrate that is attached to an immobilized layer of antibody on the gold nanoparticles layer of the patterned substrate. Raman mapping images clearly showed that the antibodies on the Raman reporter were successfully and selectively conjugated with the antigen on the patterned substrate. This method could be potentially extended to multi-protein detections and ultrasensitive biosensors.