Preparation and characterization of g-C3N4/NaTaO3 composite and their photocatalytic activity under simulated solar light

g-C3N4/NaTaO3 복합체의 제조 및 태양광 조사 하에서의 광촉매 특성 평가

  • 박지수 (선문대학교 나노화학과) ;
  • 김태호 (선문대학교 정보디스플레이학과) ;
  • 조용현 (선문대학교 재료금속공학과) ;
  • 이수완 (선문대학교 환경생명화학공학과)
  • Published : 2014.11.20

Abstract

This Paper reports the photocatalytic activity of $g-C_3N_4/NaTaO_3$ hybrid composite photocatalysts synthesized by ball-mill method. The $g-C_3N_4$ and $NaTaO_3$ were individually prepared by Solid state reaction and microwave hydrothermal process, respectively. The $g-C_3N_4/NaTaO_3$ composite showed the enhanced photocatalytic activity for degradation of rhodamine B dye (Rh. B) under simulated solar light irradiation. The results revealed that the band-gap energy absorption edge of hybrid composite samples was shifted to a longer wavelength as compared to $NaTaO_3$ and the 50 wt% $g-C_3N_4/NaTaO_3$ hybrid composite exhibited the highest percentage (99.6 %) of degradation of Rh. B and the highest reaction rate constant ($0.013min^{-1}$) in 4 h which could be attributed to the enhanced absorption of the hybrid composite photocatalyst in the UV-Vis region. Hence, these results suggest that the $g-C_3N_4/NaTaO_3$ hybrid composite exhibits enhanced photocatalytic activity for the degradation of rhodamine B under simulated solar light irradiation in comparison to the commercial $NaTaO_3$.

Keywords