• Title/Summary/Keyword: recovery ratio

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The Optimization of Hydrometallurgical Process for Recovery of Zinc from Electric Arc Furnace Dust (Part I : leaching process) (습식산화법을 이용한 제강분진 내 아연회수를 위한 최적조건 도출에 관한 연구(Part I; 침출공정))

  • Moon, Dea-Hyun;Ahn, Sang-Woo;Kim, Han-lae;Kim, Ji-Tae;Chang, Soon-Woong
    • Resources Recycling
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    • v.24 no.3
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    • pp.27-33
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    • 2015
  • EAFD (Electric Arc Furnace Dust) is considered as pernicious pollutant, assigned hazardous waste. Since this dust is a by-product of industry, it contains valuable metals such as Fe, Zn, Ni, Cu which can be turned into resources by recycling process. In this study, hydrometallurgical process was applied to recover Zn from Electric Arc Furnace Dusts. The result showed 95% Zn recovery at 3M $H_2SO_4$, Solids/Liquid ratio 1:2 and aeration of 1.8L/min for 2hr. However there was 80% Zn recovery at lower $H_2SO_4$ concentration apply for pilot scale plant.

Effect of Substitution of Recycled Fine Aggregate on Concrete Performance. (재생잔골재 대체가 콘크리트 성능에 미치는 영향)

  • 정용일;양은익;정기철;김학모;최중철
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.233-238
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    • 2002
  • In this paper, the characteristics of fresh and hardened recycled concrete were experimentally compared to investigate the applicability of the recycled fine aggregates with the substitution ratio. Test results show that the workability of the recycled concrete decreases with the increment of substitution ratio of the recycled fine aggregates except for type-D case which has a lower absorption ratio. Also air content was increased with increasing substitution ratio. It was found that the compressive strength and elastic modulus of recycled concrete were decreased with increasing substitution ratio of the recycled fine aggregates. And, the superplasticizer was more effective on the workability recovery of the recycled concrete.

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Multi-stage Process Study of PEI-PDMS Hollow Fiber Composite Membrane Modules for $H_2/CO_2$ Mixed Gas Separation ($H_2/CO_2$ 혼합기체의 분리를 위한 PEI-PDMS 중공사 복합막 모듈의 다단 공정 연구)

  • Lee, Chung Seop;Cho, Eun Hye;Ha, Seong Yong;Chung, Jong Tae;Rhim, Ji Won
    • Membrane Journal
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    • v.23 no.1
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    • pp.1-11
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    • 2013
  • Poly(ether imide) (PEI)-poly(dimethylsioxane) (PDMS) composite membranes and their modules were prepared, which are capable of selective $CO_2$ separation from the mixture gas. The gas flow rate, concentration, recovery ratio of $H_2$ and removal ratio of $CO_2$ outflowing by stage-cut were characterized at $25^{\circ}C$ and the constant pressure. In addition, to increase the recovery ratio of $H_2$, one stage, two stage series connection, and three stages series + parallel connection tests were carried out. When the stage-cut was 0.32 for the three stages connection operation, the concentration $H_2$ of the produced gas and the recovery ratio of $H_2$ was 97% and 85%, respectively. And also the removal ratio of $CO_2$ was 90% was obtained and the recycled gas concentration was similar with that of the feed gases.

A Comparative Analysis of Standard Uptake Value Using the Recovery Coefficient Before and After Correcting Partial Volume Effect (부분 체적 효과에서 회복 계수를 이용한 보정 전과 후 SUV의 비교 분석)

  • Ko, Hyun-Soo;Park, Soon-Ki;Choi, Jae-Min;Kim, Jung-Sun;Jung, Woo-Young
    • The Korean Journal of Nuclear Medicine Technology
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    • v.15 no.1
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    • pp.10-16
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    • 2011
  • Purpose: The partial volume effect occurs because of limit of the spatial resolution. It makes partial loss of intensity and causes SUV to be lower than it should actually be. So the purpose of this study is to calculate recovery coefficient for correcting PVE from phantom study and to compare before and after SUV correction applying to PET/CT examination. Materials and Methods: The flangeless Esser PET phantom consisting of four hot cylinders was used for this study. All of the hot cylinders were filled with FDG solution of 20.72 MBq per 1000 ml, and the phantom background was filled with FDG solution of different concentrations (33.30, 22.20, 16.65 MBq per 6440 ml) to yield H/B ratios of around 4:1, 6:1 and 8:1. Using the Biograph Truepoint 40(SIEMENS, Germany), we applied recovery coefficient method to 30 patients who were diagnosed with lung cancer after PET/CT exam. And then we analyzed and compared SUV before and after correcting partial volume effect. Results: The smaller the diameter of hot cylinder becomes, the more recovery coefficient decreased. When we applied recovery coefficient to clinical patients and compared SUV before and after correcting PVE, before the correction all lesions gave an average max SUV of 7.83. And after the correction, the average max SUV increases to 10.31. The differences in the max SUV between before and after correction were analyzed by paired t test. As a result, there were statistically significant differences (t=7.21, p=0.000). Conclusion: The SUV for quantification should be measured precisely to give consistent information of tumor uptake. But PVE is one of factors that causes SUV to be lower and to be underestimated. We can correct this PVE and calculate corrected SUV using the recovery coefficient from phantom study. And if we apply this correction method to clinical patients, we can finally assess and provide quantitative analysis more accurately.

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Study on Recovery of Separated Hydrofluoric Acid, Nitric Acid and Acetic Acid Respectively from Mixed Waste Acid Produced during Semiconductor Wafer Process (반도체 웨이퍼 제조공정(製造工程) 중 발생혼합폐산(發生混合廢酸)으로부터 불산, 질산 및 초산의 각 산 회수(回收)에 관한 연구(硏究))

  • Kim, Ju-Yup;Kim, Hyun-Sang;Bae, Woo-Keun
    • Resources Recycling
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    • v.18 no.4
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    • pp.62-69
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    • 2009
  • We researched separation of mixed waste acids with HF, $CH_3COOH$, $HNO_3$ that were produced during a semiconductor wafer process to recycle these acids. At first, we manufactured the fluoride compound in form of $Na_2SiF_6$ by precipitating HF using $NaNO_3$ and Si powder. The concentration of HF was reduced from the initial concentration of 127 g/L to 0.5 g/L with an HF recovery ratio of 99.5%. After the manufacture of $Na_2SiF_6$, the concentration of $HNO_3$ and $CH_3COOH$ demonstrated 502 g/L and 117 g/L respectively. Following these findings we added NaOH in this $CH_3COOH/HNO_3$ mixed acid in order to obtain pH=4. Next we separated the $CH_3COOH$ and recoverd it through the use of vaccum evaporation at -440 mmHg, $95^{\circ}C$. The concentration of the recovered $CH_3COOH$ was approximately 15% and the recovery ratio of $CH_3COOH$ was over 85%. We precipitated the $NaNO_3$ by cooling the concentrated solution to $20^{\circ}C$ with a $HNO_3$ recovery ratio of over 93%. We confirmed that only $Na_2SiF_6$ and $NaNO_3$ were manufactured by XRD analysis after drying these precipitants at $90^{\circ}C$. The precipitants demonstrated a purity of approximately 97% and 98% respectively. Therefore, the purity of the precipitants proved to be similar to that of commercial products.

A Study on Inter-agency Fare Allocation Methods under the Integrated Distance-based Fare System in Seoul (서울시의 대중교통 통합거리비례요금제 하에서 운영기관 간 요금정산방안에 관한 연구)

  • Yun, Ji-Hyeon;Kim, Seong-Su
    • Journal of Korean Society of Transportation
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    • v.25 no.1 s.94
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    • pp.37-47
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    • 2007
  • The Integrated Public Transport Reforms of the Seoul Metropolitan Government, which were implemented on the $1^{st}$ of July. 2004, launched a new fare allocation method. However, when a Private transit operator or a new transport system is introduced into the existing system, it will cause an allocation problem. Therefore, this study aims to Propose a rational fare allocation method which can be applicable regardless of the number of Public transportation modes or operators. To create alternatives, this study has adopted a fundamental principle of revenue allocation methods for the transit or communications sectors, and has applied it to the current transit system of Seoul. This study kas analyzed results of the cost recovery ratios and characteristics of each alternative through case studies. This study kas Presented an assessment criterion Z in order to select an optimal alternative. The criterion consists of the sum of the cost recovery ratio of each operator and the difference of the cost recovery ratio for each agency in inter-agency transit. Using the assessment criterion. the results showed that Alternative 1 is superior to the others : Alternative 1 is considering passenger-km of each operator and unit cost of passenger-km for each operator.

A Study on the Cementation Reaction of Copper-containing Waste Etching Solution to the Shape of Iron Samples (철 샘플에 따른 구리 함유 폐에칭액의 시멘테이션 반응에 대한 연구)

  • Kim, Bo-Ram;Jang, Dae-Hwan;Kim, Dae-Weon
    • Clean Technology
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    • v.27 no.3
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    • pp.240-246
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    • 2021
  • The waste etching solution for chip on film (COF) contained about 3.5% copper, and it was recovered through cementation using iron samples. The effect of cementation with plate, chip, and powder iron samples was investigated. The molar ratio (m/r) of iron to copper was used as a variable in order to increase the recovery rate of copper. As the molar ratio increased, the copper content in the solution rapidly decreased at the beginning of the cementation reaction. Before and after the reaction, the copper content of the solution was determined by Inductively Coupled Plasma (ICP) using copper concentration according to time. After cementation at room temperature for 1 hour, the recovery rate of copper had increased the most in the iron powder sample, having the largest specific surface area of the samples, followed by the chip and plate samples. The recovered copper powder was characterized for its crystalline phase, morphology, and elemental composition by X-ray diffraction (XRD), scanning electron microscopy (SEM), and Energy-dispersive X-ray spectroscopy (EDS), respectively. Copper and unreacted iron were present together in the iron powder samples. The optimum condition for recovering copper was obtained using iron chips with a molar ratio of iron to copper of 4 giving a recovery rate of about 98.4%.

Recovery of Acetic Acid from An Ethanol Fermentation Broth by Liquid-Liquid Extraction (LLE) Using Various Solvents

  • Pham, Thi Thu Huong;Kim, Tae Hyun;Um, Byung-Hwan
    • Korean Chemical Engineering Research
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    • v.53 no.6
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    • pp.695-702
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    • 2015
  • Liquid-liquid extraction (LLE) using various solvents was studied for recovery of acetic acid from a synthetic ethanol fermentation broth. The microbial fermentation of sugars presented in hydrolyzate gives rise to acetic acid as a byproduct. In order to obtain pure ethanol for use as a biofuel, fermentation broth should be subjected to acetic acid removal step and the recovered acetic acid can be put to industrial use. Herein, batch LLE experiments were carried out at $25^{\circ}C$ using a synthetic fermentation broth comprising $20.0g\;l^{-1}$ acetic acid and $5.0g\;l^{-1}$ ethanol. Ethyl acetate (EtOAc), tri-n-octylphosphine oxide (TOPO), tri-n-octylamine (TOA), and tri-n-alkylphosphine oxide (TAPO) were utilized as solvents, and the extraction potential of each solvent was evaluated by varying the organic phase-to-aqueous phase ratios as 0.2, 0.5, 1.0, 2.0, and 4.0. The highest acetic acid extraction yield was achieved with TAPO; however, the lowest ethanol-to-acetic acid extraction ratio was obtained using TOPO. In a single-stage batch extraction, 97.0 % and 92.4 % of acetic acid could be extracted using TAPO and TOPO when the ratio of organic-to-aqueous phases is 4:1 respectively. A higher solvent-to-feed ratio resulted in an increase in the ethanol-to-acetic acid ratio, which decreased both acetic acid purity and acetic acid extraction yield.

Outcomes of Critical Pathway in Laparoscopic and Open Surgical Treatments for Gastric Cancer Patients: Patients Selection for Fast-Track Program through Retrospective Analysis

  • Choi, Ji Woo;Xuan, Yi;Hur, Hoon;Byun, Cheul Su;Han, Sang-Uk;Cho, Yong Kwan
    • Journal of Gastric Cancer
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    • v.13 no.2
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    • pp.98-105
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    • 2013
  • Purpose: The aim of this study is to investigate the clinical factors affecting on the cure rate by invasive and open surgery for gastric cancer and to establish a subgroup of patients who can be applied by the early recovery after surgery program through this retrospective analysis. Materials and Methods: In this retrospective study, we analyzed 425 patients who underwent gastric cancer surgery between January 2011 and December 2011 and were managed with conventional clinical therapies. This clinical algorithm was made when the patient was in minimally invasive surgery group and discharged from hospital one day faster than them in open surgery group. Results: The completion rate of the clinical pathway was 62.4%. Despite the different applications of clinical pathway, completion rate in minimally invasive surgery group was significantly higher than that of open group (P<0.001). In multivariate analysis, the surgical procedure of minimally invasive surgery (odds ratio=4.281) was the most predictable factor to complete clinical pathway. Additionally, younger patients (odds ratio=1.933) who underwent distal gastrectomy (odds ratio=1.999) without combined resection (odds ratio=3.069) were predicted to accomplish the clinical pathway without any modifications. Conclusions: We concluded that high efficacy of the clinical pathway for gastric cancer surgery was expected to selected patients through retrospective analysis (expected completion rate=85.4%). In addition, these patients would become enrolled criteria for early recovery program in gastric cancer surgery.

The Optimization of Solvent Extraction Process of Iron Chloride Etching Waste Solution (염화철 에칭폐액의 용매추출공정 최적화에 관한 연구)

  • Park, Il-Jeong;Kim, Dae-Weon;Kim, Geon-Hong;Chae, Hong-jun;Lee, Sang-Woo;Jung, Hang-Chul
    • Clean Technology
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    • v.23 no.3
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    • pp.279-285
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    • 2017
  • In this study, a new organophosphorus acid-based solvent (KMC-P) from KMC Co., Ltd. was used for the recovery of the iron chloride etching waste solution. In order to increase the extraction efficiency for the new solvent in the solvent extraction process, we selected the process variables and conducted the optimization experiment according to the DOE to investigate the correlation between the variables. Solvent concentration, pH, and O/A ratio were found to be factors affecting extraction and stripping efficiency. The optimum stripping efficiency was 69.7% when the solvent concentration was 29.4 wt%, the HCl addition amount was 0 mL, and the O/A ratio was 7, and the reliability was more than 86%.