• Title/Summary/Keyword: reducing agent

Search Result 1,136, Processing Time 0.025 seconds

A Facile Synthetic Method of Silver Nanoparticles with a Continuous Size Range from sub-10 nm to 40 nm

  • Piao, Longhai;Lee, Kyung-Hoon;Min, Byoung-Koun;Kim, Woong;Do, Young-Rag;Yoon, Sung-Ho
    • Bulletin of the Korean Chemical Society
    • /
    • v.32 no.1
    • /
    • pp.117-121
    • /
    • 2011
  • Size-controlled Ag nanoparticles (NPs) were prepared from the decomposition of Ag(I) carboxylates using ethanolamine derivatives as a reducing agent without an additional stabilizing agent. The size of the Ag NPs with a narrow size distribution (sub-10 nm to ca. 40 nm) was controlled precisely by varying the processing parameters, such as the type of reducing agent and the chain length of the carboxylate in the Ag(I) carboxylate. The optical properties, surface composition and crystallinity of the Ag NPs were characterized by ultraviolet-visible spectroscopy, gas chromatography-mass spectrometry, thermal gravimetric analysis, transmission electron microscopy and X-ray diffraction.

Reward Shaping for a Reinforcement Learning Method-Based Navigation Framework

  • Roland, Cubahiro;Choi, Donggyu;Jang, Jongwook
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
    • /
    • 2022.10a
    • /
    • pp.9-11
    • /
    • 2022
  • Applying Reinforcement Learning in everyday applications and varied environments has proved the potential of the of the field and revealed pitfalls along the way. In robotics, a learning agent takes over gradually the control of a robot by abstracting the navigation model of the robot with its inputs and outputs, thus reducing the human intervention. The challenge for the agent is how to implement a feedback function that facilitates the learning process of an MDP problem in an environment while reducing the time of convergence for the method. In this paper we will implement a reward shaping system avoiding sparse rewards which gives fewer data for the learning agent in a ROS environment. Reward shaping prioritizes behaviours that brings the robot closer to the goal by giving intermediate rewards and helps the algorithm converge quickly. We will use a pseudocode implementation as an illustration of the method.

  • PDF

Effect of Reducing Agents on Bifidobacterium Fermentation of Saccharified Rice Solution (환원제 첨가가 쌀당화액의 Bifidobacterium발효에 미치는 영향)

  • 이주연;목철균;박종현;장학길
    • Microbiology and Biotechnology Letters
    • /
    • v.27 no.3
    • /
    • pp.230-235
    • /
    • 1999
  • This study was intended to develop a new rice product by the fermentation of saccharified rice solution using Bifidobacterium and to select an appropriate reducing agent to provide the anaerobic condition for the growth of Bifidobacterium during fermentation. The enhancement of the growth of Bifidobacterium in saccharified rice solution was achieved by the treatment of reducing agents such as ascorbic acid and cysteine. The physical and chemical properties of the fermented product were evaluated, and the effect of the reducing agents were compared between ascorbic acid and cysteine. The fermented product with the addition of ascorbic acid shows the lower pH and the higher titratable acidity comparing the product with the addition of cysteine. This indicated that ascorbic acid was more appropriate reducing agent than cysteine for the fermentation of the saccharified rice solution. The number of viable Bifidobacterium in the fermented product with the addition of ascorbic acid(2.2$\times$108~3.4$\times$108CFU/ml) was greater than that with the addition of cysteine (8$\times$107~2.8$\times$108CFU/ml). Ascorbic acid supplement also contributed better sensory properties, such as flavor, taste and overall acceptibility than cysteine supplement did.

  • PDF

Analysis of aqueous environment iron dissolution in different conditions (조건의 변화에 따른 수중 환경 내에서의 철 용해 분석)

  • Bae, Yeun-Ook;Min, Jee-Eun;Park, Jae-Woo
    • 한국방재학회:학술대회논문집
    • /
    • 2008.02a
    • /
    • pp.807-810
    • /
    • 2008
  • Permeable reactive barriers containing Zero-valent iron (ZVI) are used to purify ground-water contaminants. One of the representative contaminant is trichloroethylene (TCE). ZVI can act as a reducing agent of TCE. When ZVI is oxidized to Ferric iron, TCE reduced to Ethene, which is non-harmful matter. As a ZVI becomes ferric iron, the reducing effect decreases and iron becomes unavailable. So, constant reduction of TCE requires the regular supply of reducing agent. So, we use Iron-reducing bacteria(IRB) to extend the TCE degrading ability. We perform three experiment DI water, DI water with medium, and DI water with medium and IRB. By the experiment we try to found the dissolve ability.

  • PDF

Effect of Expanding Admixture and Shrinkage Reducing Agent on the Shrinkage Reducing Properties of Ultra High Performance Cement Mortar (팽창재 및 수축저감제가 초고성능 시멘트 모르타르의 수축특성에 미치는 영향)

  • Han, Dong-Yeop;Yu, Myoung-Youl;Lee, Hyun-Soo
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2006.05b
    • /
    • pp.61-64
    • /
    • 2006
  • Comparing with traditional high performance concrete, ultra high performance concrete (UHPC) has the property of high-tenacity. However, drying shrinkage and autogenous shrinkage can be arisen as the major defect to UHPC. In this study, therefore, it was tested to reduce drying shrinkage and autogeneous shrinkage by adding expanding admixture (EA) and shrinkage reducing agent (SRA). As a result, for a case drying shrinkage, the shrinkage was decreased by 94% when EA was exchanged, and it was decreased by 64% when SRA was added. For the case of autogenous shrinkage, the mortar was expanded at early age and the shrinkage was decreased by 87% when EA was exchanged, and the shrinkage was decreased by 70% when SRA was added.

  • PDF

Influences of Fly ash on the Properties of High Flowing Concrete Using Segregation-Reducing Type Superplasticizer (분리저감형 유동화제를 이용하는 고유동 콘크리트의 특성에 미치는 플라이애쉬의 영향)

  • 윤길봉;전충근;손성운;김성수;한천구
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2000.10a
    • /
    • pp.661-664
    • /
    • 2000
  • It is known that high flowing concrete performs much higher fluidity, segregation resistibility and better placeability than normal concrete. However, it is hard to apply high fluidity concrete in field because of high manufacturing cost. Therefore, we intend to investigate the validity of segregation reducing type superplasticizer which is made by combining 0.61 of viscosity agent and 0.022 of AE agent for 1 of superplasticizer. Test are conducted on high flowing concrete using fly ash by applying segregation reducing type superplasticizer. According to experimental results, As contents of fly ash increase, fluidity, segregation resistibility and placeability shows favorable results. And also compressive strength at early age shows to be retarded, while it gains high strength at later age.

  • PDF

Synthesis of Magnetic Nanoparticles Using Magnolia kobus Leaf Extract (목련잎 추출액을 이용한 자성 나노입자의 합성)

  • Song, Jae-Yong;Byun, Tae-Gang;Kim, Beom-Soo
    • KSBB Journal
    • /
    • v.27 no.3
    • /
    • pp.157-160
    • /
    • 2012
  • When iron oxide magnetic nanoparticles were synthesized by co-precipitation method using aqueous ammonia as reducing agent, the synthesized particles were aggregated and thus precipitation occurred. Using Magnolia kobus leaf extract as reducing agent, spherical nanoparticles of 50~200 nm were synthesized with low yield. By using both Magnolia kobus leaf extract and aqueous ammonia as reducing and stabilizing agents, smaller nanoparticles of 40~120 nm could be synthesized with various shapes. The synthesized magnetic nanoparticles were characterized with field emission transmission electron microscopy (FE-TEM) and scanning electron microscopy (SEM). TEM and SEM images showed that the magnetic nanoparticles are a mixture of triangles, tetragons, rods and spherical structures.

The Mortar Properties of Portland Cements Blended with Modified Coal Ashes (가공된 석탄재를 사용한 석탄재혼합시멘트의 모르터 특성)

  • 홍원표;노재성;조헌영;정수영;김무한
    • Journal of the Korean Ceramic Society
    • /
    • v.27 no.7
    • /
    • pp.833-840
    • /
    • 1990
  • For the development of multi-functional materials which has water reducing power, air entraining power and waterproofing power as well as blending additive in cement mortar the coal ash was modified with asphalt-stearic acid or asphalt-boiled oil mixtures by mechanical treatment. And the physical properties of cement mortar blended with modified coal ashes were compared with those of the water-tightness-cement mortar and the ordinary-portland-cement mortar added with AE.water reducing agent. The mortar of coalash-blend-cement modified with asphalt-stearic mixture was increased acid about 20% in initial strengths and decreased about 20% in water absorption ratio than those of ordinary coalash-blend-cement. The mortar of coalash-blend-cement modified with asphalt-bolied oil mixture was similar to the cement mortar added with AE.water reducing agent in water reduction ratio, air entraining conents and the initial strengths, also was similar to the water-tightness-cement mortar in water absorption and water permeability ratios.

  • PDF

A Study on the Shrinkage Reducing Properties of Steel Fiber Reinforced Ultra High Strength Cement Mortar (강섬유보강 초고강도 시멘트 모르터의 수축저감에 관한 연구)

  • Han Dong-Yeop;Heo Young-Sun;Pei Chang-Chun;Han Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2005.11a
    • /
    • pp.67-70
    • /
    • 2005
  • Ultra high strength concrete, nowadays, has been widely applied to construction of high-rise building. To improve ductility and mechanical properties, steel fiber is employed in UHSC. This study investigates practical application of expansive additives(EA) and shrinkage reducing agent(SRA), in order to secure volumetric stability and improved mechanical properties, such as autogenous shrinkage and dry shrinkage of steel-fiber-reinforced-ultra-high-strength-comet-mortar(FHSM). According to the test, individual addition of steel fiber does not affect shrinkage reduction, as expected. However FHSM, with combined addition of 5$\%$ of EA and 1$\%$ of SRA decreased 60$\%$ of autogenous shrinkage. It is considered that Proper combination of EA and SRA can secure the shrinkage resistance of FHSM.

  • PDF

A Study on the Development of Drying Shrinkage-Reducing Superplasticizer (건조수축 저감형 유동화제의 개발에 관한 연구)

  • Shin Jae-Kyung;Oh Chi-Hyun;Choi Jin-Man;Lee Seong-Yeun;Han Min-Cheol;Han Cheon-Goo
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2005.05b
    • /
    • pp.501-504
    • /
    • 2005
  • This paper discusses the development of drying shrinkage reducing type superplasticizer(DSRS) by varying dosage of polycarboxylic based superplasticizer, liquid type expansive admixture and antifoaming agent. Adequate mixture proportion of each admixture is fixed at 0.3$\%$ of superplasticizer, 0.15$\%$ of liquidtype expansive admixture and 0.0005$\%$ of antifoaming agent to insure the improvement in drying shrinkage as well as comparable to the slump and air content of conventional concrete. With this mixture proportion, compressive strength of concrete using DSRS is comparable to that of conventional concrete. The use of DSRS studied by the authors has a favorable effect on reducing drying shrinkage due to the effect of water content and expansion by expansive admixture.

  • PDF